Viscous sealing glass compositions for solid oxide fuel cells
US-2015125780-A1 · May 7, 2015 · US
US10483579B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10483579-B2 |
| Application number | US-201515580418-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 9, 2015 |
| Priority date | Jun 9, 2015 |
| Publication date | Nov 19, 2019 |
| Grant date | Nov 19, 2019 |
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A solid oxide fuel cell includes a metal support which is formed from a porous metal substrate and which supports a power generation cell. The metal support includes a power generating area (GA) in which the power generation cell is disposed, and a buffer area (BA) which is formed on an outer side of the power generating area (GA) in an in-plane direction. A pore in the metal support in the buffer area (BA) is filled with a material with a thermal conductivity lower than that of a formation material of the metal support.
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The invention claimed is: 1. A solid oxide fuel cell comprising: a metal support which is formed from a porous metal substrate and which supports a power generation cell, wherein the metal support includes a power generating area in which the power generation cell is disposed, a buffer area which is formed on an outer side of the power generating area in an in-plane direction, and an outer peripheral area which is formed on an outer side of the buffer area in the in-plane direction, the metal support is located on the anode side of the power generation cell, a separator is located on the anode side of the power generation cell such that a void region is formed between the separator and the buffer area of the metal support, the power generation cell is formed as a stacked body of an anode electrode, a solid oxide electrolyte, and a cathode electrode, and a pore in the metal support in the buffer area is filled with a filler material with a thermal conductivity lower than that of a formation material of the metal support. 2. The solid oxide fuel cell according to claim 1 , wherein the metal support in the buffer area is formed into a dense layer which does not allow permeation of gas in a thickness direction. 3. The solid oxide fuel cell according to claim 2 , wherein a gas is made to flow in a flow path space next to the buffer area, the gas having the same temperature as a gas made to flow in a flow path space next to the power generating area. 4. The solid oxide fuel cell according to claim 1 , wherein a pore diameter of the metal support in a boundary neighborhood portion of the buffer area adjacent to the power generating area is smaller than a pore diameter of the metal support in the power generating area. 5. The solid oxide fuel cell according to claim 1 , wherein the buffer area is a non-power generating area. 6. The solid oxide fuel cell according to claim 1 , wherein the material in the pore in the metal support in the buffer area comprises a ceramic material. 7. The solid oxide fuel cell according to claim 1 , wherein the filler material comprises yttria-stabilized zirconia (YSZ). 8. The solid oxide fuel cell according to claim 1 , wherein the filler material comprises lanthanum strontium magnesium gallate (LSGM). 9. The solid oxide fuel cell according to claim 1 , wherein the filler material comprises samarium-doped ceria (SDC). 10. The solid oxide fuel cell according to claim 1 , wherein the filler material comprises gadolinium-doped ceria (GDC). 11. The solid oxide fuel cell according to claim 1 , wherein the filler material comprises scandium-stabilized zirconia (SSZ). 12. The solid oxide fuel cell according to claim 1 , wherein a thickness of the power generating area and a thickness of the buffer area are smaller than a thickness of the outer peripheral area. 13. The solid oxide fuel cell according to claim 1 , wherein a thermal conductivity of the buffer area is lower than a thermal conductivity of the power generating area, and the thermal conductivity of the buffer area is lower than a thermal conductivity of the outer peripheral area. 14. The solid oxide fuel cell according to claim 1 , wherein a thermal capacity of the buffer area is larger than a thermal capacity of the power generating area, and the thermal capacity of the buffer area is larger than a thermal capacity of the outer peripheral area. 15. The solid oxide fuel cell according to claim 1 , further comprising a pair of separators that sandwich the metal support therebetween; and a pair of seal frames that sandwich a portion of the pair of separators and a portion of the metal support therebetween. 16. The solid oxide fuel cell according to claim 15 , wherein the outer peripheral area of the metal support is the portion of the metal support sandwiched by the pair of seal frames.
characterised by the supporting layer · CPC title
Oxides · CPC title
Grouping of unit cells of planar configuration · CPC title
Fuel cells with solid oxide electrolytes · CPC title
Metals or alloys · CPC title
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