Reducing CNT resistivity by aligning CNT particles in films

Patent metadata

Field	Value
Publication number	US-10486379-B2
Application number	US-201615373371-A
Country	US
Kind code	B2
Filing date	Dec 8, 2016
Priority date	Dec 8, 2016
Publication date	Nov 26, 2019
Grant date	Nov 26, 2019

Abstract

A method for reducing the resistivity of a thermoplastic film containing carbon nanotubes includes connecting an electric power supply to the thermoplastic film containing carbon nanotubes and passing electric current through the thermoplastic film containing carbon nanotubes to heat the thermoplastic film to an elevated temperature and align carbon nanotubes within the thermoplastic film. The thermoplastic film is solid at room temperature.

First claim

The invention claimed is:

1. A method for reducing the resistivity of a thermoplastic film containing carbon nanotubes, the method comprising:
connecting an electric power supply to the thermoplastic film containing carbon nanotubes, wherein the thermoplastic film is solid at room temperature; and
passing electric current through the thermoplastic film containing carbon nanotubes to heat the thermoplastic film to an elevated temperature lower than a melting temperature of the thermoplastic film and align carbon nanotubes within the thermoplastic film without the thermoplastic film liquifying.

2. The method of claim 1 , wherein the elevated temperature is less than the melting temperature of the thermoplastic film by at least 10° C.

3. The method of claim 2 , wherein the elevated temperature is less than the melting temperature of the thermoplastic film by at least 20° C.

4. The method of claim 1 , wherein the thermoplastic film comprises a compound selected from the group of polyethylene, polypropylene, polyimides including polyetherimide (PEI), acrylonitrile butadiene styrene (ABS), nylon, polyesters including polyethylene terephthalate (PET) and polyethylene napthalate (PEN), polylactic acid (polylactide) (PLA), polyurethanes, polyether ether ketones (PEEK), polybenzimidazole, polyether sulfone (PES) and combinations thereof.

5. The method of claim 1 , wherein electric current passes through the thermoplastic film containing carbon nanotubes to align the carbon nanotubes for no more than 60 minutes.

6. The method of claim 1 , wherein the resistivity of the thermoplastic film containing carbon nanotubes after passing electric current through the thermoplastic film is less than 3 ohms per square (Ω/sq).

7. The method of claim 1 , wherein the resistivity of the thermoplastic film containing carbon nanotubes after passing electric current through the thermoplastic film is less than 1×10 −4 ohms-cm (Ω-cm).

8. The method of claim 1 , wherein the resistivity of the thermoplastic film containing carbon nanotubes after passing electric current through the thermoplastic film is about 8×10 −5 Ω-cm.

9. The method of claim 1 , wherein pulsed electric current passes through the thermoplastic film containing carbon nanotubes to prevent the thermoplastic film from reaching its melting temperature.

10. A method comprising:
providing a thermoplastic film containing carbon nanotubes, wherein the thermoplastic film is solid at room temperature;
connecting the thermoplastic film containing carbon nanotubes to an electric power supply;
passing electric current through the thermoplastic film containing carbon nanotubes to heat the thermoplastic film to a first temperature lower than a melting temperature of the thermoplastic film and align carbon nanotubes within the thermoplastic film without the thermoplastic film liquifying;
attaching the thermoplastic film containing carbon nanotubes to a component; and
passing electric current through the thermoplastic film containing carbon nanotubes to heat the thermoplastic film to a second temperature to provide anti-icing or de-icing to the component, wherein the second temperature is lower than the first temperature.

11. The method of claim 10 , wherein the first temperature is less than the melting temperature of the thermoplastic film by at least 10° C.

12. The method of claim 11 , wherein the first temperature is less than the melting temperature of the thermoplastic film by at least 20° C.

13. The method of claim 10 , wherein the thermoplastic film comprises a compound selected from the group of polyethylene, polypropylene, polyimides such as polyetherimide (PEI), acrylonitrile butadiene styrene (ABS), nylon, polyesters such as polyethylene terephthalate (PET) and polyethylene napthalate (PEN), polylactic acid (polylactide) (PLA), polyurethanes, polyether ether ketones (PEEK), polybenzimidazole, polyether sulfone (PES) and combinations thereof.

14. The method of claim 10 , wherein electric current passes through the thermoplastic film containing carbon nanotubes to align the carbon nanotubes for no more than 60 minutes.

15. The method of claim 10 , wherein the resistivity of the thermoplastic film containing carbon nanotubes after passing electric current through the thermoplastic film is less than 3 Ω/sq.

16. The method of claim 10 , wherein the resistivity of the thermoplastic film containing carbon nanotubes after passing electric current through the thermoplastic film is less than 1×10 −4 Ω-cm.

17. The method of claim 10 , wherein the resistivity of the thermoplastic film containing carbon nanotubes after passing electric current through the thermoplastic film is about 8×10 −5 Ω-cm.

18. The method of claim 10 , wherein pulsed electric current passes through the thermoplastic film containing carbon nanotubes to prevent the thermoplastic film from reaching its melting temperature.

Assignees

• Goodrich Corp

Inventors

• Hu Jin
• Botura Galdemir Cezar
• Slane Casey
• Ching Nathaniel

Classifications

• C08J7/08

  Heat treatment · CPC title

• C01B2202/22

  Electronic properties · CPC title

• B64D15/12

  by electric heating (heating arrangements specially adapted for transparent or reflecting areas H05B3/84) · CPC title

• C08J2300/22

  Thermoplastic resins · CPC title

• H05B2214/04

  Heating means manufactured by using nanotechnology · CPC title