Lubricant compositions for direct injection engines

Patent metadata

Field	Value
Publication number	US-10494584-B2
Application number	US-201415022345-A
Country	US
Kind code	B2
Filing date	Sep 19, 2014
Priority date	Sep 19, 2013
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

The invention is directed to a method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine by supplying to the sump a lubricant composition which contains an oil of lubricating viscosity and a metal overbased detergent. The metal overbased detergent may be selected from sulfonate detergents, phenate detergents, and salicylate detergents, especially sulfonate detergents with a metal ratio of at least 5.

First claim

What is claimed:

1. A method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine wherein the engine is equipped with a turbocharger and is operated under a load with a brake mean effective pressure (BMEP) of greater than or equal to 12 bars at speeds less than or equal to 3,000 rpm, comprising supplying to the engine a lubricant composition comprising:
(a) a base oil of lubricating viscosity;
(b) a magnesium sulfonate overbased detergent in an amount to provide at least 500 ppm magnesium from the magnesium sulfonate overbased detergent to the lubricating composition;
(c) a calcium sulfonate overbased detergent in an amount to provide at least 1,000 ppm of calcium from the calcium sulfonate overbased detergent to the lubricating composition;
(d) 0.5 to 0.9 wt. % of a zinc dialkyldithiophosphate anti-wear additive; and
(e) 0.5 to 15 weight percent of one or more additional additives;

wherein the magnesium sulfonate overbased detergent and the calcium sulfonate overbased detergent collectively contribute up to about 0.8 weight percent of sulfated ash to the lubricating composition and wherein the lubricating composition has a phosphorus content of 0.12 wt. % or less and total sulfated ash of 1.1% or less.

2. The method of claim 1 , wherein the engine is fueled with a liquid hydrocarbon fuel, a liquid nonhydrocarbon fuel, or mixtures thereof.

3. The method of claim 2 , wherein the engine is fueled by natural gas, liquefied petroleum gas (LPG), compressed natural gas (CNG), or mixtures thereof.

4. The method of claim 1 , wherein the one or more additional additives is selected from an ashless dispersant, an ashless antioxidant, a friction modifier, and a polymeric viscosity modifier.

5. The method of claim 1 , wherein the magnesium overbased detergent has a metal ratio of 5 to 30.

6. The method of claim 1 , wherein the magnesium overbased detergent is present in an amount from 0.2 to 8 weight percent of the lubricant composition.

7. The method of claim 1 , wherein the one or more additional additives is a polyalkenyl succinimide dispersant in an amount from 0.5 to 4 weight % of the lubricating composition.

8. The method of claim 1 , wherein the base oil comprises at least 50 weight % of a Group II base oil, a Group III base oil, or mixtures thereof.

9. The method of claim 1 , wherein there is a reduction in the number of LSPI events of at least 10 percent.

10. The method of claim 1 , wherein the low speed pre-ignition events are reduced to less than 20 LSPI events per 100,000 combustion events.

Assignees

• Lubrizol Corp

Inventors

• Mosier Patrick E
• Dietz Jeffry G
• Sammut Alexander

Classifications

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2030/04

  Detergent property or dispersant property · CPC title

• C10N2010/12

  Groups 6 or 16 · CPC title

• C10N2010/04

  Groups 2 or 12 · CPC title