Method of manufacturing lithium ion battery cells

Patent metadata

Field	Value
Publication number	US-10483592-B2
Application number	US-201715691162-A
Country	US
Kind code	B2
Filing date	Aug 30, 2017
Priority date	Aug 30, 2017
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

A method of manufacturing a lithium ion battery cell. A non-aqueous liquid electrolyte solution is placed in contact with particles of a lithium ion-exchanged zeolite material for a time sufficient to remove water molecules from the liquid electrolyte solution. Thereafter, the liquid electrolyte solution may be introduced into an electrochemical cell assembly and hermetically sealed within a cell casing to form a lithium ion battery cell.

First claim

What is claimed is:

1. A method of manufacturing a lithium ion battery cell, the method comprising:
providing a non-aqueous liquid electrolyte solution comprising a lithium salt and a nonaqueous, aprotic organic solvent;
contacting the liquid electrolyte solution with particles of a microporous lithium ion-exchanged zeolite material such that water molecules are removed from the liquid electrolyte solution; and then
introducing the liquid electrolyte solution into an electrochemical cell assembly that includes a plurality of alternating positive and negative electrode layers having porous separator layers interposed in face-to-face contact between opposing faces of the positive and negative electrode layers,
wherein the liquid electrolyte solution is introduced into the electrochemical cell assembly such that the liquid electrolyte solution infiltrates the porous separator layers and wets the opposing faces of the positive and negative electrode layers, and
wherein the lithium ion-exchanged zeolite material comprises at least one dehydrated zeolite material having:
(i) pore openings defined by 9-membered rings and a framework type selected from the group consisting of: CHI, LOV, NAB, NAT, RSN, STT, or VSV, or
(ii) pore openings defined by 12-membered rings and a framework type selected from the group consisting of: AFI, AFR, AFS, AFY, ASV, ATO, ATS, BEA, BEC, BOG, BPH, CAN, CON, CZP, DFO, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, IWR, IWV, IWW, LTL, MAZ, MEI, MOR, MOZ, MSE, MTW, NPO, OFF, OSI, -RON, RWY, SAO, SBE, SBS, SBT, SFE, SFO, SOS, SSY, USI, or VET.

2. The method set forth in claim 1 wherein the lithium ion-exchanged zeolite material has pore openings configured to selectively adsorb water molecules from the liquid electrolyte solution, without removing molecules of organic solvent from the liquid electrolyte solution.

3. The method set forth in claim 1 wherein the liquid electrolyte solution is placed in contact with the particles of the lithium ion-exchanged zeolite material such that hydrofluoric acid molecules are removed from the liquid electrolyte solution prior to introducing the liquid electrolyte solution into the electrochemical cell assembly.

4. The method set forth in claim 1 wherein the liquid electrolyte solution is placed in contact with the particles of the lithium ion-exchanged zeolite material by mixing the liquid electrolyte solution with the particles of the lithium ion-exchanged zeolite material in a hermetically sealed vessel prior to introducing the liquid electrolyte solution into the electrochemical cell assembly.

5. The method set forth in claim 1 wherein the liquid electrolyte solution is placed in contact with the particles of the lithium ion-exchanged zeolite material by coating the particles of the lithium ion-exchanged zeolite material on wall surfaces of a flow-through substrate and flowing the liquid electrolyte solution through inner passageways of the flow-through substrate.

6. The method set forth in claim 1 wherein the lithium ion-exchanged zeolite material has pore openings with diameters or widths in the range of 3 angstroms to 7 angstroms.

7. The method set forth in claim 6 wherein the lithium ion-exchanged zeolite material has pore openings defined by 9-membered rings.

8. The method set forth in claim 1 wherein the lithium ion-exchanged zeolite material comprises at least one dehydrated zeolite material exhibiting an Si:Al ratio in the range of 1:1 to 2:1 and having a framework type selected from the group consisting of: CAN, FAU, GME, NAT, -RON, and combinations thereof.

9. The method set forth in claim 1 wherein the lithium ion-exchanged zeolite material comprises at least one dehydrated zeolite material exhibiting an Si:Al ratio in the range of 2:1 to 5:1 and having a framework type selected from the group consisting of: BOG, -CHI, EMT, FAU, LOV, LTL, MAZ, MEI, MOR, OFF, -RON, and combinations thereof.

10. The method set forth in claim 1 wherein the lithium ion-exchanged zeolite material comprises at least one dehydrated zeolite material exhibiting an Si:Al ratio of greater than 5:1 and having a framework type selected from the group consisting of: ASV, BEA, CON, GON, IFR, ISV, MTW, RSN, SFE, STT, VET, VSV, and combinations thereof.

11. The method set forth in claim 1 wherein the lithium salt comprises a lithium cation (Lit) and an anion selected from the group consisting of: ClO 4 − , AlCl 4 − , I − , Br − , SCN − , BF 4 − , B(C 6 H 5 ) 4 − , AsF 6 − , CF 3 SO 3 − , N(CF 3 SO 2 ) 2 − , PF 6 − , and combinations thereof.

12. The method set forth in claim 1 wherein the organic solvent is selected from the group consisting of: ethylene carbonate, propylene carbonate, dimethyl carbonate, diethyl carbonate, ethylmethylcarbonate, methyl formate, methyl acetate, methyl propionate, γ-butyrolactone, γ-valerolactone, 1,2-dimethoxyethane, 1,2-diethoxyethane, ethoxymethoxyethane, tetrahydrofuran, 2-methyltetrahydrofuran, and combinations thereof.

13. The method set forth in claim 1 comprising:
hermetically sealing the electrochemical cell assembly infiltrated with the liquid electrolyte solution in a cell casing to form a lithium ion battery cell.

14. The method set forth in claim 13 wherein the cell casing comprises a pouch, and wherein the pouch comprises an aluminum foil laminated between one or more polymer layers.

15. The method set forth in claim 13 comprising:
electrically connecting the lithium ion battery cell to one or more other lithium ion battery cells to form a battery module.

16. The method set forth in claim 1 wherein the lithium ion-exchanged zeolite material has pore openings defined by 12-membered rings, and wherein the lithium ion-exchanged zeolite material has pore openings with diameters or widths in the range of 6 angstroms to 8 angstroms.

17. The method set forth in claim 1 wherein the lithium ion-exchanged zeolite material has pore openings defined by 12-membered rings and a framework type selected from the group consisting of FAU or BEA.

18. The method set forth in claim 17 wherein the lithium ion-exchanged zeolite material comprises Zeolite Y or Zeolite Beta.

19. A method of manufacturing a lithium ion battery cell, the method comprising:
providing a non-aqueous liquid electrolyte solution comprising a lithium salt and a nonaqueous, aprotic organic solvent;
contacting the liquid electrolyte solution with particles of a microporous lithium ion-exchanged zeolite material such that water molecules are removed from the liquid electrolyte solution; and then
introducing the liquid electrolyte solution into an electrochemical cell assembly that includes a plurality of alternating positive and negative electrode layers having porous separator layers interposed in face-to-face contact between opposing faces of the positive and negative electrode layers,
wherein the liquid electrolyte solution is introduced into the electrochemical cell assembly such that the liquid electrolyte solution infiltrates the porous separator layers and wets the opposing faces of the positive and negative electrode layers,
wherein the lithium ion-exchanged zeolite material comprises at least one dehydrated zeolite material having 10-membered ring openings and an MWW framework type.

20. The method set forth in claim 19 wherein the lithium ion-exchanged zeolite material comprises MCM-22.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Xiao Xingcheng
• Verbrugge Mark W
• Cai Mei
• Zeng Sherman H

Classifications

• H01M10/0436

  Small-sized flat cells or batteries for portable equipment · CPC title

• H01M10/0585 Primary

  of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators · CPC title

• H01M2220/30

  Batteries in portable systems, e.g. mobile phone, laptop · CPC title

• H01M10/058 Primary

  Construction or manufacture · CPC title

• H01M2/021

  Electricity · mapped topic