Solvent-borne clearcoat coating composition, method for producing it and use thereof

Patent metadata

Field	Value
Publication number	US-10487233-B2
Application number	US-201214111042-A
Country	US
Kind code	B2
Filing date	Apr 12, 2012
Priority date	Apr 12, 2011
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

Solvent-containing clearcoat coating composition comprising (A) an OH-functional (meth)acrylate (co)polymer comprising (A1) 30%-99% by weight, based on the mass of the nonvolatile fraction of (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and glass transition temperature T g of 15° C. to 100° C., and (A2) 1%-70% by weight, based on the mass of the nonvolatile fraction of (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature T g of −100° C. to −20° C., (B) a crosslinker component comprising functional groups reactive toward OH, (C) 0.02%-1.2% by weight, based on the mass of the nonvolatile fraction of (A), of at least one polyamide and (D) 0.04%-2.9% by weight, based on the mass of the nonvolatile fraction of (A), of at least one urea adduct of a polyisocyanate and benzylamine.

First claim

The invention claimed is:

1. A solvent-containing clearcoat coating composition comprising:
(A) an OH-functional (meth)acrylate (co)polymer component comprising:
(A1) 30%-99% by weight, based on the mass of the nonvolatile fraction of the OH-functional (meth)acrylate (co)polymer component (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature T g of 15° C. to 100° C., and
(A2) 1%-70% by weight, based on the mass of the nonvolatile fraction of the OH-functional (meth)acrylate (co)polymer component (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature T g of −100° C. to −20° C.;

(B) a crosslinker component comprising at least one crosslinking agent having functional groups that are reactive toward OH groups;
(C) 0.02%-1.2% by weight, based on the mass of the nonvolatile fraction of the OH-functional (meth)acrylate (co)polymer component (A), of at least one polyamide; and
(D) 0.04%-2.9% by weight, based on the mass of the nonvolatile fraction of the OH-functional (meth)acrylate (co)polymer component (A), of at least one urea compound comprising an adduct of a polyisocyanate and benzylamine.

2. The solvent-containing clearcoat coating composition of claim 1 , wherein the (meth)acrylate (co)polymers (A1) and (A2) have an OH number of 70-180 mg KOH/g.

3. The solvent-containing clearcoat coating composition of claim 1 , wherein the crosslinking component (B) comprises as crosslinking agent(s) a member selected from the group consisting of at least one polyisocyanate, at least one amino resin, and mixtures of two or more of the foregoing.

4. The solvent-containing clearcoat coating composition of claim 2 , wherein the crosslinking agent comprise one or more polyisocyanates.

5. The solvent-containing clearcoat coating composition of claim 4 , wherein the at least one crosslinking agent is a trimeric hexamethylene diisocyanate.

6. The solvent-containing clearcoat coating composition of claim 4 , wherein in the one or more polyisocyanates are nonblocked.

7. The solvent-containing clearcoat coating composition of claim 1 , comprising a two-component clearcoat coating composition.

8. The solvent-containing clearcoat coating composition of claim 1 , wherein the polyamides (C) comprise synthetic polyamide waxes.

9. The solvent-containing clearcoat coating composition of claim 1 , wherein the polyamides (C) comprise reaction products of monomeric polyamines and (hydroxy) fatty acids which comprise 16 to 20 C atoms per molecule.

10. A process for preparing a solvent-containing clearcoat coating composition of claim 1 comprising mixing the components (A), (B), (C), and (D).

11. The process of claim 10 , wherein the OH-functional (meth)acrylate (co)polymer component (A) is mixed with the components (C) and (D), and the crosslinker component (B) with at least one organic solvent added is mixed in with the components (A), (B), and (C) only within 30 minutes prior to application to a substrate.

12. The process of claim 10 , wherein the urea compound is added in the form of a paste which comprises a mixture of the urea compound with a polyester and/or a (meth)acrylate (co)polymer and at least one organic solvent.

13. The process of claim 10 , wherein the polyamides are added in the form of a dispersion which comprises a mixture of the polyamides with a (meth)acrylate (co)polymer and at least one organic solvent.

14. A method of producing a cured clearcoat on a substrate, comprising applying the solvent-containing clearcoat coating composition of claim 1 to a substrate to produce a coated substrate and subsequently thermal curing the coated substrate at a temperature of 40 to 190° C.

15. The method of claim 14 , wherein the substrate is a plastic substrate.

16. The method of claim 14 , wherein actinic radiation is excluded.

17. A multicoat coating system comprising: at least one coating of the solvent-containing clearcoat coating composition of claim 1 and one or more of the following coatings: a primersurfacer, a single-coat topcoat, and a basecoat.

18. The solvent-containing clearcoat coating composition of claim 1 , wherein the OH-functional (meth)acrylate (co)polymers of (A1) and (A2) are formed from monomers selected from the group consisting of: (meth)acrylates and hydroxyalkyl (meth)acrylates; and optionally further from monomers selected from the group consisting of: vinylaromatic hydrocarbons, amides of (meth)acrylic acid, nitriles of (meth)acrylic acid, vinyl esters, vinyl ethers, and (meth)acrylic acid.

19. The solvent-containing clearcoat coating composition of claim 1 comprising:
(A1) 55%-95% by weight of the at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature T g of 15° C. to 100° C., and
(A2) 5%-45% by weight of the at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature T g of −100° C. to −20° C.

20. The solvent-containing clearcoat coating composition of claim 1 further comprising an organic solvent in an amount from 30% to 70% by weight of the composition.

21. The solvent-containing clearcoat coating composition of claim 1 containing not more than 1% by weight of water based on the total amount of the composition.

Assignees

• Wegner Egon
• Mayenfels Peter
• Basf Coatings Gmbh

Inventors

• Wegner Egon
• Mayenfels Peter

Classifications

• C09D133/066

  containing -OH groups · CPC title

• C08K5/29

  Compounds containing {one or more} carbon-to-nitrogen double bonds · CPC title

• C09D175/04

  Polyurethanes · CPC title

• C08G18/2865

  Compounds having only one primary or secondary amino group; Ammonia · CPC title

• C08L75/04

  Polyurethanes · CPC title