Hybrid high-temperature swing adsorption and fuel cell
US-2017141421-A1 · May 18, 2017 · US
US10480403B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10480403-B2 |
| Application number | US-201615364299-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 30, 2016 |
| Priority date | Feb 22, 2016 |
| Publication date | Nov 19, 2019 |
| Grant date | Nov 19, 2019 |
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A combustor having an ion transport membrane therein and an adjustable swirler, which is mechanically connected at an inlet of a combustion zone of the combustor; a combustion system comprising the combustor, a feedback control system adapted to adjust swirler blades of the combustor based on a compositional variation of a fuel stream, and a plurality of feedback control systems to control operational variables within the combustor for an efficient oxy-combustion; and a process for combusting a fuel stream via the combustion system. Various embodiments of the combustor, the combustion system, and the process for combusting the fuel stream are disclosed.
Opening claim text (preview).
The invention claimed is: 1. A combustion system, comprising: a combustor comprising: a cylindrical vessel with an internal cavity, an ion transport membrane that divides the internal cavity of said cylindrical vessel into a first and a second concentric cylindrical zone, wherein the first concentric cylindrical zone is a feed zone and the second concentric cylindrical zone is a combustion one, a first inlet and a first outlet located in the feed zone, and a second inlet and a second outlet located in the combustion zone, and a swirler that is connected to the second inlet, wherein the swirler has adjustable blades with adjustable angles: an oxygen supplier located upstream of and fluidly connected to the first inlet via a feed line for supplying an oxygen-containing stream; a fuel supplier located upstream of and fluidly connected to the second inlet via a fuel line for supplying a fuel stream; an expander located downstream of and fluidly connected to the second outlet via an exhaust line for expanding an exhaust stream to generate power; a recycle line that fluidly connects the exhaust line to the fuel line; a mixer located upstream of the combustor and fluidly connected to the fuel line and the recycle line configured to mix the fuel stream with the exhaust stream; an oxygen-depleted line fluidly connected to the first outlet; and a primary heat exchanger disposed on the recycle line and fluidly connected to the oxygen-depleted line, wherein the primary beat exchanger is located downstream of the first outlet and upstream of the mixer, and is configured to heat exchange the exhaust stream with an oxygen-depleted stream that egresses the first outlet to raise a temperature of the exhaust stream. 2. The combustion system of claim 1 , further comprising: a swirler control unit comprising a first gas analyzer disposed on the fuel line configured to determine a composition of the fuel stream, a second gas analyzer disposed on the exhaust line configured to determine a composition of the exhaust stream, an actuator connected to the adjustable blades of the swirler configured to adjust an angle of the adjustable blades, and a processor that is configured to receive a first signal from the first gas analyzer and a second signal from the second gas analyzer, and to transmit a first output signal to the actuator, wherein the swirler control unit is configured to adjust an angle of the adjustable blades based on the composition of the fuel stream and the exhaust stream. 3. The combustion system of claim 2 , further comprising: a flow control unit comprising: the first gas analyzer disposed on the fuel line configured to determine the composition of the fuel stream, a flowmeter disposed on the fuel line configured to determine a volumetric flow rate of the fuel stream, a first control valve disposed on the feed line configured to control a volumetric flow rate of the oxygen-containing stream, a flow controller that is configured to receive the first signal from the first gas analyzer and a flow rate signal from the flowmeter, and to transmit a second output signal to the first control valve, wherein the flow control unit is configured to control the volumetric flow rate of the oxygen-containing stream based on the composition and volumetric flow rate of the fuel stream. 4. The combustion system of claim 3 , further comprising: a temperature control unit comprising: a temperature sensor disposed on the exhaust line configured to determine the temperature of the exhaust stream, a second control valve disposed on the recycle line configured to control a volumetric flow rate of the exhaust stream, a temperature controller configured to receive a temperature signal from the temperature sensor, and to transmit a third output signal to the second control valve, wherein the temperature control unit is configured to control a temperature of the fuel stream based on the temperature of the exhaust stream. 5. The combustion system of claim 1 , further comprising: a secondary heat exchanger disposed on the feed line and fluidly connected to the oxygen-depleted line, wherein the secondary heat exchanger is located upstream of the first inlet and downstream of the first outlet, and is configured to heat exchange the oxygen-containing stream with the oxygen-depleted stream that egresses the first outlet. 6. The combustion system of claim 1 , further comprising: a condenser located downstream of and fluidly connected to the expander via the exhaust line configured to separate a liquid phase from the exhaust stream. 7. The combustion system of claim 1 , wherein the combustor further comprises: a third concentric cylindrical zone sandwiched between the first and the second concentric cylindrical zones, defining a sweep zone; and a third inlet and a third outlet located in the sweep zone. 8. The combustion system of claim 7 , wherein the recycle line fluidly connects the exhaust line to the third inlet. 9. The combustion system of claim 1 , wherein the swirler comprises a plurality of the adjustable blades extending radially from a shaft, wherein each blade of the plurality of the adjustable blades has a longitudinal axis and an angle of the longitudinal axis of said each blade is adjustable relative to a longitudinal axis of the shaft. 10. The combustion system of claim 9 , wherein the angle of the longitudinal axis of said each blade is adjustable in the range of 0 to 85 degrees relative to the longitudinal axis of the shaft. 11. The combustion system of claim 1 , wherein the combustor further comprises a third concentric cylindrical zone which is sandwiched between the first and the second concentric cylindrical zones, defining a sweep zone, and a third inlet and a third outlet located in the sweep zone. 12. A process for combusting a fuel stream with a combustor comprising: a cylindrical vessel with an internal cavity; an ion transport membrane that divides the internal cavity of said cylindrical vessel into a first and a second concentric cylindrical tone, wherein the first concentric cylindrical zone is a feed zone and the second concentric cylindrical zone is a combustion zone; a first inlet and a first outlet located in the feed zone, and a second inlet and a second outlet located in the combustion zone; a swirler that is connected to the second inlet, wherein the swirler has adjustable blades with adjustable angles; a third concentric cylindrical zone which is sandwiched between the first and the second concentric cylindrical zones, defining a sweep zone; and a third inlet and a third outlet located in the sweep zone, the process comprising: combusting the fuel stream with molecular oxygen in the combustion zone to form an exhaust stream comprising water vapor and carbon dioxide; delivering an oxygen-containing stream to the first inlet of the combustor, wherein molecular oxygen present in the oxygen-containing stream is transported to the sweep zone through the ion transport membrane; flowing a portion of the exhaust stream into the third inlet of the combustor to sweep the molecular oxygen away from the sweep zone and to form an oxygen-enriched stream; mixing the oxygen-enriched stream with the fuel stream in a mixer to form a combustion mixture; and delivering the combustion mixture to the second inlet of the combustor, wherein the combustion mixture is expanded and/or agitated in the combustion zone via the swirler and is combusted to form the exhaust stream; and repeating the flowing, the mixing, and the delivering. 13. The process of claim 12 , wherein the fuel stream is a syngas stream.
using detectors sensitive to combustion gas properties (F23N5/02, F23N5/18 - F23N5/26 take precedence) · CPC title
characterised by the fuel supply (burners F23D) · CPC title
Swirling means inside the mixing tube or chamber to improve premixing · CPC title
the fuel or oxidant being gaseous at standard temperature and pressure (F02C3/28 takes precedence) · CPC title
by using swirl vanes · CPC title
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