Battery

Patent metadata

Field	Value
Publication number	US-10497938-B2
Application number	US-201414898993-A
Country	US
Kind code	B2
Filing date	Jun 5, 2014
Priority date	Jun 21, 2013
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

The present invention relates to a battery that includes at least one electrochemical cell. The at least one electrochemical cell includes a first electrode, a second electrode, a first electroactive material, a second electroactive material, and an electrolyte which is in contact with both electrodes, and at least one of the first electroactive material and the second electroactive material includes a radialene compound. Also provided is an electroactive material as well as a radialene compound.

First claim

The invention claimed is:

1. A battery comprising at least one electrochemical cell, the at least one electrochemical cell comprising a first electrode, a second electrode, a first electroactive material, a second electroactive material, and an electrolyte, wherein the electrolyte is in contact with both electrodes, and at least one of the first electroactive material or the second electroactive material comprises a radialene compound at an amount of at least 50% by weight, based on the weight of the first electroactive material or the second electroactive material, respectively, wherein the radialene compound comprises a carbocyclic core substituted with one or more groups independently selected from imino or methylidene, wherein the imino and methylidene groups are substituted with one or more electron withdrawing substituents, wherein the one or more electron withdrawing substituents are cyano groups.

2. The battery according to claim 1 , wherein the first electroactive material comprises the radialene compound, and is disposed in a first compartment of the electrochemical cell, the first compartment comprising the first electrode, which is electrically connected with the positive pole of the battery.

3. The battery according to claim 1 , wherein the radialene compound has the general formula (I):

wherein Z 1 , Z 2 and Z 3 are independently selected from dicyanomethylidene, or a cyanimino group, x is an integer selected from 1 or 2, y is an integer selected from 0, 1 or 2, and the dashed lines represent the following when y is 0, 1, or 2—
i) when y is 0,
6 electrons delocalized over 6 bonds if x is 1, and
8 electrons delocalized over 8 bonds if x is 2,

ii) when y is 1,
7 electrons delocalized over 6 bonds if x is 1, and
9 electrons delocalized over 8 bonds if x is 2, and

iii) when y is 2,
8 electrons delocalized over 6 bonds if x is 1, and
10 electrons delocalized over 8 bonds if x is 2.

4. The battery according to claim 3 , wherein at least one of Z 1 and Z 2 , and at least one Z 3 is dicyanomethylidene.

5. The battery according to claim 1 , wherein the electrolyte comprises alkali metal cations.

6. The battery according to claim 1 , wherein the first electroactive material in its reduced state comprises alkali metal cations.

7. The battery according to claim 1 , wherein the second electroactive material in its reduced state comprises an alkali metal.

8. The battery according to claim 6 , wherein the alkali metal cations are lithium cations.

9. The battery according to claim 7 , wherein the alkali metal is Li.

10. An electroactive material comprising a radialene compound, wherein the electroactive material is solid or gel-like.

11. A compound having formula (II):

wherein Z 1 , Z 2 , and Z 3 are independently selected from dicyanomethylidene or a cyanimino group, x is an integer selected from 1 or 2, the dashed lines represent 8 electrons delocalized over 6 bonds if x is 1, and 10 electrons delocalized over 8 bonds if x is 2, and excluding a compound of formula (II) wherein [i] x is 1, and [ii] Z 1 , Z 2 , and Z 3 are dicyanomethylidene.

12. The compound according to claim 11 , wherein at least one of Z 1 and Z 2 , and at least one Z 3 is dicyanomethylidene.

Assignees

• Novaled Gmbh

Inventors

• Bouazza Sofiane
• Bobbio Carla
• Werner Ansgar

Classifications

• C07C255/61

  containing cyano groups and nitrogen atoms being part of imino groups bound to the same carbon skeleton · CPC title

• H01M2220/30

  Batteries in portable systems, e.g. mobile phone, laptop · CPC title

• C07C2601/04

  with a four-membered ring · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title

• C07C255/31

  having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing rings other than six-membered aromatic rings · CPC title