Glass compositions and fibers made therefrom

Patent metadata

Field	Value
Publication number	US-10487007-B2
Application number	US-201615263010-A
Country	US
Kind code	B2
Filing date	Sep 12, 2016
Priority date	Aug 3, 2009
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

Some embodiments of the present invention provide fiberizable glass compositions formed from batch compositions comprising amounts of one or more glassy minerals, including perlite and/or pumice. Some embodiments of the present invention related to glass fibers formed from such batch compositions, and composites and other materials incorporating such glass fibers.

First claim

That which is claimed:

1. A polymeric composite comprising:
a polymeric material; and
at least one glass fiber in the polymeric material, the at least one glass fiber comprising a glass composition formed from a batch composition, wherein the glass fiber comprises:
53 to less than 62 weight percent SiO 2 ;
8-12 weight percent Al 2 O 3 ;
0-3 weight percent ZnO;
greater than 0 to 3 weight percent TiO 2 ;
8.5-18 weight percent alkali metal oxide (R 2 O) component;
a metal oxide (RO) component selected from the group consisting of MgO, CaO, BaO, SrO, and ZnO, wherein the first metal oxide component is present in an amount to provide a mass ratio of R 2 O/RO ranging from about 0.28 to about 1.7;
0-3 weight percent ZrO 2 ;
0-3 weight percent MnO 2 ;
0-3 weight percent La 2 O 3 ; and
greater than 0 to less than 1 weight percent of Fe 2 O 3 ,
wherein the glass fiber is resistant to acidic corrosion.

2. The polymeric composite of claim 1 , wherein the batch composition comprises at least 10 weight percent of a glassy mineral and at least 5 weight percent of a sodium source, wherein the glassy mineral comprises a combination of SiO 2 and Al 2 O 3 in an amount of at least 80 weight percent.

3. The polymeric composite of claim 1 , wherein the at least one glass fiber comprises MnO 2 in an amount up to 3 weight percent.

4. The polymeric composite of claim 1 , wherein the resistance to acidic corrosion as determined by percent weight loss of the glass fiber in solution of sulfuric acid at a concentration of 1 normal is less than 4 weight percent after 12 hours.

5. The polymeric composite of claim 4 , wherein the solution is at a pH range of 0-1.

6. The polymeric composite of claim 1 , wherein the resistance to acidic corrosion as determined by percent weight loss of the glass fiber in solution of sulfuric acid at a concentration of 1 normal is less than 3 weight percent after 12 hours.

7. The polymeric composite of claim 1 , wherein the resistance to acidic corrosion as determined by percent weight loss of the glass fiber in solution of sulfuric acid at a concentration of 1 normal is 0.55 to 1.7 weight percent after 1 hour.

8. The polymeric composite of claim 1 , wherein the glass fiber further comprises resistance to alkaline corrosion.

9. The polymeric composite of claim 8 , wherein the resistance to alkaline corrosion as determined by percent weight loss of the glass fiber in solution of sodium hydroxide at a concentration of 1 normal is less than 4 weight percent.

10. The polymeric composite of claim 8 , wherein the resistance to alkaline corrosion as determined by percent weight loss of the glass fiber in solution of sodium hydroxide at a concentration of 1 normal is less than 3 weight percent.

11. The polymeric composite of claim 8 , wherein the resistance to acidic corrosion as determined by percent weight loss of the glass fiber in solution of sodium hydroxide at a concentration of 1 normal is 0.25 to 0.85 weight percent after 1 hour.

12. The polymeric composite of claim 8 , wherein the solution is at a pH range of 12-14.

13. The polymeric composite of claim 1 , wherein the at least one glass fiber has a length of less than about 105 millimeters.

14. The polymeric composite of claim 1 , wherein the at least one glass fiber has a length of less than about 13 millimeters.

15. The polymeric composite of claim 1 , wherein the at least one glass fiber has a length of greater than about fifty microns.

16. The polymeric composite of claim 1 , wherein the at least one glass fiber has a length of greater than about fifty millimeters.

17. The polymeric composite of claim 1 , wherein the at least one glass fiber is in the form of a non-woven fabric.

18. The polymeric composite of claim 1 , wherein the at least one glass fiber is in the form of a woven fabric.

19. The polymeric composite of claim 1 , wherein the polymeric material comprises a thermoplastic polymer or thermosetting polymer.

20. A polymeric composite comprising:
a polymeric material; and
at least one glass fiber in the polymeric material, the at least one glass fiber comprising a glass composition formed from a batch composition, wherein the glass fiber comprises:
53 to less than 62 weight percent SiO 2 ;
8-12 weight percent Al 2 O 3 ;
0-3 weight percent ZnO;
greater than 0 to 3 weight percent TiO 2 ;
8.5-18 weight percent alkali metal oxide (R 2 O) component;
a metal oxide (RO) component selected from the group consisting of MgO, CaO, BaO, SrO, and ZnO, wherein the metal oxide component is present in an amount to provide a mass ratio of R 2 O/RO ranging from about 0.28 to about 1.7; and
greater than 0 to less than 1 weight percent of Fe 2 O 3 ; and
wherein the glass fiber is resistant to acidic corrosion with the glass fiber losing less than 3 weight percent after 12 hours of immersion in a solution with a pH of 0.

Assignees

• Ppg Ind Ohio Inc

Inventors

• Li Hong
• Watson James C

Classifications

• C03C13/00

  Fibre or filament compositions (manufacture of fibres or filaments C03B37/00) · CPC title

• C08J5/043

  with glass fibres · CPC title

• Y10T442/60

  Nonwoven fabric [i.e., nonwoven strand or fiber material] · CPC title

• C03C13/06 Primary

  Mineral fibres, e.g. slag wool, mineral wool, rock wool · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title