Dual function current collector

Patent metadata

Field	Value
Publication number	US-10483523-B2
Application number	US-201715436574-A
Country	US
Kind code	B2
Filing date	Feb 17, 2017
Priority date	Feb 19, 2016
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

A battery can include a separator, a first current collector, a protective layer, and a first electrode. The first current collector and the protective layer can be disposed on one side of the separator. The first electrode can be disposed on an opposite side of the separator as the first current collector and the protective layer. Subjecting the battery to an activation process can cause metal to be extracted from the first electrode and deposited between the first current collector and the protective layer. The metal can be deposited to at least form a second electrode between the first current collector and the protective layer.

First claim

What is claimed is:

1. A battery, comprising:
a separator;
a first current collector;
a protective layer disposed on the first current collector, the protective layer comprising a polymer and/or a polymer composite that is impenetrable to dendrites comprising a first electrode that is formed in situ between the protective layer and the first current collector, the first current collector and the protective layer being disposed on one side of the separator, and the protective layer being non-ionically conductive in an absence of an electrolyte; and
a second electrode, the second electrode being disposed on an opposite side of the separator as the first current collector and the protective layer;
wherein subjecting the battery to an activation process causes metal to be extracted from the second electrode and deposited between the first current collector and the protective layer, wherein the deposit of the metal forms the first electrode between the first current collector and the protective layer, and wherein the protective layer prevents the dendrites comprising the first electrode from penetrating the separator.

2. The battery of claim 1 , wherein the activation process comprises charging the battery.

3. The battery of claim 1 , wherein the activation process comprising charging the battery at less than ½ C rate and/or greater than 2 volts.

4. The battery of claim 1 , wherein the first current collector comprises copper (Cu) and/or plated copper.

5. The battery of claim 1 , wherein the first current collector comprises copper foil, stainless steel foil, titanium (Ti) foil, nickel (Ni) plated copper foil, aluminum (Al) plated copper foil, and/or titanium plated copper foil.

6. The battery of claim 1 , wherein the first current collector has a thickness of 10 microns.

7. The battery of claim 1 , wherein the second electrode is formed from a metal oxide, a metal fluoride, a metal sulfide, and/or a doped salt.

8. The battery of claim 1 , wherein the second electrode is formed from a lithium cobalt oxide (LiCoO 2 ), lithium nickel cobalt oxide (LiNiCoO 2 ), lithium manganese nickel cobalt oxide (LiNiMnCoO 2 ), lithium manganese silicon oxide (Li 2 MnSiO 4 ), lithium iron phosphate (LiFePO 4 ), lithium fluoride (LiF), and/or lithium sulfide (Li 2 S).

9. The battery of claim 1 , wherein the metal extracted from the second electrode comprises lithium metal.

10. The battery of claim 1 , wherein the protective layer is formed from a crosslinked polymer and/or a non-crosslinked polymer.

11. The battery of claim 1 , wherein the protective layer further includes one or more additives, and wherein the one or more additives comprise ceramic particles, metal salt particles, and/or metal stabilizers.

12. The battery of claim 1 , wherein the battery further includes the electrolyte, and wherein a presence of the electrolyte renders the protective layer ionically conductive.

13. The battery of claim 12 , wherein the electrolyte comprises a liquid electrolyte, the liquid electrolyte including metal ions, and wherein the liquid electrolyte further includes one or more organic solvents.

14. The battery of claim 13 , wherein the metal irons comprise lithium ions, and wherein the one or more organic solvents comprise ethylene carbonate ((CH 2 O) 2 CO) and/or lithium hexafluorophosphate (Li 1 PF 6 ).

15. The battery of claim 12 , wherein the electrolyte comprises a solid-state electrolyte.

16. The battery of claim 15 , wherein the solid-state electrolyte comprises a glass-ceramic binary sulfide electrolyte and/or a polymer electrolyte.

17. The battery of claim 1 , wherein the battery further comprises a second current collector, the second current collector being coupled with the second electrode.

18. The battery of claim 17 , wherein the battery further comprises a safety layer deposited on the second current collector, and wherein the safety layer is configured to respond to a temperature trigger and/or a voltage trigger.

19. The battery of claim 1 , wherein the activation process causes a reduction at the second electrode, the reduction extracting metal from the second electrode, and the metal extracted from the second electrode being deposited between the first current collector and the protective layer to form the first electrode in situ between the first current collector and the protective layer.

Assignees

• American Lithium Energy Corp

Inventors

• Fan Jiang

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M4/0445 Primary

  Forming after manufacture of the electrode, e.g. first charge, cycling · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M4/661

  Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence) · CPC title