Column for thermal treatment of fluid mixtures

Patent metadata

Field	Value
Publication number	US-10493376-B2
Application number	US-201615382073-A
Country	US
Kind code	B2
Filing date	Dec 16, 2016
Priority date	Dec 18, 2015
Publication date	Dec 3, 2019
Grant date	Dec 3, 2019

Abstract

The present invention relates to a column (1) for thermal treatment of fluid mixtures, having a cylindrical, vertically aligned column body (2) which forms a column cavity (3), having a sequence of vertically spaced-apart dual-flow mass transfer trays (8) which are mounted in the column cavity (3) and which have orifices for passage of liquid and gas in countercurrent, and having at least one gas entry orifice (5) disposed below the lowermost of the sequence of dual-flow mass transfer trays (8). It is a characteristic feature of the column of the invention that a gas distribution tray (9) which is disposed between the lowermost of the sequence of dual-flow mass transfer trays (8) and the gas entry orifice (5) has orifices (32) for vertical passage of gas which can be introduced into the column cavity (3) via the gas entry orifice (5), the orifices (32) being formed so as to bring about equal gas distribution over the column cross section. The invention further relates to a process for thermal treatment of fluid mixtures in such a column (1).

First claim

The invention claimed is:

1. A column for thermal treatment of fluid mixtures, comprising:
a cylindrical, vertically aligned column body which forms a column cavity;
a sequence of vertically spaced-apart dual-flow trickle sieve trays which are mounted in the column cavity and which have orifices for passage of liquid and gas in countercurrent;
a gas distribution tray disposed below the lowermost of the sequence of dual-flow trickle sieve trays; and
at least one gas entry orifice disposed below the gas distribution tray;
wherein
the gas distribution tray has orifices for vertical passage of gas introduced into the column cavity via the at least one gas entry orifice and a liquid draw for passage of liquid below the gas distribution tray,
the orifices for vertical passage of gas are arranged in homogeneous distribution over the cross section of the gas distribution tray,
a pressure drop obtained by the orifices of the gas distribution tray is 6 to 10 times the dynamic pressure of the gas at the at least one gas entry orifice, and
a ratio of the orifice area of the orifices of the lowermost of the sequence of dual-flow trickle sieve trays relative to an inner cross-sectional area of the column is at least 1.13 times larger than a ratio of the orifice area of the orifices of the gas distribution tray to the inner cross-sectional area of the column,
so as to obtain equal gas distribution over the column cross section of the gas introduced into the column through the at least one gas entry orifice.

2. The column according to claim 1 , wherein the gas distribution tray has 0.2 to 1 orifice per square meter.

3. The column according to claim 1 , wherein the proportion of the orifice area formed by the orifices of the gas distribution tray relative to the inner cross-sectional area of the column is within a range from 10% to 20%.

4. The column according to claim 1 , wherein the pressure drop of the gas distribution tray is at least 20% of the pressure drop of the lowermost dual-flow trickle sieve tray of the sequence of dual-flow trickle sieve trays.

5. The column according to claim 1 , wherein the proportion of the orifice area formed by the orifices of at least of the lowermost of the sequence of dual-flow trickle sieve trays relative to the inner cross-sectional area of the column is within a range from 14% to 20%.

6. The column according to claim 1 , wherein the at least one gas entry orifice in the column is aligned such that gas entering the column cavity forms a horizontal vortex.

7. The column according to claim 1 , wherein the liquid draw disposed above the gas distribution tray or in the gas distribution tray has an inlet for liquid from an upper collecting area of the gas distribution tray and an outlet in a region beneath the gas distribution tray.

8. The column according to claim 7 , wherein a collecting tank for the liquid flowing through the liquid draw disposed between the inlet and the outlet of the liquid draw is arranged such that the liquid collecting in the collecting tank provides a hydraulic seal.

9. The column according to claim 8 , wherein the liquid draw comprises a pipe in siphon form which forms the collecting tank.

10. The column according to claim 7 , wherein the inlet of the liquid draw comprises an orifice in the upper collecting area of the gas distribution tray, from which a drainpipe extends downward, and wherein a collecting tank is a collecting cup disposed beneath the lower orifice of the drainpipe, the drainpipe passing through an area of the collecting cup which is formed by the upper edge of the collecting cup, and the upper edge of the collecting cup being disposed above the lower edge of the lower orifice of the drainpipe, such that liquid collecting in the collecting cup forms the hydraulic seal.

11. The column according to claim 1 , wherein the gas distribution tray is a chimney tray comprising a chimney having a covering hood.

12. A process for thermal treatment of fluid mixtures in a column according to claim 1 , comprising:
introducing liquid into an upper region of the column wherein the liquid descends within the column and
introducing gas into the column cavity through the at least one gas entry orifice wherein the gas flows upward through the orifices of the gas distribution tray, giving rise to a pressure drop,
the orifices being formed so as to bring about equal gas distribution over the column cross section.

13. The process according to claim 12 , wherein the ascending gas and/or the descending liquid comprises (meth)acrylic monomers.

Assignees

• Basf Se

Inventors

• Hammon Ulrich
• Walter Thomas

Classifications

• C07C51/44

  by distillation · CPC title

• B01D3/26

  Fractionating columns in which vapour and liquid flow past each other, or in which the fluid is sprayed into the vapour, or in which a two-phase mixture is passed in one direction · CPC title

• B01D3/225

  Dual-flow sieve trays · CPC title

• B01D3/20

  Bubble caps; Risers for vapour; Discharge pipes for liquid · CPC title

• C07C67/52

  by change in the physical state, e.g. crystallisation · CPC title