Lubricating oil compositions and methods of use thereof

Patent metadata

Field	Value
Publication number	US-10487289-B2
Application number	US-201815880946-A
Country	US
Kind code	B2
Filing date	Jan 26, 2018
Priority date	Feb 21, 2017
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

A method for improving oxidation stability and viscosity control, while maintaining or improving cleanliness performance and deposit control, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and a mixture of (i) at least one detergent, and (ii) at least one antioxidant, or a mixture of (i) at least one detergent, (ii) at least one dispersant, and (iii) at least one antioxidant, as minor components. The at least one detergent comprises a sulfonate detergent, the at least one dispersant comprises a borated dispersant, and the at least one antioxidant includes an alkylated diphenylamine. The engine or other mechanical component is lubricated with the lubricating oil operating in the presence of biodiesel fuel. A lubricating oil formulated with the above major and minor components.

First claim

The invention claimed is:

1. A method for improving oxidation stability and viscosity control, while maintaining or improving cleanliness performance and deposit control, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil, said formulated oil having a composition comprising a lubricating oil base stock at from about 81.0 wt. % to 93.1 wt. % of the lubricating oil comprising a blend of a Group III base stock, a Group IV base stock and about 5 wt % of a Group V base stock; and a mixture of (i) at least one detergent, (ii) at least one dispersant, and (iii) at least one antioxidant, as minor components; wherein the at least one detergent comprises a magnesium sulfonate detergent at from about 0.6 to 2.0 wt. % of the lubricating oil; wherein the at least one dispersant comprises a borated dispersant at from about 0.4 to 7.7 wt. % of the lubricating oil and selected from the group consisting of a boron-containing polyisobutenyl succinimide/succinic acid with a Boron to Nitrogen (B/N) of about 1.0, a boron-containing polyisobutenyl succinimide/succinic acid with a B/N of about 2.0, and combinations thereof; that provides a boron concentration from about 100 to about 1000 parts per million in said formulated oil; wherein the at least one antioxidant comprises an alkylated diphenylamine at from about 0.8 to 1.5 wt. % of the lubricating oil; wherein the engine or other mechanical component is lubricated with the lubricating oil operating in the presence of biodiesel fuel; and wherein oxidation stability as measured by the CEC L-109-14 FTIR oxidation at 216 hours and viscosity control as measured by the CEC L-109-14 Relative KV100 increase at 100 deg. C. for 216 hours are improved and cleanliness performance and deposit control are maintained or improved as compared to oxidation stability, viscosity control, cleanliness performance and deposit control achieved using a lubricating oil containing minor components other than the mixture of (i) at least one magnesium-containing detergent, (ii) at least one borated dispersant, and (iii) at least one alkylated diphenylamine antioxidant.

2. The method of claim 1 wherein said at least one antioxidant comprises a mixture of (i) an alkylated diphenylamine and (ii) a hindered phenol ester.

3. The method of claim 1 wherein the formulated oil further comprises one or more of an antiwear additive, viscosity modifier, other antioxidant, other detergent, other dispersant, pour point depressant, corrosion inhibitor, metal deactivator, seal compatibility additive, anti-foam agent, inhibitor, and anti-rust additive.

4. The method of claim 1 wherein the formulated oil is a passenger vehicle engine oil (PVEO) or a commercial vehicle engine oil (CVEO).

5. A lubricating oil having a composition comprising a lubricating oil base stock at from about 81.0 wt. % to 93.1 wt. % of the lubricating oil comprising a blend of a Group III base stock, a Group IV base stock and about 5 wt % of a Group V base stock; and a mixture of (i) at least one detergent, (ii) at least one dispersant, and (iii) at least one antioxidant, as minor components; wherein the at least one detergent comprises a magnesium sulfonate detergent at from about 0.6 to 2.0 wt. % of the lubricating oil; wherein the at least one dispersant comprises a borated dispersant at from about 0.4 to 7.7 wt. % of the lubricating oil and selected from the group consisting of a boron-containing polyisobutenyl succinimide/succinic acid with a Boron to Nitrogen (B/N) of about 1.0, a boron-containing polyisobutenyl succinimide/succinic acid with a B/N of about 2.0, and combinations thereof; that provides a boron concentration from about 100 to about 1000 parts per million in said lubricating oil; wherein the at least one antioxidant comprises an alkylated diphenylamine at from about 0.8 to 1.5 wt. % of the lubricating oil; wherein the engine or other mechanical component is lubricated with the lubricating oil operating in the presence of biodiesel fuel; and wherein oxidation stability as measured by the CEC L-109-14 FTIR oxidation at 216 hours and viscosity control as measured by the CEC L-109-14 Relative KV100 increase at 100 deg. C. for 216 hours are improved and cleanliness performance and deposit control are maintained or improved as compared to oxidation stability, viscosity control, cleanliness performance and deposit control achieved using a lubricating oil containing minor components other than the mixture of (i) at least one magnesium-containing detergent, (ii) at least one borated dispersant, and (iii) at least one alkylated diphenylamine antioxidant.

6. The lubricating oil of claim 5 wherein said at least one antioxidant comprises a mixture of (i) an alkylated diphenylamine and (ii) a hindered phenol ester.

7. The lubricating oil of claim 5 wherein the formulated oil further comprises one or more of an antiwear additive, viscosity modifier, other antioxidant, other detergent, other dispersant, pour point depressant, corrosion inhibitor, metal deactivator, seal compatibility additive, anti-foam agent, inhibitor, and anti-rust additive.

8. The lubricating oil of claim 5 which is a passenger vehicle engine oil (PVEO) or a commercial vehicle engine oil (CVEO).

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Burns Iii Raymond G
• Dance Smruti A
• Deckman Douglas E

Classifications

• C10N2060/14

  by boron or a compound containing boron · CPC title

• C10N2040/253

  Small diesel engines · CPC title

• C10N2040/252

  Diesel engines · CPC title

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title

• C10N2030/04

  Detergent property or dispersant property · CPC title