Catalyst deterioration diagnosis system and catalyst deterioration diagnosis method
US-2016161370-A1 · Jun 9, 2016 · US
US10494256B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10494256-B2 |
| Application number | US-201715635756-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 28, 2017 |
| Priority date | Jul 4, 2016 |
| Publication date | Dec 3, 2019 |
| Grant date | Dec 3, 2019 |
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A burner combustion chamber ( 3 ), a reformer catalyst ( 4 ) to which burner combustion gas is fed, and a heat exchange part ( 13 a ) for heating the air fed to the burner ( 7 ) are provided. When the temperature of the reformer catalyst ( 4 ) exceeds the allowable catalyst temperature (TX) or when it is predicted the temperature of the reformer catalyst ( 4 ) will exceed the allowable catalyst temperature (TX), the air circulation route for guiding air to the burner ( 7 ) is switched from a high temperature air circulation route ( 13 ) for guiding air heated by the heat exchange part ( 13 a ) to the burner ( 7 ) to a low temperature air circulation route ( 14 ) for guiding air not flowing within the heat exchange part ( 13 a ) and lower in temperature than the air heated at the heat exchange part ( 13 a ) to the burner ( 7 ).
Opening claim text (preview).
The invention claimed is: 1. A heat and hydrogen generation device comprising: a burner combustion chamber; a burner arranged in the burner combustion chamber for performing burner combustion; a fuel feed device able to control an amount of feed of fuel fed from the burner into the burner combustion chamber; an air feed device able to control a temperature and amount of feed of air fed from the burner into the burner combustion chamber; an ignition device for causing the fuel to ignite, a reformer catalyst to which burner combustion gas is fed; and an electronic control unit, wherein said air feed device is provided with a heat exchange part for heating the air fed from the burner into the burner combustion chamber by the burner combustion gas, heat and hydrogen being generated by performing the burner combustion, wherein an allowable catalyst temperature enabling heat degradation of said reformer catalyst to be avoided is set in advance, said electronic control unit is programmed to control said air feed device to lower the temperature of the air fed from said burner into the burner combustion chamber for maintaining the temperature of the reformer catalyst at below the allowable catalyst temperature when the burner combustion is being performed and when the temperature of said reformer catalyst exceeds said allowable catalyst temperature or it is predicted that the temperature of said reformer catalyst will exceed said allowable catalyst temperature, and when the heat and hydrogen generation device starts to be operated, said electronic control unit is programmed to perform a primary warm-up operation in which the temperature of the reformer catalyst is made to rise by performing burner combustion by a lean air-fuel ratio, and then perform a secondary warm-up operation in which the temperature of the reformer catalyst is made to rise and hydrogen is generated at the reformer catalyst by performing burner combustion by a rich air-fuel ratio. 2. The heat and hydrogen generation device as claimed in claim 1 , wherein said electronic control unit is programmed to lower the temperature of the air fed from said burner into the burner combustion chamber by stopping the feed of air heated at said heat exchange part into the burner combustion chamber and feeding air of a lower temperature than the air heated at said heat exchange part from said burner into said burner combustion chamber. 3. The heat and hydrogen generation device as claimed in claim 2 , wherein said heat and hydrogen generation device further comprises a switching device for switching an air flow route for feeding air from said burner into said burner combustion chamber between a high temperature air flow route for feeding air heated at said heat exchange part and a low temperature air flow route for feeding air lower in temperature than the air heated at said heat exchange part, and said electronic control unit is programmed to switch the air flow route for feeding air from said burner into said burner combustion chamber from said high temperature air flow route to said low temperature air flow route when lowering the temperature of the air fed into said burner combustion chamber. 4. The heat and hydrogen generation device as claimed in claim 1 , wherein said electronic control unit is programmed to determine that the temperature of the reformer catalyst will exceed said allowable catalyst temperature when the primary warm-up operation is switched to the secondary warm-up operation and thereby lower the temperature of the air fed from said burner into said burner combustion chamber. 5. The heat and hydrogen generation device as claimed in claim 1 , wherein at the time of said primary warm-up operation, the O 2 /C molar ratio of the air and fuel which are made to react is made 2.0 to 4.0. 6. The heat and hydrogen generation device as claimed in claim 1 , wherein at the time of said secondary warm-up operation, the O 2 /C molar ratio of the air and fuel which are made to react is made 0.5 to 0.56. 7. The heat and hydrogen generation device as claimed in claim 1 , wherein said electronic control unit is programmed to switch to said secondary warm-up operation if the temperature of said reformer catalyst exceeds a predetermined temperature when said primary warm-up operation is being performed. 8. The heat and hydrogen generation device as claimed in claim 1 , wherein said electronic control unit is programmed to switch to said secondary warm-up operation if the temperature of the air flowing out from the heat exchange part exceeds a predetermined temperature when said primary warm-up operation is being performed. 9. The heat and hydrogen generation device as claimed in claim 1 , wherein said electronic control unit is programmed to switch an operating mode of the heat and hydrogen generation device to either a heat generating operating mode generating heat by performing a complete oxidation reaction by a lean air-fuel ratio and a heat and hydrogen generating operating mode generating heat and hydrogen by performing a partial oxidation reforming reaction by a rich air-fuel ratio.
Controlling the temperature · CPC title
containing a catalytic partial oxidation step [CPO] · CPC title
by combustion of fuel · CPC title
by indirect heat exchange · CPC title
Controlling the temperature of the process · CPC title
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