Alkali ion conducting plastic crystals

Patent metadata

Field	Value
Publication number	US-10497970-B2
Application number	US-201816023959-A
Country	US
Kind code	B2
Filing date	Jun 29, 2018
Priority date	Mar 14, 2013
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

A solid electrolyte represented by general formula LiySiRx(MO4), where x is an integer from 1 to 3 inclusive, y=4−x, each R present is independently C1-C3 alkyl or C1-C3 alkoxy, and M is sulfur, selenium, or tellurium. Methods of making the solid electrolyte include combining a phenylsilane and a first acid to yield mixture including benzene and a second acid, and combining at least one of an alkali halide, and alkali amide, and an alkali alkoxide with the second acid to yield a product d represented by general formula LiySiRx(MO4)y. The second acid may be in the form of a liquid or a solid. The phenylsilane includes at least one C1-C3 alkyl substituent or at least one C1-C3 alkoxy substituent, and the first acid includes at least one of sulfuric acid, selenic acid, and telluric acid.

First claim

What is claimed is:

1. A solid electrolyte represented by general formula Li y SiR x (MO 4 ) y , wherein:
x is an integer from 1 to 3 inclusive,
y=4−Z,
each R present is independently C1-C2 alkoxy, and
M is sulfur or selenium.

2. The solid electrolyte of claim 1 , wherein each R present is independently C1-C2 alkoxy.

3. The solid electrolyte of claim 2 , wherein at least one R is methoxy.

4. The solid electrolyte of claim 2 , wherein at least one R is ethoxy.

5. The solid electrolyte of claim 1 , wherein x is 1.

6. The solid electrolyte of claim 1 , wherein x is 2.

7. The solid electrolyte of claim 1 , wherein x is 3.

8. A composition comprising a mixture of two or more different solid electrolytes of claim 1 .

9. A method of making a solid electrolyte, the method comprising:
combining a phenylsilane and a first acid to yield a mixture comprising benzene and a second acid, wherein the phenylsilane comprises at least one C1-C3 alkyl substituent or at least one C1-C2 alkoxy substituent and the first acid comprises a diprotic acid;
combining at least one of an alkali halide, an alkali amide, or an alkali alkoxide with the second acid to yield a product comprising a solid electrolyte represented by general formula Li y SiR x (MO 4 ) y , wherein:
x is an integer from 1 to 3 inclusive, y=4−X,
each R present is independently C1-C2 alkoxy, and
M is sulfur or selenium.

10. The method of claim 9 , wherein the phenylsilane is selected from the group consisting of trimethylphenylsilane, trimethoxyphenylsilane, methyldiethylphenylsilane, dimethylethylphenylsilane, diphenyldimethylsilane, dimethyldiphenylsilane, monomethyltriphenylsilane, triethylphenylsilane, methyldimethoxyphenylsilane, dimethylmethoxyphenylsilane, dimethylethoxyphenylsilane, methyldiethoxyphenylsilane, methylmethoxyethoxyphenylsilane, ethylmethoxyethoxyphenylsilane, triethoxyphenylsilane, methylethylpropylphenylsilane, methyldipropylphenylsilane, ethyldipropylphenylsilane, methypropyldiphenylsilane, methylpropyldiphenylsilane, ethylpropyldiphenylsilane, methylethylpropoxyphenylsilane, methyldipropoxyphenylsilane, dipropoxydiphenylsilane, methylethoxypropoxyphenylsilane, and ethoxypropoxydiphenylsilane.

11. The method of claim 9 , wherein the alkali amide is selected from the group consisting of lithium amides, sodium amides, and potassium amides.

12. The method of claim 9 , wherein the alkali alkoxide is selected from the group consisting of lithium alkoxides, sodium alkoxides, and potassium alkoxides.

13. The method of claim 9 , wherein combining the phenylsilane and the first acid replaces a phenyl group of the phenylsilane with a hydrogen oxyacid group to yield a silane, and the oxyacid group comprises sulfate or selenite.

14. The method of claim 9 , wherein the solid electrolyte is a first solid electrolyte, and further comprising combining the first solid electrolyte and a second solid electrolyte to yield a composite solid electrolyte.

15. The method of claim 9 , wherein the diprotic acid comprises at least one of sulfuric acid or selenic acid.

16. The method of claim 9 , wherein the alkali halide is selected from the group consisting of lithium halides, sodium halides, and potassium halides.

17. The method of claim 16 , wherein the alkali halide is an alkali chloride.

18. The method of claim 9 , wherein the second acid is in the form of a liquid or a solid.

19. The method of claim 9 , wherein the product is in the form of a waxy solid.

Assignees

• Angell Charles Austen
• Klein Iolanda Santana
• Tucker Telpriore Greg
• Univ Arizona State

Inventors

• Angell Charles Austen
• Klein Iolanda Santana
• Tucker Telpriore Greg

Classifications

• H01M2300/0091

  in the form of mixtures · CPC title

• H01M2300/0065

  Solid electrolytes · CPC title

• H01M2300/006

  Hydroxides · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M10/0564 Primary

  the electrolyte being constituted of organic materials only · CPC title