Gas sensor device, gas measurement method, and gas measurement device

Patent metadata

Field	Value
Publication number	US-10495595-B2
Application number	US-201615381074-A
Country	US
Kind code	B2
Filing date	Dec 15, 2016
Priority date	Mar 3, 2016
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

A gas sensor device includes: a sensor film including a sensor surface and a resistance which increases with an increase in an amount of gas adsorbed on the sensor surface; a first electrode, a second electrode, and a third electrode that are electrically coupled to the sensor film; and a protective film that covers the sensor surface in a region between the first electrode and the second electrode, wherein the sensor surface is exposed in a region near the third electrode.

First claim

What is claimed is:

1. A gas sensor device comprising: a sensor film, which is a film containing one of CuBr, a Cu compound, and an Ag compound, including a sensor surface and a resistance which increases with an increase in an amount of ammonia gas adsorbed on the sensor surface; a first electrode, a second electrode, and a third electrode that are electrically coupled to the sensor film; and a protective film that covers the sensor surface in a region between the first electrode and the second electrode, wherein the sensor surface is exposed in a region adjacent to the third electrode.

2. The gas sensor device according to claim 1 , further comprising a fourth electrode, wherein the sensor surface is exposed in a region adjacent to the fourth electrode.

3. The gas sensor device according to claim 2 , wherein the sensor surface has a rectangular shape, the first electrode and the second electrode are connected to a first pair of opposing sides of the rectangular shape, and the third electrode and the fourth electrode are connected to a second pair of opposing sides of the rectangular shape.

4. The gas sensor device according to claim 2 , wherein a resistance between the third electrode and the fourth electrode makes a lamer change than a resistance between the first electrode and the second electrode with the increase in the amount of the ammonia gas adsorbed on the sensor surface.

5. The gas sensor device according to claim 1 , further comprising a substrate that contains an insulating material, wherein the first electrode, the second electrode, and the third electrode are disposed on the substrate, and the sensor film is disposed on the first electrode, the second electrode, and the third electrode.

6. The gas sensor device according to claim 1 , further comprising a substrate that contains an insulating material, wherein the sensor film is disposed on the substrate, and the first electrode, the second electrode, and the third electrode are disposed on the sensor film.

7. The gas sensor device according to claim 1 , wherein a resistance between the first electrode and the third electrode and a resistance between the second electrode and the third electrode make a larger change than a resistance between the first electrode and the second electrode with the increase in the amount of the ammonia gas adsorbed on the sensor surface.

8. A gas measurement method comprising: measuring, with use of a gas sensor device including a sensor film which is a film containing one of CuBr, a Cu compound, and an Ag compound and of which resistance increases with an increase in an amount of ammonia gas adsorbed on a sensor surface, a first electrode, a second electrode, and a third electrode that are electrically coupled to the sensor film, and a protective film that covers the sensor surface in a region between the first electrode and the second electrode, the sensor surface being exposed in a region adjacent to the third electrode, a resistance R A between the first electrode and the second electrode; measuring, with use of the gas sensor device, a resistance R B between the first electrode or the second electrode and the third electrode; sensing absence of the ammonia gas in case of R A ≈R B ; and sensing presence of the ammonia gas in case of R A <R B .

9. The gas measurement method according to claim 8 , further comprising: determining a resistance ratio R B /R A ; and calculating a concentration of the ammonia gas in accordance with a formula of C 1 ×(R B /R A )−C 2 by employing values of constants C 1 and C 2 which are respective predetermined values to calculate the concentration of the ammonia gas.

10. The gas measurement method according to claim 9 , wherein the respective predetermined values of the constants C 1 and C 2 are 14.3 and 104.

11. The gas measurement method according to claim 8 , wherein a measurement of the resistance R A and a measurement of the resistance R B are performed substantially at the same time.

12. A gas measurement device comprising: a memory that stores a gas measurement program; and a processor that performs, based on the gas measurement program, operations of: measuring, with use of a gas sensor device including a sensor film which is a film containing one of CuBr, a Cu compound, and an Ag compound and of which resistance increases with an increase in an amount of ammonia gas adsorbed on a sensor surface, a first electrode, a second electrode, and a third electrode that are electrically coupled to the sensor film, and a protective film that covers the sensor surface in a region between the first electrode and the second electrode, the sensor surface being exposed in a region adjacent to the third electrode, a resistance R A between the first electrode and the second electrode; measuring, with use of the gas sensor device, a resistance R B between the first electrode or the second electrode and the third electrode; sensing absence of the ammonia gas in case of R A ≈R B ; and sensing presence of the ammonia gas in case of R A <R B .

13. The gas measurement device according to claim 12 , wherein the processor:
determines a resistance ratio R B /R A ; and
calculates a concentration of the ammonia gas in accordance with a formula of C 1 ×(R B /R A )−C 2 by employing values of constants C 1 and C 2 which are respective predetermined values to calculate the concentration of the ammonia gas.

14. The gas measurement device according to claim 13 , wherein the respective predetermined values of the constants C 1 and C 2 are 14.3 and 104.

15. The gas measurement device according to claim 12 , wherein a measurement of the resistance R A and a measurement of the resistance R B are performed substantially at the same time.

Assignees

• Fujitsu Ltd

Inventors

• Karasawa Kazuaki
• Ushigome Michio
• Momose Satoru
• Takasu Ryozo
• Tsuboi Osamu

Classifications

• G01N33/0009

  General constructional details of gas analysers, e.g. portable test equipment (devices for withdrawing samples in the gaseous state G01N1/22) · CPC title

• G01N27/12 Primary

  of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid {, for detecting components in the fluid} · CPC title

• G01N33/0054

  Ammonia · CPC title

• G01N33/0027

  concerning the detector · CPC title

• G01N27/4077

  Means for protecting the electrolyte or the electrodes · CPC title