Process for manufacture of purified alkaline earth metal carbonate

Patent metadata

Field	Value
Publication number	US-10486980-B2
Application number	US-201515328210-A
Country	US
Kind code	B2
Filing date	Jul 21, 2015
Priority date	Jul 23, 2014
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

Process for manufacture of purified alkaline earth metal carbonate The invention concerns a process for the manufacture of a purified alkaline earth metal carbonate, the purified alkaline earth metal carbonate obtainable by said process, and its use in the manufacture of products and devices in the field of electronics and glass. The process comprises the steps of calcinating the alkaline earth metal carbonate with an aqueous phase comprising a salt. The alkaline earth metal carbonate might be barium carbonate or strontium carbonate.

First claim

The invention claimed is:

1. A process for the manufacture of a purified alkaline earth carbonate, comprising the steps of
a) calcining an alkaline earth metal carbonate, wherein the alkaline earth metal carbonate is BaCO 3 and/or SrCO 3 ,
b) washing the calcinated alkaline earth metal carbonate with an aqueous phase comprising a metal salt.

2. The process according to claim 1 , wherein the alkaline earth metal carbonate of step a) has a particle size D90 value of from 700 to 1100 μm and a particle size D50 value of from 350 to 750 μm after calcination.

3. The process according to claim 1 , wherein the calcination procedure of step a) is performed at a temperature of from 150 to 1000° C.

4. The process according to claim 1 , wherein the metal salt comprised in the aqueous phase of step b) is a carbonate, chloride, bromide, phosphate or citrate.

5. The process according to claim 4 , wherein the metal salt is an alkali metal carbonate.

6. The process according to claim 5 , wherein the metal salt is sodium carbonate.

7. The process according to claim 4 , wherein the metal salt comprised in the aqueous phase of step b) is a carbonate.

8. The process according to claim 1 , wherein the content of metal salt in the aqueous phase of step b) corresponds to from 1 to 200 equivalents, wherein 1 equivalent is one mole metal salt cation, if the metal salt cation is divalent, or is two moles metal salt cation, if the metal salt cation is monovalent, per mole of MSO 4 , wherein M is an alkaline earth metal, formed by oxidation of all sulfur impurities in the calcination product of step a).

9. The process according to claim 8 , wherein the content of metal salt in the aqueous phase of step b) corresponds to from 10-20 equivalents.

10. The process according to claim 1 , wherein step b) is repeated.

11. The process according to claim 1 , wherein the alkaline earth metal carbonate provided to the calcination procedure of step a) has a total sulfur content of from 200 to 1700 ppm.

12. The process according to claim 1 , wherein the alkaline earth metal carbonate after step b) has a total sulfur content of from 0.1 to 200 ppm.

13. The process according to claim 1 , wherein the alkaline earth metal carbonate provided to the calcination procedure of step a) has a particle size D90 value of from 12 to 30 μm and a has a particle size D50 value of from 2,5 to 9 μm.

Assignees

• Solvay

Inventors

• Hardinghaus Ferdinand
• Bonmann Erik
• Engels Achim

Classifications

• C01F11/186 Primary

  Strontium or barium carbonate · CPC title

• C01F11/185 Primary

  After-treatment, e.g. grinding, purification, conversion of crystal morphology · CPC title

• C01P2006/12

  Surface area · CPC title

• C01P2004/51

  Particles with a specific particle size distribution · CPC title

• C01P2004/60

  Particles characterised by their size · CPC title