Lithium metal anode electrode

Patent metadata

Field	Value
Publication number	US-10483534-B2
Application number	US-201514797331-A
Country	US
Kind code	B2
Filing date	Jul 13, 2015
Priority date	Jul 16, 2014
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

A lithium metal anode electrode includes (a) a porous conductive layer including a current collector layer that is porous and has a plurality of first pores, at least parts of the first pores extending through the current collector layer; and a conduction loading layer composed of a porous material that does not alloy with lithium, disposed proximate to the current collector layer, and that having a plurality of second pores, at least parts of the second pores extending through the conduction loading layer; and (b) a lithium metal active material layer composed of lithium metal disposed proximate to the porous conductive layer. Parts of the first and second pores are connected and expose the lithium metal active material layer for electrochemical reactions. The first and second pores have respective surface areas that are adapted for lithium deposition so that a stable SEI layer can be formed thereon.

First claim

What is claimed is:

1. A lithium metal anode electrode, comprising:
(a) a single active layer that consists of a pore-free layer of non-porous lithium metal; and
(b) a porous conductive layer that is disposed on the single active layer so that the single active layer is exposed for electrochemical reactions through the porous conductive layer, and that comprises:
a current collector layer that has a plurality of pores defined therein at least a portion of which extend through the current collector layer; and
a conduction loading layer electrically connected to the single active layer, the conduction loading layer having a plurality of pores defined therein at least a portion of which extend through the conduction loading layer, that comprises a porous material that does not alloy with lithium, and that is disposed proximate to the current collector layer,

wherein the porous conductive layer has a surface area effective for lithium deposition in use so that a stable solid-electrolyte interphase (SEI) layer is formed thereon.

2. The lithium metal anode electrode of claim 1 , wherein the single active layer is disposed adjacent to the current collector layer of the porous conductive layer.

3. The lithium metal anode electrode of claim 1 , wherein the single active layer is disposed adjacent to the conduction loading layer of the porous conductive layer.

4. The lithium metal anode electrode of claim 1 , wherein the porous conductive layer has a surface which is distanced from the single active layer and on which is disposed an isolation region which is electrically isolated and which comprises an isolation layer.

5. The lithium metal anode electrode of claim 1 , further comprising an ionic conducting layer that is disposed between the single active layer and the porous conductive layer, and that is chemically inert to the lithium metal of the single active layer.

6. The lithium metal anode electrode of claim 5 , wherein the ionic conducting layer is electrically conductive.

7. The lithium metal anode electrode of claim 5 , wherein the ionic conducting layer is structured to have a porous structure, a grid structure, a mesh structure, a rod structure or a combination thereof.

8. The lithium metal anode electrode of claim 5 , wherein the ionic conducting layer comprises a material selected from the group consisting of a ceramic material, a polymeric material, a liquid-phase electrolyte, a solid-phase electrolyte, a gel-type electrolyte, a liquid ion, a conductive material, and a combination thereof.

9. The lithium metal anode electrode of claim 1 , wherein the current collector layer comprises at least one material selected from the group consisting of copper, nickel, iron, gold, zinc, silver, titanium, and a material that does not alloy with lithium.

10. The lithium metal anode electrode of claim 1 , wherein the current collector layer and the conduction loading layer are integrated.

11. The lithium metal anode electrode of claim 1 , wherein the conduction loading layer is a porous metal layer.

12. The lithium metal anode electrode of claim 11 , wherein the porous metal layer comprises at least one material selected from the group consisting of copper, nickel, iron, gold, zinc, silver, titanium and a material that does not alloy with lithium.

13. The lithium metal anode electrode of claim 1 , wherein the conduction loading layer is a conductive film comprising at least a conductive material.

14. The lithium metal anode electrode of claim 13 , wherein the conductive material is at least one conductive material selected from the group consisting of graphite, graphene, carbon particles, carbon tubes, and metal particles.

15. The lithium metal anode electrode of claim 1 , wherein the anode electrode further comprises a metal film covering the conduction loading layer.

16. The lithium metal anode electrode of claim 15 , wherein the metal film comprises at least one material selected from the group consisting of copper, nickel, iron, gold, zinc, silver, titanium and a material that does not alloy with lithium.

17. The lithium metal anode electrode of claim 8 , wherein the ceramic material comprises metal oxides, metal sulfides, metal nitrides, metal phosphates, an acidized metal or a combination thereof.

18. The lithium metal anode electrode of claim 8 , wherein the conductive material is at least one conductive material selected from the group consisting of graphite, graphene, carbon particles, carbon tubes, and metal particles.

19. The lithium metal anode electrode of claim 1 , wherein the material of the conduction loading layer that does not alloy with lithium is a material that is chemically inert to the lithium metal of the single active layer.

20. A lithium metal anode electrode, comprising:
(a) a single active layer that consists of a pore-free layer of non-porous lithium metal; and
(b) a porous conductive layer that is disposed on the single active layer so that the single active layer is exposed for electrochemical reactions through the porous conductive layer, and that comprises:
(i) a current collector layer that is disposed in contact with the single active layer, that has a plurality of pores defined therein at least some of which extend through the current collector layer; and
(ii) a conduction loading layer electrically connected to the single active layer, the conduction loading layer having a plurality of pores defined therein at least a portion of which extend through the conduction loading layer, that comprises a porous material that does not alloy with lithium, and that is disposed proximate to the current collector layer,
(iii) a metal film formed to cover surfaces of the conduction loading layer including surfaces of the plurality of pores defined therein,

wherein the porous conductive layer has a surface area effective for lithium deposition in use so that a stable solid-electrolyte interphase (SEI) layer is formed thereon.

Assignees

• Prologium Holding Inc

Inventors

• Yang Szu-Nan

Classifications

• H01M4/80 Primary

  Porous plates, e.g. sintered carriers · CPC title

• H01M4/624

  Electric conductive fillers · CPC title

• H01M4/72

  Grids · CPC title

• H01M4/742

  perforated material · CPC title

• H01M2004/027

  Negative electrodes · CPC title