Image forming method and ink set

Patent metadata

Field	Value
Publication number	US-10493775-B2
Application number	US-201816159874-A
Country	US
Kind code	B2
Filing date	Oct 15, 2018
Priority date	Oct 16, 2017
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

There is provided an image forming method for forming an image on a recording medium which is fabric or recording paper by using an ink set including an ink and a treatment agent. In a case that the recording medium is the fabric, the image forming method includes: applying the treatment agent, which includes a cationic substance and a water-soluble organic solvent, to the fabric in an application amount of the treatment agent per an area of the fabric in a range of 4.7 mg/cm2 to 34 mg/cm2; drying the applied treatment agent and thereby reducing weight of the treatment agent in the fabric to be not more than 50% of the application amount of the treatment agent; and jetting the ink, which includes an anionic dye and a water-soluble organic solvent, onto the fabric by an ink-jet system.

First claim

What is claimed is:

1. An image forming method for forming an image on a recording medium which is a fabric or a recording paper by using an ink set including an ink and a treatment agent,
in a case that the recording medium is the fabric, the image forming method comprising:
applying the treatment agent, which includes a cationic substance and a water-soluble organic solvent, to the fabric in an application amount of the treatment agent per an area of the fabric in a range of 4.7 mg/cm 2 to 34 mg/cm 2 ;
drying the applied treatment agent and thereby reducing weight of the treatment agent in the fabric to be not more than 50% of the application amount of the treatment agent; and
jetting the ink, which includes an anionic dye and a water-soluble organic solvent, onto the fabric by an ink-jet system,

wherein the ink and the treatment agent satisfy the following expression (1):
(0.2× A 1)+(0.8× A 2)<25  (1)

in the expression (1),
A1: a blending amount (% by weight) of a water-soluble organic solvent, of which boiling point is not less than 230° C., in an entire amount of the ink, and
A2: a blending amount (% by weight) of a water-soluble organic solvent, of which boiling point is not less than 230° C., in an entire amount of the treatment agent.

2. The image forming method according to claim 1 , wherein in the drying of the applied treatment agent, the weight of the treatment agent in the fabric is reduced to be not more than 30% of the application amount of the treatment agent.

3. The image forming method according to claim 1 , wherein the ink and the treatment agent satisfy the following expression (2):
(0.2× A 1)+(0.8× A 2)<18  (2)

in the expression (2),
A1: the blending amount (% by weight) of the water-soluble organic solvent, of which boiling point is not less than 230° C., in the entire amount of the ink, and
A2: the blending amount (% by weight) of the water-soluble organic solvent, of which boiling point is not less than 230° C., in the entire amount of the treatment agent.

4. The image forming method according to claim 1 , wherein in the drying of the applied treatment agent, a drying temperature is in a range of 130° C. to 220° C.

5. The image forming method according to claim 1 , wherein the applying of the treatment agent, the drying of the applied treatment agent and the jetting of the ink are performed in this order.

6. The image forming method according to claim 1 , further comprising washing the fabric with water, wherein
the applying of the treatment agent, the drying of the applied treatment agent, the jetting of the ink, and the washing of the fabric are performed in this order.

7. The image forming method according to claim 1 , in a case that the recording medium is the recording paper, the image forming method comprising:
applying the treatment agent to the recording paper; and
jetting the ink onto the recording paper by the ink-jet system.

8. The image forming method according to claim 1 , in a case that the recording medium is the recording paper, the image forming method comprising jetting the ink onto the recording paper by the ink-jet system without applying the treatment agent to the recording paper.

9. The image forming method according to claim 1 , further comprising determining which one among a first printing mode, a second printing mode and a third printing mode is to be performed,
wherein in the first printing mode, the recording medium is the fabric, and the image forming method comprises the applying of the treatment agent, the drying of the applied treatment agent, and the jetting of the ink;
in the second printing mode, the recording medium is the recording paper, and the image forming method comprises jetting the ink onto the recording paper by the ink-jet system, without applying the treatment agent to the recording paper; and
in the third printing mode, the recording medium is the recording paper, and the image forming method comprises applying the treatment agent to the recording paper, and jetting the ink onto the recording paper by the ink-jet system.

10. An ink set comprising:
an ink including an anionic dye and a water-soluble organic solvent; and
a treatment agent including a cationic substance and a water-soluble organic solvent,
wherein the ink and the treatment agent satisfy the following expression (1):
(0.2× A 1)+(0.8× A 2)<25  (1)

in the expression (1),
A1: a blending amount (% by weight) of a water-soluble organic solvent, of which boiling point is not less than 230° C., in an entire amount of the ink, and
A2: a blending amount (% by weight) of a water-soluble organic solvent, of which boiling point is not less than 230° C., in an entire amount of the treatment agent.

11. The ink set according to claim 10 , wherein a blending amount of a water-soluble organic solvent, of which boiling point is in a range of not less than 130° C. and less than 230° C., is not more than 50% by weight in the entire amount of the treatment agent.

12. The ink set according to claim 11 , wherein the blending amount of the water-soluble organic solvent, of which boiling point is in the range of not less than 130° C. and less than 230° C., is in a range of 5% by weight to 40% by weight in the entire amount of the treatment agent.

13. The ink set according to claim 11 , wherein the water-soluble organic solvent, which is included in the treatment agent and of which boiling point is in the range of not less than 130° C. and less than 230° C., is at least one of alkylene glycol and trimethylol alkyl.

14. The ink set according to claim 10 , wherein the water-soluble organic solvent included in the treatment agent includes a penetrant.

15. The ink set according to claim 14 , wherein a blending amount of the penetrant in the entire amount of the treatment agent is in a range of 0.4% by weight to 10% by weight.

16. The ink set according to claim 10 , wherein the treatment agent further includes a surfactant which is different from a cationic surfactant.

17. The ink set according to claim 16 , wherein the surfactant which is included in the treatment agent and which is different from the cationic surfactant is an acetylenic glycol-based nonionic surfactant represented by the following formula (S):

in the formula (S),
each of R 11 to R 14 is an alkyl group having 1 to 5 carbon atoms, and R 11 to R 14 are identical with one another or different from one another;
m and n are identical with each other or different from each other and are numbers, respectively, satisfying: m+n=1 to 15; and
the alkyl group of each of R 11 to R 14 has a straight chain or a branched chain.

18. The ink set according to claim 16 , wherein a blending amount of the surfactant which is different from the cationic surfactant is in a range of 0.2% by weight to 2% by weight in the entire amount of the treatment agent.

19. The ink set according to claim 10 , wherein the cationic substance is a cationic polymer including a urethane structure.

20. The ink set according to claim 10 , wherein the anionic dye is at least one selected from the group consisting of: a yellow dye, a magenta dye and a cyan dye;
the yellow dye is an azo dye;
the magenta dye is at least one of an azo dye and an anthrapyridone dye; and
the cyan dye is a phthalocyanine dye.

Assignees

• Brother Ind Ltd

Inventors

• Ito Shinpei
• Taga Yasuhiro
• Yuhara Keisuke
• Maeda Mitsunori

Classifications

• D06P5/225

  Aminalization of cellulose; introducing aminogroups into cellulose · CPC title

• D06P1/65118

  Compounds containing hydroxyl groups · CPC title

• B41J2/21

  for multi-colour printing · CPC title

• C09D11/54

  Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink · CPC title

• B41J3/4078 Primary

  Printing on textile · CPC title