Method and system for eliminating reverse current decay in fuel cells

Patent metadata

Field	Value
Publication number	US-10483569-B2
Application number	US-201515320824-A
Country	US
Kind code	B2
Filing date	Jun 29, 2015
Priority date	Jun 30, 2014
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

The invention relates to a system and a method for eliminating reverse current decay in the fuel cells. According to the invention, the system comprises
a fuel cell having an anode and a cathode; a fuel feed system for supplying the anode of the fuel cell with fuel and forming an anode system; a bypass line fitted in parallel and in flow connection with said anode system and capable of circulating fuel past the anode; an oxygen reduction unit; and a pressure unit for circulating gas in at least part of said anode system and said bypass line.

The bypass line is adapted to receive and circulate a flow of hydrogen during a fuel cell shutdown in order to mix the hydrogen with any oxygen present in the anode system, and to remove the oxygen from the anode system in said oxygen reduction unit by catalytic conversion. A control unit for receiving sensing signals representative of the state of the oxygen reduction process and controlling the amount of hydrogen passing through the system in response to said sensor is also described.

First claim

The invention claimed is:

1. A system for eliminating reverse current decay in fuel cells, comprising:
a fuel cell having an anode and a cathode;
a fuel feed system for supplying the anode of the fuel cell with fuel and comprising an anode fuel feed line for supplying the anode with fuel from the fuel feed system and a fuel return line for circulating unused fuel from the anode back to said fuel feed system;
a bypass line fitted between said anode fuel feed line and said fuel return line in parallel and in flow connection with said anode system and capable of circulating fuel past the anode in a loop;
an oxygen reduction unit included in said bypass line;
a branch from said anode fuel feed line provided with a valve for feeding hydrogen to said bypass line and said oxygen reduction unit during a fuel cell shutdown; and
a pressure unit for circulating gas in at least part of said anode system and said bypass line;

wherein the bypass line is adapted to receive and circulate a flow of hydrogen during a fuel cell shutdown in order to mix the hydrogen with any oxygen present in the anode system, and to remove the oxygen from the anode system in said oxygen reduction unit by catalytic conversion.

2. The system according to claim 1 , wherein the oxygen reduction unit is disposed in said bypass line.

3. The system according to claim 2 , wherein the oxygen reduction unit in said bypass line is combined with a slipstream filter for removing impurities from the gas flow.

4. The system according to claim 1 , wherein the system further comprises a control unit for receiving sensing signals representative of the state of the oxygen reduction process in said oxygen reduction unit from at least one sensor, and wherein the control unit in response to said sensor signals controls the amount of hydrogen passing through said valve.

5. A method for minimizing the amount of oxygen present in an anode system of a fuel cell during shutdown, comprising the steps of:
providing a fuel cell with a cathode and an anode and a fuel feed system comprising an anode fuel feed line for supplying the anode with fuel and a fuel return line for circulating unused fuel from the anode back to said fuel feed system;
providing a bypass line fitted in parallel and in flow connection with said anode system capable of circulating fuel past the anode;
feeding during a fuel cell shutdown condition a flow of hydrogen into said bypass line in order to mix the hydrogen with any oxygen present in the anode system:
circulating the gas flow in said bypass line in a loop including said anode fuel feed line and said fuel return line to an oxygen reduction unit;
receiving sensing signals representative of the state of the oxygen reduction process in said oxygen reduction unit from at least one sensor, and controlling in response to said sensor signals the appropriate amount of hydrogen fed to the oxygen reduction unit;
reducing in said oxygen reduction unit any oxygen present in the anode system by catalytic conversion.

6. The method according to claim 5 , further comprising the additional step of filtering the gas in said bypass line in order to remove any impurities from the gas flow.

7. The method according to claim 5 , wherein gas in said bypass line is circulated in a loop including said anode fuel feed line and said fuel return line.

Assignees

• Teknologian Tutkimuskeskus Vtt Oy

Inventors

• Ihonen Jari

Classifications

• H01M8/04097 Primary

  with recycling of the reactants (H01M8/04119, H01M8/04104 take precedence) · CPC title

• H01M8/04492

  Humidity; Ambient humidity; Water content · CPC title

• H01M8/04425

  at auxiliary devices, e.g. reformers, compressors, burners · CPC title

• H01M8/04455 Primary

  of cathode reactants at the inlet or inside the fuel cell · CPC title

• H01M8/04303 Primary

  applied during shut-down · CPC title