Photochemical reaction device

Patent metadata

Field	Value
Publication number	US-10494724-B2
Application number	US-201615260908-A
Country	US
Kind code	B2
Filing date	Sep 9, 2016
Priority date	Mar 11, 2014
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

According to one embodiment, a photochemical reaction device includes: a solar cell; an electrolytic tank having a first tank storing a first solution including an oxidant and/or reductant of a redox medium and a second tank storing a second solution including water and/or proton; a first electrode set in the first tank, connected to a positive electrode of the solar cell through a first switching element, and connected to a negative electrode of the solar cell through a second switching element; and a second electrode set in the second tank, connected to the positive electrode of the solar cell through a third switching element, and connected to the negative electrode of the solar cell through a fourth switching element.

First claim

What is claimed is:

1. A photochemical reaction device comprising: a solar cell;
an electrolytic tank having a first tank storing a first solution comprising an oxidant and/or reductant of a redox medium and a second tank storing a second solution comprising water and/or protons, the first tank and second tank separated by a permeable membrane;
a first electrode set in the first tank, electrically connected to a positive electrode of the solar cell through a first switching element, and electrically connected to a negative electrode of the solar cell through a second switching element;
a second electrode set in the second tank and electrically connected to the positive electrode of the solar cell through a third switching element and not directly connected to the negative electrode of the solar cell;
a third electrode set in the second tank and electrically connected to the negative electrode of the solar coil through a fourth switching element and not directly connected to the positive electrode of the solar cell;
a switching element controller which controls on/off of the first switching element to the fourth switching element;
a first catalyst formed in contact with the first electrode and promoting an oxidation reaction and a reduction reaction of the redox medium in the first electrode;
a second catalyst formed in contact with the second electrode and promoting an oxidation reaction of water in the second electrode; and
a third catalyst formed in contact with the third electrode and promoting a reduction reaction of proton in the third electrode, wherein
the switching element controller is configured to turn the second switching element and the third switching element on and to turn the first switching element and the fourth switching element off to reduce the oxidant of the redox medium in the first tank and oxidize water in the second tank to produce oxygen, and
the switching element controller is configured to turn the first switching element and the fourth switching element on and to turn the second switching element and the third switching element off to oxidize the reductant the redox medium in the first tank and reduce proton in the second tank to produce hydrogen.

2. The photochemical reaction device of claim 1 , wherein the second solution comprises carbon dioxide, the switching element controller turns the first switching element and the fourth switching element on and turns the second switching element and the third switching element off to oxidize the reductant of the redox medium in the first tank and reduce carbon dioxide in the second tank to produce a carbon compound.

3. The photochemical reaction device of claim 1 , wherein the second solution comprises carbon dioxide, the switching element controller turns the first switching element and the fourth switching element on and turns the second switching element and the third switching element off to oxidize the reductant of the redox medium in the first tank and reduce carbon dioxide in the second tank to produce a carbon compound.

4. The photochemical reaction device of claim 1 , wherein a standard oxidation-reduction potential of the redox medium is smaller than the standard oxidation-reduction potential of water/oxygen and larger than the standard oxidation-reduction potential of proton/hydrogen.

5. The photochemical reaction device of claim 1 , wherein the second solution comprises a sacrificial reagent having a standard oxidation-reduction potential smaller than the standard oxidation-reduction potential of water/oxygen and larger than the standard oxidation-reduction potential of the redox medium.

6. The photochemical reaction device of claim 1 , wherein the solar cell is a single junction cell having a pair of pn junctions.

7. The photochemical reaction device of claim 1 , further comprising a sensor which measures states of the first solution, the second solution, the first tank, and the second tank.

8. The photochemical reaction device of claim 1 , further comprising an electrolyte storage tank storing a third solution which is the same as the first solution and supplying the third solution to the first tank.

9. The photochemical reaction device of claim 1 , further comprising: an external power supply; and a power demand unit,
wherein the first electrode is electrically connected to a positive electrode of the external power supply through a fifth switching element and electrically connected to a negative electrode of the external power supply through a sixth switching element,
the second electrode is electrically connected to the positive electrode of the external power supply through a seventh switching element,
the third electrode is electrically connected to the negative electrode of the external power supply through an eighth switching element,
the power demand unit is electrically connected to the solar cell through a ninth switching element, and
the switching element controller controls on/off of the filth switching element to the ninth switching element.

10. A chemical reaction system comprising:
a solar cell;
an external power source;
an electrolytic tank having a first tank and a second tank, the first tank and the second tank separated by a permeable membrane;
a first electrode set in the first tank, electrically connected to a positive electrode of the solar cell through a first switching element, electrically connected to a negative electrode of the solar cell through a second switching element, electrically connected to a positive electrode of the external power source through a third switching element, and electrically connected to a negative electrode of the external power source through a fourth switching element;
a second electrode set in the second tank, electrically connected to the positive electrode of the solar cell through a fifth switching element, electrically connected to a positive electrode of the external power source through a seventh switching element, and not directly connected to the negative electrode of the solar cell or the negative electrode of the external power source;
a third electrode set in the second tank, electrically connected to the negative electrode of the solar cell through a sixth switching element and electrically connected to a negative electrode of the external power source through a eighth switching element, and not directly connected to the positive electrode of the solar cell or the positive electrode of the external power source;
a power demand unit electrically connected to the solar cell through a ninth switching element; and
a switching element controller which controls on/off of the first switching element to the ninth switching element, wherein
the switching element controller controls connection of the first switching element to the ninth switching element based on one or more conditions including presence or absence of surplus power and presence or absence of solar energy.

11. The chemical reaction system of claim 10 , wherein
the electrolytic tank has the first tank to store a first solution comprising an oxidant and/or reductant of a redox medium and the second tank to store a second solution comprising water and/or proton.

12. The chemical reaction system of claim 10 , wherein the switching element controller is configured to keep the third, fourth, seventh, eighth and ninth switching elements off and to control turning on and off of the first, second, fifth and sixth switching elements, so that the chemical reaction system functions as an external power electrolysis system.

13. The chemical reaction system of claim 10 , wherein the switching element controller is configured to keep the fir

Assignees

• Toshiba Kk

Inventors

• Ono Akihiko
• Mikoshiba Satoshi
• Kudo Yuki
• Kitagawa Ryota
• Tamura Jun
• Huang Chingchun

Classifications

• C25B15/02

  Process control or regulation · CPC title

• H01G9/2013

  the electrolyte comprising ionic liquids, e.g. alkyl imidazolium iodide · CPC title

• C25B13/04 Primary

  characterised by the material · CPC title

• C25B1/003 Primary

  Chemistry & Metallurgy · mapped topic

• Y02E70/10

  Cross-Sectional Technologies · mapped topic