Living cationic ring-opening polymerization (c-ROP) self healing coating for battery module packaging in electric vehicles (EV)

Patent metadata

Field	Value
Publication number	US-10487235-B2
Application number	US-201715435820-A
Country	US
Kind code	B2
Filing date	Feb 17, 2017
Priority date	Feb 17, 2017
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

The present disclosure provides a battery pack component including a self-healing coating. The self-healing coating is disposed on at least a portion of a surface of the battery pack component. The self-healing coating includes a first precursor including a cyclic ether capable of reacting in a self-healing cationic ring-opening polymerization reaction. The self-healing coating further includes an initiator including an alkali metal salt. The self-healing cationic ring-opening polymerization reaction occurs when a defect is present in the self-healing coating. In certain aspects, the cyclic ether may include 1,3-dioxolane (C 3 H 6 O 2 ) and the initiator may include lithium bis(fluorosulfonyl)imide (F 2 NaNO 4 S 2 ). In other aspects, the self-healing coating may include a second precursor that is capable of copolymerizing with the first precursor. In still other aspects, the present disclosure provides a method of making a self-healing coating for a battery pack component.

First claim

What is claimed is:

1. A battery pack component comprising:
a self-healing coating disposed on at least a portion of a surface of the battery pack component, wherein the self-healing coating comprises,
a first polymer formed from one or more precursors, the one or more precursors including a first precursor comprising a heterocycle capable of reacting in a self-healing cationic ring-opening polymerization reaction, and
an initiator comprising an alkali metal salt selected from the group consisting of: lithium hexafluorophosphate (LiPF 6 ), lithium tetrafluoroborate (LiBF 4 ), lithium fluoride (LiF), lithium bis(fluorosulfonyl)imide (F 2 LiNO 4 S 2 ), sodium hexafluorophosphate (NaPF 6 ), sodium tetrafluoroborate (NaBF 4 ), sodium fluoride (NaF), sodium bis(fluorosulfonyl)imide (F 2 NaNO 4 S 2 ), potassium hexafluorophosphate (KPF 6 ), potassium tetrafluoroborate (KBF 4 ), potassium fluoride (KF), potassium bis(fluorosulfonyl)imide (F 2 KNO 4 S 2 ), and combinations thereof, wherein:

a polymer chain of the first polymer is configured to break upon damage to the self-healing coating such that the first precursor is present as a reactive end group, and
the reactive end group is configured to react with another first precursor in the presence of the initiator in the self-healing cationic ring-opening polymerization reaction.

2. The battery pack component of claim 1 , wherein the alkali metal salt is an alkali metal imide salt selected from the group consisting of: lithium bis(fluorosulfonyl)imide (F 2 LiNO 4 S 2 ), sodium bis(fluorosulfonyl)imide (F 2 NaNO 4 S 2 ), potassium bis(fluorosulfonyl)imide (F 2 KNO 4 S 2 ), and combinations thereof.

3. The battery pack component of claim 1 , wherein the heterocycle is selected from the group consisting of: 1,3-dioxolane (C 3 H 6 O 2 ), tetrahydrofuran (THF) (C 4 H 8 O), 1,4-dioxane (C 4 H 8 O 2 ), ethylene oxide (C 2 H 4 O), tetrahydropyran (C 5 H 10 O), and combinations thereof.

4. The battery pack component of claim 1 , wherein the one or more precursors further comprises a second precursor capable of copolymerizing with the first precursor.

5. The battery pack component of claim 4 , wherein the second precursor comprises a monomer selected from the group consisting of: hexamethylene cyclotrisiloxane (D3) (C 6 H 18 O 3 Si 3 ), allyl disulfide (C 6 H 10 S 2 ), poly(ethylene glycol) methyl ether methacrylate (PMMA) ((C 5 O 2 H 8 ) n ), polydimethylsiloxane (PDMS) ((C 2 H 6 OSi) n ), and combinations thereof.

6. The battery pack component of claim 1 , wherein the self-healing coating has a thickness of greater than or equal to about 50 nanometers to less than or equal to about 500 microns.

7. The battery pack component of claim 1 , wherein the battery pack component is selected from the group consisting of: a cooling system, a coolant pipe, a coolant plate, a case, a cover, a package, a cell, a body, and combinations thereof.

8. The battery pack component of claim 7 , wherein:
the battery pack component includes one or more cells,
each cell includes two tabs and two respective joints connecting the tabs to the cell; and
the self-healing coating is disposed on at least one of: a surface of the one or more cells, an edge of the one or more cells, and a joint.

9. The battery pack component of claim 1 , wherein the self-healing coating is capable of repairing defects in the self-healing coating, thereby sealing the battery pack component to prevent fluid leaks from an interior of the battery pack component to an exterior of the battery pack component.

10. The battery pack component of claim 1 , wherein the battery pack component further comprises an insulating layer comprising a second polymer, wherein the insulating layer is disposed between the surface and the self-healing coating.

11. The battery pack component of claim 10 , wherein the insulating layer comprises nylon ((C 12 H 22 N 2 O 2 ) n ).

12. The battery pack component of claim 1 , wherein the surface of the battery pack component comprises aluminum.

13. The battery pack component of claim 1 , wherein the heterocycle comprises 1,3-dioxolane (C 3 H 6 O 2 ) and the initiator comprises lithium bis(fluorosulfonyl)imide (F 2 LiNO 4 S 2 ).

14. A method of coating a battery pack component with a self-healing coating, the method comprising:
forming the self-healing coating by combining a precursor comprising a heterocycle and an initiator comprising an alkali metal salt selected from the group consisting of: lithium hexafluorophosphate (LiPF 6 ), lithium tetrafluoroborate (LiBF 4 ), lithium fluoride (LiF), lithium bis(fluorosulfonyl)imide (F 2 LiNO 4 S 2 ), sodium hexafluorophosphate (NaPF 6 ), sodium tetrafluoroborate (NaBF 4 ), sodium fluoride (NaF), sodium bis(fluorosulfonyl)imide (F 2 NaNO 4 S 2 ), potassium hexafluorophosphate (KPF 6 ), potassium tetrafluoroborate (KBF 4 ), potassium fluoride (KF), potassium bis(fluorosulfonyl)imide (F 2 KNO 4 S 2 ), and combinations thereof, wherein the heterocycle is polymerizes by a cationic ring-opening reaction to form a polymer; and
disposing the self-healing coating on at least a portion of a surface of the battery pack component, wherein:

a polymer chain of the polymer is configured to break upon damage to the self-healing coating such that the precursor is present as a reactive end group, and
the reactive end group is configured to react with another precursor in the presence of the initiator in the cationic ring-opening reaction.

15. The method of claim 14 , wherein the forming comprises adding the precursor and the initiator at greater than or equal to 1 molar initiator to precursor to less than or equal to 2 molar initiator to precursor.

16. The method of claim 14 , further comprising:
repairing a defect in the self-healing coating by polymerizing the precursor in the presence of the initiator by the cationic ring-opening reaction to form a repaired region within the defect.

17. The method of claim 16 , wherein repairing the defect further comprises applying a pre-polymer solution comprising the precursor and the initiator to the defect to form the repaired region within the defect, and wherein the repaired region comprises the self-healing coating.

18. A battery pack component comprising:
a self-healing coating disposed on at least a portion of a surface of the battery pack component, wherein the self-healing coating comprises,
a non-reactive polymer matrix,
a precursor dispersed in the non-reactive polymer matrix, the precursor comprising a heterocycle capable of reacting in a self-healing cationic ring-opening polymerization reaction, and
an initiator dispersed in the non-reactive polymer matrix, the initiator comprising an alkali metal salt selected from the group consisting of: lithium hexafluorophosphate (LiPF 6 ), lithium tetrafluoroborate (LiBF 4 ), lithium fluoride (LiF), lithium bis(fluorosulfonyl)imide (F 2 LiNO 4 S 2 ), sodium hexafluorophosphate (NaPF 6 ), sodium tetrafluoroborate (NaBF 4 ), sodium fluoride (NaF), sodium bis(fluorosulfonyl)imide (F 2 NaNO 4 S 2 ), potassium hexafluorophosphate (KPF 6 ), potassium tetrafluoroborate (KBF 4 ), potassium fluoride (KF), potassium bis(fluorosulfonyl)imide (F 2 KNO 4 S 2 ), and combinations thereof, wherein the precursor is configured to react in a self-healing cationic ring-opening reaction in the presence of the initiator, wherein the precursor and the initiator are dispersed in capsules or channels configured to rupture upon damage to the non-reactive polymer matrix to initiate the self-healing cationic ring-opening reaction.

19.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Dai Fang
• Cai Mei
• Wang Tao
• Bahauddin Mohammed
• Zeng Sherman

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C09D171/00 Primary

  Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain (based on polyacetals C09D159/00; based on epoxy resins C09D163/00; based on polythioether-ethers C09D181/02; based on polyethersulfones C09D181/06); Coating compositions based on derivatives of such polymers · CPC title

• H01M10/625

  Vehicles · CPC title

• F28D1/03

  with plate-like or laminated conduits {(stacked plates having one or more openings therein to form tubular heat-exchange passages F28F3/086)} · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title