Halogen-free flame-retardant polyolefin insulation composition and cable having an insulating layer formed from the same

Patent metadata

Field	Value
Publication number	US-10497491-B2
Application number	US-201715560329-A
Country	US
Kind code	B2
Filing date	Jun 26, 2017
Priority date	Mar 30, 2017
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

A halogen-free flame-retardant insulation composition including: halogen-free resin serving as base resin; and a flame-retardant agent. The halogen-free resin includes: first polyolefin resin having a melting point of 90 to 170° C.; and second polyolefin resin having a melting point of 50 to 80° C. Content of the flame-retardant agent is 100 to 200 parts by weight with respect to 100 parts by weight of the base resin, and an insulating sample formed of the insulation composition has an elongation rate of 125% or more.

First claim

The invention claimed is:

1. A halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube, comprising:
halogen-free resin serving as base resin;
a flame-retardant agent,
a flame-retardant supplement;
an inorganic filler; and
at least one type of a silane-based cross-linking agent selected from a group consisting of vinyl trimethoxy silane, 3-(trimethoxysilyl)-propylmethacrylate, vinyl triethoxy silane, and vinyl trimethoxyethoxy silane,
wherein the halogen-free resin comprises:
first polyolefin resin having a melting point of 90 to 170° C.; and
second polyolefin resin having a melting point of 50 to 80° C.,

wherein the inorganic filler comprises calcium carbonate (CaCO3),
wherein a mixing ratio of the first polyolefin resin and the second polyolefin resin is 2:8 to 6:4,
wherein content of the flame-retardant agent is 100 to 200 parts by weight with respect to 100 parts by weight of the base resin,
wherein total content of inorganic additives including the flame-retardant agent and the inorganic filler is 110 to 230 parts by weight with respect to 100 parts by weight of the base resin,
wherein content of the inorganic filler is 10 to 50 parts by weight with respect to 100 parts by weight of the base resin,
wherein an amount of the flame-retardant agent is three to six times greater than that of the inorganic filler,
wherein an amount of the silane based cross-linking agent is 2.0 to 5.0 parts by weight with respect to 100 parts by weight of the base resin, wherein a gel fraction of the insulation composition is in a range of 50 to 95% after halogen-free resin of the insulation composition is crosslinked, and
wherein an insulating sample formed of the insulation composition has an elongation rate of 125% or more.

2. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 1 , wherein content of the flame-retardant supplement is 10 to 50 parts by weight with respect to 100 parts by weight of the base resin.

3. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 1 , wherein a difference between the melting points of the first polyolefin resin and the second polyolefin resin is 20° C. or more.

4. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 1 , wherein the insulating sample formed of the insulation composition has an elongation rate of 125% to 250%.

5. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 1 , wherein a heat distortion rate of a tubular insulating sample formed of the insulation composition and having a length of 70 mm is measured to be 50% or less according to a standard KS C 60811-2-1, the heat distortion rate being a rate of increase in the length of the tubular insulation sample, measured by attaching a weight having a certain weight to the tubular insulating sample in an oven of 200° C. and measuring the rate of increase in the length of the sample after fifteen minutes.

6. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 1 , wherein the first polyolefin resin comprises low-density polyethylene resin, and
the second polyolefin resin comprises polyolefin elastomer.

7. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 1 , wherein the halogen-free resin further comprises a modified polyolefin resin, and the modified polyolefin resin comprises modified linear low-density polyethylene resin (LLDPE) of 5 to 20 parts by weight with respect to 100 parts by weight of the base resin.

8. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 7 , wherein the modified linear low-density polyethylene resin (LLDPE) comprises linear low-density polyethylene resin (MA-g-LLDPE) grafted with maleic anhydride.

9. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 1 , further comprising internal lubricant of 1 to 10 parts by weight with respect to 100 parts by weight of the base resin.

10. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 9 , wherein the internal lubricant comprises polyethylene-based wax of 1 to 4 parts by weight with respect to 100 parts by weight of the base resin.

11. The halogen-free flame-retardant insulation composition for a silane cross-linked insulation layer of a cable used for interior wiring and transferred through a conduit tube of claim 1 , wherein the flame-retardant agent comprises magnesium hydroxide (Mg(OH) 2 ) or aluminum hydroxide (Al(OH) 3 ) which is surface-treated with at least one type of a surface modifier selected from a group consisting of vinylsilane, metacrylic silane, stearic acid, oleic acid, aminopolysiloxane, and a titanate-based coupling agent.

12. A halogen-free flame-retardant insulation cable used for interior wiring and transferred through a conduit tube, comprising:
a conductor; and
a silane cross-linked insulation layer covering the conductor, and formed of the halogen-free flame-retardant insulation composition of claim 1 .

13. The halogen-free flame-retardant insulation cable used for interior wiring and transferred through a conduit tube of claim 12 , wherein the halogen-free flame-retardant insulation composition further comprises:
a flame-retardant supplement; and
an inorganic filler.

14. The halogen-free flame-retardant insulation cable used for interior wiring and transferred through a conduit tube of claim 12 , further comprising an outer insulation layer covering the insulation layer,
wherein the outer insulation layer is formed of the halogen-free flame-retardant insulation composition of claim 1 ,
wherein the outer insulation layer has a thickness of 30 to 500 μm, and comprises external lubricant.

Assignees

• Ls Cable & System Ltd

Inventors

• Ryu Ik-Hyun
• Lee Jae-Ik
• Lee Won-Suck
• Shin Ji-Wook
• Lee Tae-Hyun

Classifications

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• H01B7/0216

  Two layers · CPC title

• H01B3/427

  Polyethers · CPC title

• H01B3/307

  Other macromolecular compounds · CPC title

• H01B7/295 Primary

  using material resistant to flame · CPC title