Thermoelectric converter and manufacturing method for manufacturing thermoelectric converter

Patent metadata

Field	Value
Publication number	US-10497850-B2
Application number	US-201415303644-A
Country	US
Kind code	B2
Filing date	Aug 25, 2014
Priority date	May 1, 2014
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

A thermoelectric converter includes a substrate and two thermoelectric elements that may include a flat portion and a concave portion. The thermoelectric elements each include one end that contacts with the thermoelectric element and an other end that contacts with thermoelectric element at a bottom surface of the concave portion. The thermoelectric elements are each positioned to be suspended across a space defined by the concave portion. The thermoelectric converter can be manufactured through photolithographic process, and can be incorporated into an exhaust gas recirculation device.

First claim

The invention claimed is:

1. A thermoelectric converter, comprising:
a substrate including first and second regions having different heights than each other; and
a thermoelectric element including higher and lower temperature ends that are in physical contact with the first and second regions, respectively, the thermoelectric element including a bridge provided in an open space defined between the first and second regions in midair,
wherein the substrate includes a concave portion, and wherein the bridge is suspended across the concave portion.

2. A thermoelectric converter according to claim 1 , wherein the substrate includes on an upper surface thereof the concave portion having a bottom surface and a flat portion lacking the concave portion therein, and one of the first and second regions is provided on the flat portion and the other one of the first and second regions is provided on the bottom surface of the concave portion.

3. A thermoelectric converter according to claim 1 , wherein one of the higher and lower temperature ends of the thermoelectric element is in contact with another thermoelectric element having a conductivity type different from one of the thermoelectric element, and the other of higher and lower temperature ends is in contact with a conductor.

4. A thermoelectric converter according to claim 1 , wherein the substrate is a silicon-on-insulator substrate including two silicon layers and an insulating layer sandwiched between the two silicon layers, and wherein upper surfaces of the two silicon layers have crystalline orientations that are different from each other.

5. A thermoelectric converter according to claim 1 , wherein the thermoelectric converter is provided in an automobile having an engine and between a higher temperature pipe connected to an exhaust pipe of the engine and a lower temperature pipe through which coolant passes.

6. A thermoelectric converter according to claim 1 , wherein the thermoelectric element includes at least one of:
a p-type thermoelectric material selected from the group consisting of 1) Ag-doped Mg 2 Si, 2) Mn-doped or Al-doped β-FeSi 2 , 3) MnSi 2 , 4) FeSb based material, and 5) PbTe based material; and
an n-type thermoelectric material selected from the group consisting of Al-doped, Sb-doped or Bi-doped Mg 2 Si, 2) Co-doped, Ni-doped or B-doped β-FeSi 2 , 3) CoSi 2 , 4) CoSb based material, and 5) PbTe based material.

7. A thermoelectric converter according to claim 1 , wherein the thermoelectric element includes ZnO in which Al or In 2 O 3 is doped.

8. A thermoelectric converter according to claim 1 , wherein the bridge of the thermoelectric element includes a cut-out portion.

9. A thermoelectric converter according to claim 1 , wherein the bridge of the thermoelectric element includes a first cut-out portion provided in a first side of the bridge and a second cut-out portion provided in a second side opposite to the first side of the bridge.

10. A thermoelectric converter according to claim 1 , wherein the thermoelectric element includes one selected from the group consisting of a bent portion and a curved portion formed in the bridge.

11. A method for manufacturing a thermoelectric converter according to claim 1 , comprising:
preparing a substrate;
performing an anisotropic etching on the substrate;
depositing a thermoelectric material on the substrate;
performing an anisotropic etching on the substrate to form a concave portion therein so that the thermoelectric material is suspended across in the concave portion.

12. A thermoelectric converter according to claim 1 , wherein a surface of the bridge facing to the second region does not contact the substrate.

Assignees

• Mitsubishi Electric Corp

Inventors

• Yamashita Akira
• Motonami Kaoru
• Fujiwara Nobuo
• Tokioka Hidetada

Classifications

• F01N5/025

  the device being thermoelectric generators · CPC title

• H01L35/18

  Electricity · mapped topic

• H01L35/20

  Electricity · mapped topic

• H01L35/32 Primary

  Electricity · mapped topic

• H01L35/10

  Electricity · mapped topic