Method and system for providing upgraded biogas

Patent metadata

Field	Value
Publication number	US-10487282-B2
Application number	US-201815970591-A
Country	US
Kind code	B2
Filing date	May 3, 2018
Priority date	Oct 20, 2016
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

A method for providing upgraded biogas includes feeding a stream of biogas into a biogas upgrading system in order to remove carbon dioxide from the stream of biogas. The biogas upgrading system, which may be based on absorption, adsorption, membrane permeation, and/or cryogenics, provides a stream of upgraded biogas and a tail gas stream. The tail gas stream, which may be CO 2 -rich, is enriched with natural gas so that it is combustible in medium-BTU equipment. The upgraded biogas is used for transportation use and/or the generation of fuel credits. Accordingly, both the tail gas and the upgraded biogas are used effectively and at lower cost.

First claim

What is claimed is:

1. A method of providing upgraded biogas comprising:
feeding biogas into a biogas upgrading system, said biogas upgrading system comprising a membrane having a feed side and a permeate side;
passing biogas across the feed side of the membrane;
passing natural gas across the permeate side of the membrane as a sweep stream such that permeate comprising carbon dioxide is conveyed with natural gas to an outlet of the biogas upgrading system as an enriched tail gas;
feeding upgraded biogas provided by the biogas upgrading system into a distribution system; and
withdrawing natural gas from the distribution system to enrich the tail gas,
wherein passing natural gas across the permeate side of the membrane as a sweep stream comprises passing at least a portion of the natural gas withdrawn from the distribution system across the permeate side of the membrane.

2. The method according to claim 1 , wherein withdrawing natural gas from the distribution system comprises withdrawing an amount of natural gas sufficient to provide the enriched tail gas with a methane content that is at least 70% of the methane content of the biogas fed to the biogas upgrading system.

3. The method according to claim 2 , further comprising feeding the enriched tail gas to a combustion system, said combustion system configured to produce at least one of heat and electricity.

4. The method according to claim 1 , wherein withdrawing natural gas from the distribution system comprises withdrawing an amount of natural gas selected such that for every unit of biogas fed to the biogas upgrading system at least 0.5 unit of natural gas is withdrawn from the distribution system.

5. The method according to claim 1 , wherein withdrawing natural gas from the distribution system comprises withdrawing an amount of natural gas sufficient to provide the enriched tail gas with a methane content of at least 30%.

6. The method according to claim 1 , wherein a rate of energy delivered of natural gas withdrawn from the distribution system for enriching the tail gas is equal to at least half of a rate of energy delivered of upgraded biogas fed to the distribution system.

7. The method according to claim 1 , wherein passing natural gas across the permeate side of the membrane comprises providing the natural gas in a counterflow configuration with the biogas passed across the feed side of the membrane.

8. The method according to claim 1 , wherein passing natural gas across the permeate side of the membrane comprises providing the natural gas in a co-current configuration with the biogas passed across the feed side of the membrane.

9. The method according to claim 1 , further comprising feeding the enriched tail gas to a combustion system.

10. The method according to claim 1 , wherein the biogas upgrading system comprises:
a separating unit for removing carbon dioxide from biogas to provide upgraded biogas and tail gas, said separating unit including a first inlet configured to receive the biogas, a second inlet configured to receive natural gas; a first outlet configured to provide the upgraded biogas, and a second outlet configured to provide the tail gas, said separating unit comprising the membrane having a feed side and a permeate side,
wherein passing biogas across the feed side of the membrane comprises passing biogas received at the first inlet across said feed side of the membrane such that upgraded biogas is provided at the first outlet, and
wherein passing natural gas across the permeate side of the membrane as a sweep stream comprises passing natural gas received at the second inlet across the permeate side of the membrane such that the permeate comprising carbon dioxide is conveyed with the natural gas to the second outlet.

11. The method according to claim 10 , comprising adding at least a portion of the withdrawn natural gas to a gas provided by the second outlet.

12. The method according to claim 10 , wherein the separating unit comprises a single-stage membrane system.

13. The method according to claim 1 , wherein feeding biogas into the biogas upgrading system comprises feeding biogas having a methane content greater than 35% into the biogas upgrading system, wherein feeding upgraded biogas provided by the biogas upgrading system into the distribution system comprises feeding upgraded biogas having a methane content greater than 95% into the distribution system, wherein withdrawing natural gas from the distribution system to enrich the tail gas comprises withdrawing natural gas having a methane content greater than 95%, and wherein the enriched tail gas has a methane content greater than 30%.

14. A process for providing upgraded biogas comprising:
i) obtaining biogas;
ii) feeding the biogas into a biogas upgrading system, said biogas upgrading system comprising a separating unit, said separating unit comprising a membrane having a feed side and a permeate side and having a first inlet configured to receive the biogas, a second inlet configured to receive natural gas; a first outlet configured to provide upgraded biogas, and a second outlet configured to provide tail gas;
iii) passing biogas received at the first inlet across the feed side of the membrane such that some of the carbon dioxide in the biogas permeates through the membrane to the permeate side and such that some methane in the biogas is retained on the feed side and passes to the first outlet;
iv) injecting methane from the biogas provided by the first outlet into a distribution system;
v) withdrawing natural gas from the distribution system;
vi) passing at least a portion of the withdrawn natural gas across the permeate side of the membrane such that the natural gas is conveyed with carbon dioxide permeate to the second outlet; and,
vii) feeding carbon dioxide and natural gas provided by the second outlet to a combustion system.

15. The process according to claim 14 , wherein the biogas upgrading system comprises a single-stage membrane system.

16. The process according to claim 14 , further comprising producing heat, power, or a combination thereof, using the combustion system.

17. The process according to claim 9 , further comprising producing heat, power, or a combination thereof, using the combustion system.

18. The process according to claim 9 , comprising removing water, hydrogen sulfide, or a combination thereof from the biogas prior to passing the biogas across the feed side of the membrane.

19. The process according to claim 14 , comprising removing water, hydrogen sulfide, or a combination thereof from the biogas prior to passing the biogas across the feed side of the membrane.

20. The process according to claim 9 , wherein the enriched tail gas has a heating value of at least 350 BTU/cubic foot.

Assignees

• Iogen Corp

Inventors

• Foody Brian
• Foody Patrick J

Classifications

• C02F2103/28

  from the paper or cellulose industry · CPC title

• B01D2257/304

  Hydrogen sulfide · CPC title

• B01D2257/556

  Organic compounds · CPC title

• C10L2290/02

  Combustion or pyrolysis · CPC title

• B01D2257/102

  Nitrogen · CPC title