Temperature profile for rock sample composition analysis

Patent metadata

Field	Value
Publication number	US-10488327-B2
Application number	US-201715663572-A
Country	US
Kind code	B2
Filing date	Jul 28, 2017
Priority date	Jul 29, 2016
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

A method for analyzing the petroleum content of a rock sample includes at least three repetitions of heating a rock sample to a holding temperature, holding the rock sample at the holding temperature for a holding period, and collecting data about the rock sample during each holding period. The holding temperature for each subsequent holding period may be greater than or equal to a previous holding temperature. The data collected may be analyzed to determine the S1 parameter and calculated to determine the API gravity of the rock sample.

First claim

What is claimed is:

1. A method for analyzing a free petroleum content reservoired within a rock sample to enable a more accurate and available testing of petroleum quality for oil exploration and acquisition, comprising:
heating the rock sample from a base temperature of about ambient or room temperature to a first holding temperature, the first holding temperature being less than 350° C.;
holding the rock sample at the first holding temperature for a first holding period;
heating the rock sample to a second holding temperature, the second holding temperature being greater than the first holding temperature;
holding the rock sample at the second holding temperature for a second holding period;
heating the rock sample to a third holding temperature, the third holding temperature being greater than the second holding temperature and no more than 350° C.;
holding the rock sample at the third holding temperature for a third holding period;
collecting data on properties of gases released from the rock sample during the first holding period, the second holding period and the third holding period through at least one of pyrolysis, gas chromatography, or mass spectrometry; and
determining the free petroleum content of the rock sample based on the collected data, the determined free petroleum content of the rock sample enabling a more accurate and available testing of petroleum quality for oil exploration and acquisition.

2. The method of claim 1 , the method further comprising analyzing the rock sample using Fourier transform infrared spectroscopy prior to heating the rock sample from the base temperature to the first holding temperature and after the third holding period.

3. The method of claim 1 , wherein the rock sample has a free hydrocarbon content, and the third holding temperature corresponds with a temperature required to determine the free hydrocarbon content.

4. The method of claim 1 , wherein holding the rock sample at the first holding temperature, holding the rock sample at the second holding temperature, and holding the rock sample at the third holding temperature includes holding a temperature of the rock sample within plus or minus 1° C. during the first holding period, the second holding period and the third holding period, respectively.

5. The method of claim 1 , wherein a first difference in temperature between the base temperature and the first holding temperature, a second difference in temperature between the first holding temperature and the second holding temperature, and a third difference in temperature between the second holding temperature and the third holding temperature are about the same.

6. The method of claim 1 , wherein a first difference in temperature between the base temperature and the first holding temperature, a second difference in temperature between the first holding temperature and the second holding temperature, and a third difference in temperature between the second holding temperature and the third holding temperature are each at least 10° C.

7. The method of claim 1 , wherein the heating of the rock sample from the base temperature to the first holding temperature, heating of the rock sample from the first holding temperature to the second holding temperature, and heating of the rock sample the second holding temperature to the third holding temperature occurs at a rate of between 50° C. and 200° C. per minute.

8. The method of claim 1 , wherein the first holding period, the second holding period, and the third holding period are between three and seven minutes.

9. The method of claim 1 , wherein the first holding period, the second holding period, and the third holding period are the same.

10. The method of claim 1 , wherein the rock sample is heated in a closed system.

11. The method of claim 1 , wherein the rock sample is heated in an inert environment.

12. A method for analyzing a free petroleum content reservoired within a rock sample to enable a more accurate and available testing of petroleum quality for oil exploration and acquisition, comprising:
analyzing the rock sample using Fourier transform infrared spectroscopy;
heating the rock sample from a base temperature of about ambient or room temperature to a first holding temperature less than 350° C. after analyzing the rock sample using Fourier transform infrared spectroscopy;
holding the rock sample at the first holding temperature for a first holding period;
heating the rock sample to a second holding temperature, the second holding temperature being greater than the first holding temperature;
holding the rock sample at the second holding temperature for a second holding period;
heating the rock sample to a third holding temperature, the third holding temperature being greater than the second holding temperature and no more than 350° C.;
holding the rock sample at the third holding temperature for a third holding period;
collecting data on properties of gases released from the rock sample during the first holding period, the second holding period, and the third holding period through at least one of pyrolysis, gas chromatography, and mass spectrometry;
analyzing the rock sample using Fourier transform infrared spectroscopy after the third holding period and while the rock sample is at a temperature no more than 350° C.;
heating the rock sample to a fourth holding temperature, the fourth holding temperature being greater than the third holding temperature and no more than 800° C.; and
determining the free petroleum content of the rock sample based at least on data collected from the properties of gases released from the rock sample during the first holding period, the second holding period, and the third holding period, from analyzing the rock sample using Fourier transform infrared spectroscopy prior to heating the rock from the base temperature to the first holding temperature, and from analyzing the rock sample using Fourier transform infrared spectroscopy after the third holding period,
wherein the determined free petroleum content of the rock sample enables a more accurate and available testing of petroleum quality for oil exploration and acquisition.

13. The method of claim 12 , wherein the fourth holding temperature corresponds to the temperature at which hydrocarbons stop decomposing.

14. The method of claim 12 , wherein holding the rock sample at the first holding temperature, holding the rock sample at the second holding temperature, and holding the rock sample at the third holding temperature includes holding a temperature of the rock sample of plus or minus 1° C. during the first holding period, the second holding period and the third holding period, respectively.

15. The method of claim 12 , wherein a first difference in temperature between the base temperature and the first holding temperature, a second difference in temperature between the first holding temperature and the second holding temperature, and a third difference in temperature between the second holding temperature and the third holding temperature are about the same.

16. The method of claim 12 , wherein the first holding period, the second holding period, and the third holding period have a duration between three and seven minutes.

17. A computing system comprising:
one or more processors; and
one or more computer readable media having stored thereon computer-executable instructions that when executed by the one or more processors configure the computing system to perform at least the following:
receive data from an analysis of the rock sample using Fourier transform infrared spectro

Assignees

• Univ Utah Res Found

Inventors

• Thul David J
• Beti Dhrupad Raghuveer

Classifications

• G01N30/02

  Column chromatography · CPC title

• G06F17/14

  Fourier, Walsh or analogous domain transformations {, e.g. Laplace, Hilbert, Karhunen-Loeve, transforms (for correlation function computation G06F17/156; spectrum analysers G01R23/16)} · CPC title

• G01N1/44

  Sample treatment involving radiation, e.g. heat · CPC title

• G01N1/28

  Preparing specimens for investigation {including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q}(mounting specimens on microscopic slides G02B21/34; means for supporting the objects or the materials to be analysed in electron microscopes H01J37/20 {; laboratory gas handling apparatus B01L5/00}) · CPC title

• G01N2030/8854

  involving hydrocarbons · CPC title