Membrane water treatment facility and method incorporating adsorption on an adsorbent powdered material and means for limiting the abrasion of the membranes

Patent metadata

Field	Value
Publication number	US-10486987-B2
Application number	US-201415105221-A
Country	US
Kind code	B2
Filing date	Dec 11, 2014
Priority date	Dec 20, 2013
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

Method for treating water comprising: a step for putting said water into contact with an adsorbent powdery material in a concentration of 0.1 to 5 g/L in a membrane reactor containing at least one submerged filtration membrane; a step of filtration by submerged membrane of said water containing said adsorbent powdery material in said membrane reactor, said membrane being at least partly constituted by an organic material; characterized in that it includes steps aimed at limiting the abrasion of said at least one submerged membrane by said adsorbent powdery material, said steps consisting in: putting said water containing said adsorbent powdery material into contact, in said membrane reactor, with a particulate polymer material constituted by particles in a concentration of 1 g/L to 10 g/L, said particles having an average diameter of 1 mm to 5 mm and a density of 1.05 to 1.5; and stirring said mixture constituted by water, adsorbent powdery material and particulate polymer material within said membrane reactor containing said at least one filtration membrane.

First claim

The invention claimed is:

1. A method for treating water comprising:
directing the water into a membrane reactor having a submerged filtration membrane constituted by organic material and contacting the water in the membrane reactor with powdered activated carbon having a concentration of 0.1 to 5.0 g/L;
filtering the water in the membrane reactor with the submerged filtration membrane;
limiting the abrasion of the submerged membrane by the powdered activated carbon by:
i. injecting polymer beads into the membrane reactor
ii. injecting air into the membrane reactor;
iii. utilizing the injected air to stir the water, polymer beads and powdered activated carbon and homogenize the powdered activated carbon and polymer beads and causing the polymer beads and the turbulence induced by the polymer beads to form a protective shield around the membrane protecting the membrane and limiting the accumulation of powdered activated carbon on the membrane and limiting the abrading of the membrane that results from the accumulation of powdered activated carbon on the membrane; and
iv. wherein the polymer beads have a concentration of 1 g/L to 10 g/L and have an average diameter of 1 mm to 5 mm and a density of 1.05 to 1.5.

2. The method of claim 1 wherein the water, powdered activated carbon and the polymeric beads form a mixture and wherein the method includes stirring the mixture with sequenced or non-sequenced injection of air into the mixture.

3. The method of claim 1 wherein the water, powdered activated carbon and the polymeric beads constitute a mixture and wherein the method includes stirring the mixture by recirculating at least a part of the mixture in the membrane reactor.

4. The method of claim 1 wherein said the polymeric beads are chosen from the group consisting of polypropylene beads, carbonated polypropylene beads, hollow polypropylene beads filled with minerals, polycarbonate beads, polyurethane beads, polymethylmethacrylate beads, polybutylene terephtalate beads, polyoxymethylene beads, polyethylene beads, and polyvinyl chloride beads.

5. The method of claim 1 including circulating the water in the membrane reactor through a recirculation loop at a speed of 3 to 15 m/h.

6. The method of claim 1 wherein said submerged filtration membrane is chosen from the group including nanofiltration membranes, ultrafiltration membranes and microfiltration membranes.

7. The method of claim 1 further including injecting ozone into the water to be treated at a point upstream of the membrane reactor or in said membrane reactor.

Assignees

• Veolia Water Solutions & Tech

Inventors

• Gaid Abdelkader
• Tazi-Pain Annie
• Daines-Martinez Catherine

Classifications

• C02F2103/343

  from the pharmaceutical industry, e.g. containing antibiotics · CPC title

• C02F2101/306

  Pesticides · CPC title

• C02F2101/305

  Endocrine disruptive agents · CPC title

• B01D61/14

  Ultrafiltration; Microfiltration · CPC title

• C02F2303/16

  Regeneration of sorbents, filters · CPC title