Method for producing nickel powder having low carbon concentration and low sulfur concentration

Patent metadata

Field	Value
Publication number	US-10500644-B2
Application number	US-201515303557-A
Country	US
Kind code	B2
Filing date	Apr 13, 2015
Priority date	Apr 15, 2014
Publication date	Dec 10, 2019
Grant date	Dec 10, 2019

Abstract

Provided a production method for reducing the content level of sulfur and carbon which are impurities in nickel powder to improve the quality of nickel powder produced by a complexing reduction method. The method of producing nickel powder having low carbon and sulfur concentrations includes: a complexing treatment of adding a complexing agent to a nickel sulfate aqueous solution to form a solution containing nickel complex ions; maintaining the solution containing nickel complex ions at a solution temperature of 150 to 250° C. in a pressure vessel and blowing hydrogen gas into the solution containing nickel complex ions to perform hydrogen reduction to produce nickel powder; washing the nickel powder with water; and then roasting the nickel powder washed with water in a mixed gas atmosphere of nitrogen and hydrogen.

First claim

The invention claimed is:

1. A method of producing nickel powder having low carbon and sulfur concentrations, the method sequentially comprising:
a complexing treatment of adding a complexing agent to a nickel sulfate aqueous solution to prepare a solution containing nickel complex ions;
a hydrogen reduction treatment of charging the solution containing nickel complex ions in a pressure vessel, maintaining the solution at a solution temperature of 150 to 250° C., and blowing hydrogen gas into the solution containing nickel complex ions to perform hydrogen reduction to produce nickel powder;
a water-washing treatment of washing the nickel powder with water of which amount is at least equal to and at most 5 times larger than a weight of the nickel powder at a solution temperature of 50 to 90° C., or of subjecting a mixture of the nickel powder and water to ultrasonic washing at atmospheric pressure or below, to thereby produce nickel powder having a content level of sulfur reduced by 95% from the content level of sulfur in the nickel powder obtained in the hydrogen reduction treatment and having a content level of carbon reduced by 65% from the content level of the carbon in the nickel powder obtained in the hydrogen reduction treatment; and
a roasting treatment of roasting the nickel powder washed with water in a mixed gas atmosphere of hydrogen having a concentration of 2 to 4% by weight and nitrogen, and thereby causing the content level of the sulfur to be reduced further from the content level of the sulfur obtained in the water-washing treatment and causing the content level of the carbon to be reduced further from the content level of the carbon obtained in the water-washing treatment nickel.

2. The method of producing nickel powder having low carbon and sulfur concentrations according to claim 1 , wherein a temperature during the roasting treatment is 700° C. or more and 1250° C. or less.

3. The method of producing nickel powder having low carbon and sulfur concentrations according to claim 1 , wherein the roasting treatment is carried out so that the content level of sulfur is reduced by at least 50% from the content level of sulfur in the nickel powder obtained in the water-washing treatment and so that the content level of carbon is reduced by at least 29% from the content level of carbon in the nickel powder obtained in the water-washing treatment.

4. The method of producing nickel powder having low carbon and sulfur concentrations according to claim 1 , wherein the roasting treatment is carried out so that the content level of sulfur is reduced by at least 75% from the content level of sulfur in the nickel powder obtained in the water-washing treatment and so that the content level of carbon is reduced by at least 71% from the content level of carbon in the nickel powder obtained in the water-washing treatment.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Ozaki Yoshitomo
• HEGURI Shin-ichi
• Takaishi Kazuyuki
• Ikeda Osamu
• Ohara Hideki
• Yoneyama Tomoaki
• Kudo Yohei

Classifications

• B22F1/00

  Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties · CPC title

• B22F2301/15

  Nickel or cobalt · CPC title

• B22F2009/245

  Reduction reaction in an Ionic Liquid [IL] · CPC title

• C22C19/03

  based on nickel · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title