Absorbent fabric

Patent metadata

Field	Value
Publication number	US-10494741-B2
Application number	US-201415038915-A
Country	US
Kind code	B2
Filing date	Nov 25, 2014
Priority date	Nov 25, 2013
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

Provided is a fabric that semi-permanently absorbs water even without being subjected to water absorption treatment, i.e., an absorbent fabric that has a pleasant feel, can quickly absorb perspiration when worn, has excellent comfort, and is soft and suitable for use in inner wear, sportswear, etc. The absorbent fabric according to the present invention includes polyester fibers in which ethylene terephthalate constitutes at least 95 mol % of repeating units, wherein a carboxylic acid terminated linear oligomer component is present on the surface of the polyester fibers, and the absorbency according to the JIS L1907 dripping method after washing 30 times according to the JIS L0217 103 C method is at most 5 seconds. The polyester fibers preferably contain 0.005-1 wt % of the S element.

First claim

The invention claimed is:

1. An absorbent fabric comprising polyester fibers wherein the polyester fibers contain 0.005% by weight to 1% by weight of the element sulfur, 95 mol % or more of the repeating units of the polyester is ethylene terephthalate, carboxylic acid terminated linear oligomer components are present on the surface of the polyester fibers, wherein the concentration of a n=4 carboxylic acid terminated linear oligomer component represented by the following Formula 1:

as measured in LC/MS (liquid chromatography-mass spectroscopy) is equivalent to a concentration of 3 μg/ml to 15 μg/ml converted to a concentration of methyl benzoate by internal standardization, wherein the concentration of a n=3 cyclic oligomer represented by the following Formula 2:

as measured in LC/MS (liquid chromatography-mass spectroscopy) is equivalent to a concentration of 70 μg/ml or less converted to a concentration of methyl benzoate by internal standardization, and wherein water absorbency according to the dripping method of JIS L1907 after washing 100 times according to Method C of JIS L0217 No. 103 is 5 seconds or less.

2. The absorbent fabric according to claim 1 , wherein the polyester fibers containing 0.005% by weight to 1% by weight of the element sulfur are polyester fibers containing 0.5 mol % to 5 mol % of an ester-forming sulfonate compound.

3. The absorbent fabric according to claim 2 , wherein the ester-forming sulfonate compound is a metal sulfonate group-containing isophthalic acid.

4. The absorbent fabric according to claim 1 , wherein 0.1 to 30 pits having a length of 0.5 μm are formed in an area of 100 μm 2 on the surface of the polyester fibers containing 0.005% by weight to 1% by weight of the element sulfur.

5. The absorbent fabric according to claim 1 , wherein the peak intensity ratio of a Na adduct of a n=8 carboxylic acid terminated liner oligomer component represented by the following Formula 1:

to a Na adduct of α-cyano-4-hydroxycinnamic acid (CHCA) as an internal standard, as measured in MALDI-TOF/MS, is 0.05 to 0.100.

6. A method for producing the absorbent fabric according to claim 1 , comprising:
a step for performing alkaline reduction on polyester fibers at a reduction rate of 0.6% to 9% in a fabric containing polyester fibers containing the S element at 0.005% by weight to 1% by weight.

Assignees

• Asahi Chemical Ind
• Asahi Kasei Fibers Corp

Inventors

• Deguchi Junko
• Kinouchi Hiroyuki
• Yamamuro Misako

Classifications

• D06M13/228 Primary

  Cyclic esters, e.g. lactones · CPC title

• D01F6/92 Primary

  of polyesters · CPC title

• D06M2101/32

  Polyesters · CPC title

• D01F11/08

  of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• D06M11/38

  Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table · CPC title