Graphene-metal chalcogenide porous material

Patent metadata

Field	Value
Publication number	US-10493426-B2
Application number	US-201515112355-A
Country	US
Kind code	B2
Filing date	Jan 9, 2015
Priority date	Jan 27, 2014
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

A method of preparing a graphene-metal chalcogenide porous material is provided. The method includes providing a dispersion comprising graphene oxide; adding a metal precursor and a chalcogenide precursor to the dispersion to form a mixture; heating the mixture under hydrothermal conditions to form a gel; and freeze drying the gel to obtain the graphene-metal chalcogenide porous material. A graphene-metal chalcogenide porous material prepared by the method, and use of the material in water treatment, energy storage, fire proofing, batteries or supercapacitors are also provided.

First claim

The invention claimed is:

1. A method of preparing a graphene-metal chalcogenide porous material, the method comprising
a) providing a dispersion comprising graphene oxide;
b) adding a metal precursor and a chalcogenide precursor to the dispersion to form a mixture;
c) heating the mixture under hydrothermal conditions to form a gel; and
d) freeze drying the gel to obtain the graphene-metal chalcogenide porous material,
wherein a weight ratio of metal chalcogenide to graphene in the graphene-metal chalcogenide material is in the range of about 700 wt % to about 900 wt %.

2. The method according to claim 1 , wherein the metal precursor is a precursor of a metal selected from Group 4 to Group 6 of the Periodic Table of Elements.

3. The method according to claim 1 , wherein the metal precursor is a precursor of a metal selected from the group consisting of Mo, Ta, Ti, W, and combinations thereof.

4. The method according to claim 1 , wherein the metal precursor is selected from the group consisting of a molybdate, a tantalate, a titanate, a tungstate, and combinations thereof.

5. The method according to claim 1 , wherein the metal precursor comprises an alkali metal molybdate salt.

6. The method according to claim 1 , wherein the metal precursor comprises sodium molybdate dehydrate.

7. The method according to claim 1 , wherein the chalcogenide precursor is selected from the group consisting of a thioamide, a selenoamide, a tellurium amide, and combinations thereof.

8. The method according to claim 1 , wherein the chalcogenide precursor comprises thioacetamide.

9. The method according to claim 1 , wherein heating the mixture under hydrothermal conditions comprises heating the mixture in a closed vessel at a temperature in the range of about 150° C. to about 250° C.

10. The method according to claim 1 , wherein heating the mixture under hydrothermal conditions comprises heating the mixture in a closed vessel for a time period in the range of about 12 h to about 48 h.

11. The method according to claim 1 , wherein freeze drying the gel is carried out at a temperature in the range of about −50° C. to about 0° C.

12. The method according to claim 1 , wherein freeze drying the gel is carried out for a time period in the range of about 24 h to about 56 h.

13. The method according to claim 1 , wherein the metal chalcogenide comprises a metal dichalcogenide.

14. The method according to claim 1 , wherein the metal chalcogenide is selected from the group consisting of MoS 2 , MoSe 2 ,TaS 2 , TiS 2 , WS 2 , and combinations thereof.

15. The method according to claim 1 , wherein the metal chalcogenide is negatively charged.

16. The method according to claim 1 , wherein adding the metal precursor and the chalcogenide precursor to the dispersion to form a mixture comprises adding at least one of metal particles or metal oxide particles to the dispersion.

17. The method according to claim 16 , wherein the metal particles are selected from the group consisting of gold particles, silver particles, copper particles, and combinations thereof.

18. The method according to claim 16 , wherein the metal oxide particles are selected from the group consisting of nickel oxide particles, manganese oxide particles, iron oxide particles, zinc oxide particles, and combinations thereof.

19. The method according to claim 1 , wherein porosity of the graphene-metal chalcogenide porous material is in the range of about 99.5% to about 99.9%.

Assignees

• Univ Nanyang Tech

Inventors

• Zhang Hua
• Bi Hengchang
• Chen Bo
• Ma Qinglang

Classifications

• C09K21/06

  Organic materials · CPC title

• C01G23/007

  Titanium sulfides (C01G23/001 takes precedence) · CPC title

• B01J20/205

  Carbon nanostructures, e.g. nanotubes, nanohorns, nanocones, nanoballs (carbon nanotubes per se C01B32/15) · CPC title

• B01J20/0285

  Sulfides of compounds other than those provided for in B01J20/045 · CPC title

• B01J20/0262

  Compounds of O, S, Se, Te · CPC title