Method for activating metal surfaces to be phosphated

Patent metadata

Field	Value
Publication number	US-10480080-B2
Application number	US-201515302365-A
Country	US
Kind code	B2
Filing date	Apr 7, 2015
Priority date	Apr 11, 2014
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

A method of activating a metal surface, such as a galvanized steel sheet, before a phosphating process, may involve bringing the metal surface into contact with an activating bath containing activating particles, which may be based on phosphate and/or titanium, dispersed in water. To alleviate or even eliminate the problems of poor adhesion of surface coatings to preferably electrolytically galvanized, phosphated metal strip, an additive that suppresses or at least slows agglomeration of the activating particles may be added to the activating bath. In some examples, polyethylene glycol (PEG) and/or sodium stearate may be added. Further, the particle size distribution of the activating particles present in the activating bath may be determined and the activating bath may be replaced or taken out of operation as a function of the particle size distribution of the activating particles.

First claim

The invention claimed is:

1. A method for activating a metal surface prior to a phosphating process, the method comprising:
adding to an activating bath of activating particles dispersed in water an additive that suppresses or at least slows agglomeration of the activating particles, wherein the activating particles are based on at least one of phosphate or titanium;
adding to the activating bath a surfactant for suppressing or slowing agglomeration of the activating particles, wherein the surfactant is at least one of polyethylene glycol or sodium stearate; and
bringing the metal surface into contact with the activating bath.

2. The method of claim 1 wherein the metal surface is a coated metal surface.

3. The method of claim 1 wherein the metal surface is a galvanized steel sheet.

4. The method of claim 1 further comprising agitating the activating bath continuously or discontinuously by at least one of stirring, pumped circulation, or ultrasound.

5. The method of claim 4 wherein the agitating occurs at least when the additive is added to the activating bath and when the metal surface is brought into contact with the activating bath.

6. The method of claim 5 further comprising stirring the activating bath by a mechanical stirrer.

7. The method of claim 1 further comprising:
determining a particle size distribution of the activating particles in the activating bath; and
replacing the activating bath based on the particle size distribution of the activating particles.

8. The method of claim 7 wherein the determining of the particle size distribution of the activating particles occurs either continuously or periodically by way of dynamic light scattering during operation of the activating bath.

9. The method of claim 7 wherein the determining of the particle size distribution of the activating particles occurs either continuously or periodically by way of nanoparticle tracking analysis during operation of the activating bath.

10. The method of claim 1 further comprising adjusting the activating bath to have an activating particle concentration in a range of 0.1 g/l to 10 g/l.

11. The method of claim 1 further comprising adjusting the activating bath to have an activating particle concentration in a range of 0.5 g/l to 3 g/l.

12. The method of claim 1 further comprising adjusting the activating bath to have an activating particle concentration in a range of 0.7 g/l to 1.5 g/l.

13. A method for activating a metal surface for a phosphating process, the method comprising:
galvanizing the metal surface in an electrolytic cell;
adding to an activating bath of activating particles dispersed in water an additive that suppresses or at least slows agglomeration of the activating particles, wherein the activating particles are based on at least one of phosphate, titanium, or metal oxides;
determining a particle size distribution of the activating particles in the activating bath;
replacing the activating bath based on the particle size distribution of the activating particles; and
bringing the metal surface into contact with the activating bath.

14. The method of claim 13 further comprising rinsing the metal surface after the metal surface is galvanized.

15. The method of claim 13 further comprising squeezing, wiping, or blowing the metal surface a liquid film from the metal surface after the metal surface exits the activating bath.

16. The method of claim 15 further comprising spraying a phosphating solution onto the metal surface after the metal surface exits the activating bath.

17. The method of claim 13 further comprising spraying a phosphating solution onto the metal surface after the metal surface exits the activating bath.

Assignees

• Thyssenkrupp Steel Europe Ag
• Thyssenkrupp Ag

Inventors

• Junge Fabian
• Müller Gregor
• Weiher Nicole
• Meyring Heinrich
• Panter Frank

Classifications

• C23C18/30 Primary

  Activating {or accelerating or sensitising with palladium or other noble metal} · CPC title

• C23C22/78

  Pretreatment of the material to be coated · CPC title

• C23C22/80 Primary

  with solutions containing titanium or zirconium compounds · CPC title

• C23F17/00

  Multi-step processes for surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by subclass C21D or C22F or class C25 (coating for obtaining at least two superposed coatings either by methods not provided for in a single one of main groups C23C2/00 - C23C26/00, or by combinations of methods providedfor in subclasses C23C and C25D, C23C28/00) · CPC title

• C23C22/07

  containing phosphates · CPC title