Manufacturing method for propylene block copolymer

Patent metadata

Field	Value
Publication number	US-10487169-B2
Application number	US-201515504482-A
Country	US
Kind code	B2
Filing date	Aug 14, 2015
Priority date	Aug 26, 2014
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

A method for producing a propylene-based block copolymer produces a propylene-based copolymer that exhibits excellent stereoregularity, rigidity, and impact resistance in a convenient and efficient manner while achieving high polymerization activity. The method for producing a propylene-based block copolymer includes bringing a catalyst into contact with propylene, or propylene and an α-olefin, and bringing an electron donor compound into contact with the resulting product to produce a propylene-based block copolymer, the catalyst including a solid catalyst component that includes titanium, magnesium, a halogen, and an internal electron donor compound, a specific organoaluminum compound, and a specific external electron donor compound.

First claim

The invention claimed is:

1. A method for producing a propylene-based block copolymer comprising:
a first step of bringing an olefin polymerization catalyst into contact with propylene, and bringing an electron donor compound (IV) into contact with the resulting product so that the propylene is formed into a homopolymer,
after the first step, a second step of bringing the homopolymer into contact with an olefin other than propylene to form a propylene-based copolymer,
the olefin polymerization catalyst comprising a solid catalyst component for olefin polymerization that comprises titanium, magnesium, a halogen, and an internal electron donor compound, an organoaluminum compound represented by a general formula (I), and an external electron donor compound represented by a general formula (III),
R 1 p AlQ 3-p   (I)

wherein R 1 is a hydrocarbyl group having 1 to 6 carbon atoms, p is a real number that satisfies 0<p≤3, provided that a plurality of R 1 are either identical to or different from each other when a plurality of R 1 are present, and Q is a hydrogen atom,
a hydrocarbyloxy group having 1 to 6 carbon atoms, or a halogen atom, provided that
a plurality of Q are either identical to or different from each other when a plurality of Q are present,
(R 4 R 5 N)Si(OR 6 ) 3   (III)

wherein R 4 and R 5 are a hydrogen atom, a linear alkyl group having 1 to 20 carbon atoms, a branched alkyl group having 3 to 20 carbon atoms, a vinyl group, an allyl group, a linear or branched alkenyl group having 3 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a cycloalkenyl group having 3 to 20 carbon atoms, an aromatic hydrocarbon group having 6 to 24 carbon atoms, a nitrogen atom-containing hydrocarbon group having 2 to 24 carbon atoms that is terminated by a carbon atom, or an amino group having 2 to 24 carbon atoms, provided that R 4 and R 5 are either identical to or different from each other, and are optionally bonded to each other to form a ring, and R 6 is a linear alkyl group having 1 to 20 carbon atoms,
a branched alkyl group having 3 to 20 carbon atoms, a vinyl group, an allyl group,
a linear or branched alkenyl group having 3 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a cycloalkenyl group having 3 to 20 carbon atoms, or
an aromatic hydrocarbon group having 6 to 24 carbon atoms, provided that the three R 6 are either identical to or different from each other, and
wherein the electron donor compound (IV) is an alcohol.

2. The method for producing a propylene-based block copolymer according to claim 1 , wherein the electron donor compound (IV) is methanol or ethanol.

3. The method for producing a propylene-based block copolymer according to claim 2 , wherein
the external electron donor compound represented by the general formula (III) is an external electron donor compound represented by a general formula (IIIa),
(R 9 R 10 N)Si(OR 11 ) 3   (IIIa)

wherein R 9 and R 10 are a hydrogen atom, a linear alkyl group having 1 to 12 carbon atoms, a branched alkyl group having 3 to 12 carbon atoms, a vinyl group, an allyl group, a linear or branched alkenyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, a cycloalkenyl group having 3 to 12 carbon atoms, an aromatic hydrocarbon group having 6 to 12 carbon atoms, a nitrogen atom-containing hydrocarbon group having 2 to 12 carbon atoms that is terminated by a carbon atom, or an amino group having 2 to 12 carbon atoms, provided that R 9 and R 10 are either identical to or different from each other, and are optionally bonded to each other to form a ring, and R 11 is a linear alkyl group having 1 to 12 carbon atoms,
a branched alkyl group having 3 to 12 carbon atoms, a vinyl group, an allyl group,
a linear or branched alkenyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, a cycloalkenyl group having 3 to 12 carbon atoms, or
an aromatic hydrocarbon group having 6 to 12 carbon atoms, provided that the three R 11 are either identical to or different from each other.

4. The method for producing a propylene-based block copolymer according to claim 2 , wherein the external electron donor compound (III) is one or more compounds selected from diethylaminotriethoxysilane, diethylaminotrimethoxysilane, dimethylaminotriethoxysilane, and dimethylaminotrimethoxysilane.

5. The method for producing a propylene-based block copolymer according to claim 1 , wherein
the external electron donor compound represented by the general formula (III) is an external electron donor compound represented by a general formula (IIIa),
(R 9 R 10 N)Si(OR 11 ) 3   (IIIa)

wherein R 9 and R 10 are a hydrogen atom, a linear alkyl group having 1 to 12 carbon atoms, a branched alkyl group having 3 to 12 carbon atoms, a vinyl group, an allyl group, a linear or branched alkenyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, a cycloalkenyl group having 3 to 12 carbon atoms, an aromatic hydrocarbon group having 6 to 12 carbon atoms, a nitrogen atom-containing hydrocarbon group having 2 to 12 carbon atoms that is terminated by a carbon atom, or an amino group having 2 to 12 carbon atoms, provided that R 9 and R 10 are either identical to or different from each other, and are optionally bonded to each other to form a ring, and R 11 is a linear alkyl group having 1 to 12 carbon atoms,
a branched alkyl group having 3 to 12 carbon atoms, a vinyl group, an allyl group,
a linear or branched alkenyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, a cycloalkenyl group having 3 to 12 carbon atoms, or
an aromatic hydrocarbon group having 6 to 12 carbon atoms, provided that the three R 11 are either identical to or different from each other.

6. The method for producing a propylene-based block copolymer according to claim 1 , wherein the external electron donor compound (III) is one or more compounds selected from diethylaminotriethoxysilane, diethylaminotrimethoxysilane, dimethylaminotriethoxysilane, and dimethylaminotrimethoxysilane.

Assignees

• Toho Titanium Co Ltd

Inventors

• Imai Masafumi
• Sugano Toshihiko
• Uozumi Toshiya
• HAGA Yuta

Classifications

• C08F297/083 Primary

  the monomers being ethylene or propylene · CPC title

• C08F210/06 Primary

  Propene · CPC title

• C08F4/654

  with magnesium or compounds thereof · CPC title

• C08F297/06 Primary

  using a catalyst of the coordination type · CPC title

• C08F2/001

  Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence) · CPC title