Dye removal from aqueous compositions

Patent metadata

Field	Value
Publication number	US-10487040-B2
Application number	US-201815980811-A
Country	US
Kind code	B2
Filing date	May 16, 2018
Priority date	Nov 24, 2015
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

A functionalized asphaltene, obtained by refluxing with an acid solution. The functionalized asphaltene contains elevated levels of oxygen content due to nitration and oxidation of the refluxing process. The refluxing process also imparts organic functional groups including at least amines, nitro groups carbonyl groups, carboxylic groups and hydroxyl groups to the functionalized asphaltene, and these functional groups are attached to, thereby coating the surface of a functionalized asphaltene particle. A method for removing dye compounds from an aqueous sample with the functionalized asphaltene is also described.

First claim

The invention claimed is:

1. A method for treating an aqueous sample to remove a a dye compound therefrom, comprising:
contacting the aqueous sample with particles of a functionalized asphaltene to adsorb the dye compound onto the particles of the functionalized asphaltene, and then
filtering the aqueous sample to remove the particles of the functionalized asphaltene having the dye compound adsorbed thereon;
wherein the functionalized asphaltene comprises:
10-35% by weight of elemental oxygen per total weight of the functionalized asphaltene;
3-10% by weight of elemental nitrogen per total weight of the functionalized asphaltene; and
3-10% by weight of elemental sulfur per total weight of the functionalized asphaltene;
wherein the particles of the functionalized asphaltene are obtained by refluxing a petroleum asphaltene with an acid, and
wherein the functionalized asphaltene has at least one active group selected from the group consisting of an amine group, a nitro group, a carbonyl group, a carboxylic group and a hydroxyl group covalently bonded to an asphaltene core.

2. The method of claim 1 , wherein the particles of the functionalized asphaltene have an adsorption capacity of 1-5 mg of the dye compound per g of the functionalized asphaltene.

3. The method of claim 1 , wherein the aqueous sample is contacted with the particles of the functionalized asphaltene for 2-7 h.

4. The method of claim 1 , wherein the aqueous sample is contacted with 1-10 mg/ml of the particles of the functionalized asphaltene.

5. The method of claim 1 , wherein the dye compound is bromophenol blue and the aqueous sample is contacted with the particles of the functionalized asphaltene at pH 4-9.

6. The method of claim 1 , wherein the dye compound is methyl orange and the aqueous sample is contacted with the particles of the functionalized asphaltene at pH of 2.5-4.

7. The method of claim 5 , further comprising:
desorbing the bromophenol blue from the particles of the functionalized asphaltene at a pH of lower than 4 or higher than 9.

8. The method of claim 1 , wherein the particles of the functionalized asphaltene have an average particle size of 10-20 nm.

9. The method of claim 1 , wherein the particles of the functionalized asphaltene have a particle size distribution of 0.5-100 nm with at least 60% of the particles having a particle size of 10-20 nm.

10. The method of claim 1 , wherein the particles of the functionalized asphaltene have a specific surface area of no higher than 10 m 2 /g.

11. The method of claim 1 , wherein the particles of the functionalized asphaltene have an adsorption average pore width of 1-10 nm.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Siddiqui Mohammad Nahid

Classifications

• C07C205/00 Primary

  Compounds containing nitro groups bound to a carbon skeleton · CPC title

• B01J2220/4875

  the starting material being a waste, residue or of undefined composition · CPC title

• B01J20/28059

  being less than 100 m2/g · CPC title

• B01J20/3206

  Organic carriers, supports or substrates · CPC title

• B01J20/22

  comprising organic material · CPC title