Method for producing silica aerogel and silica aerogel produced thereby

Patent metadata

Field	Value
Publication number	US-10494265-B2
Application number	US-201715768999-A
Country	US
Kind code	B2
Filing date	Sep 6, 2017
Priority date	Sep 12, 2016
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

The present invention relates to a method for producing a silica aerogel and a silica aerogel produced thereby. More specifically, a first water glass solution is used to form a first silica wet gel, and then a second water glass solution is additionally added to form a second silica wet gel organically bonded to the first silica wet gel which serves as a basic skeleton, so that a silica aerogel with enhanced physical properties is formed to increase the resistance to shrinkage in ambient drying, and the concentration of silicon dioxide in each of the first and second water glass solutions is controlled, thereby providing a method for producing a silica aerogel by which a silica aerogel having a specific tap density and controllable density can be produced, and also providing a silicon aerogel produced by the method.

First claim

The invention claimed is:

1. A method for producing a silica aerogel, comprising:
1) adding a first water glass solution and an acid catalyst to a reactor to form a first silica wet gel;
2) adding a second water glass solution and an acid catalyst to the first silica wet gel;
3) adding a surface modifier solution to the first silica wet gel to form a second silica wet gel; and
4) drying a silica wet gel including the first silica wet gel and the second silica wet gel,
wherein the concentration of silicon dioxide in the first water glass solution is 3.5 to 8.5 wt %, and the concentration of silicon dioxide in the second water glass solution is 0.5 to 3.5 wt %.

2. The method of claim 1 , wherein the concentration ratio of the silicon dioxide in the first water glass solution to the silicon dioxide in the second water glass solution is 1:1 to 10:1.

3. The method of claim 1 , wherein the silica aerogel has a tap density of 0.03 to 0.10 g/ml.

4. The method of claim 1 , wherein the acid catalyst is at least one selected from the group consisting of hydrochloric acid, nitric acid, acetic acid, sulfuric acid and hydrofluoric acid.

5. The method of claim 1 , further comprising, after step 1), aging and pulverizing the first wet gel.

6. The method of claim 1 , wherein the surface modifier solution is a solution in which a surface modifier is added to a nonpolar organic solvent.

7. The method of claim 1 , wherein the surface modifier is at least one selected from the group consisting of trimethylchlorosilane (TMCS), hexamethyldisilazane (HMDS), methyltrimethoxysilane, trimethylethoxysilane, ethyltriethoxysilane, and phenyltriethoxysilane.

8. The method of claim 1 , wherein the nonpolar organic solvent is at least one selected from the group consisting of hexane, heptane, toluene, and xylene.

9. The method of claim 1 , wherein the surface modifier solution is added in an amount such that a molar ratio of a surface modifier to the silicon dioxide in the first water glass solution becomes 0.05 to 20.

10. The method of claim 1 , wherein gelation, solvent exchange, and surface modification are simultaneously performed in step 3).

11. The method of claim 1 , wherein the second silica wet gel is organically bonded to the first silica wet gel which serves as a basic skeleton.

12. The method of claim 1 further comprising, during step 3), a step of adding ammonium hydroxide (NH 4 OH).

13. The method of claim 12 , wherein the ammonium hydroxide is added in an amount such that a molar ratio of the ammonium hydroxide to the silicon dioxide in the first water glass solution becomes 0.5 to 25.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Young Hun
• Lee Je Kyun

Classifications

• C01B33/157

  After-treatment of gels · CPC title

• C01B33/158

  Purification; Drying; Dehydrating · CPC title

• C01B33/16

  Preparation of silica xerogels · CPC title

• C01B33/1585 Primary

  Dehydration into aerogels · CPC title

• C01B33/325

  After-treatment, e.g. purification or stabilisation of solutions, granulation; Dissolution; Obtaining solid silicate, e.g. from a solution by spray-drying, flashing off water or adding a coagulant · CPC title