Process for preparing acrylic acid

Patent metadata

Field	Value
Publication number	US-10479751-B2
Application number	US-201414915929-A
Country	US
Kind code	B2
Filing date	Aug 11, 2014
Priority date	Sep 2, 2013
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

The present invention provides an apparatus comprising a feed arranged below the middle of the apparatus, a quenching agent inlet arranged above the feed, an outlet arranged below the feed and a draw arranged above the quenching agent inlet, the apparatus having a region provided with one or more packing elements, wherein at least one means which ensures the formation of a liquid layer having a height of at least 1 cm is present between the quenching agent inlet and a packing element present between the quenching agent inlet and feed. The present invention also provides a process for preparing acrylic acid, which includes a step of oxidizing acrolein, wherein the reaction mixture obtained in this oxidation is contacted with water as quenching agent in an inventive apparatus, and a composition obtainable as bottom product in the process according to the invention, comprising acrylic acid and water.

First claim

The invention claimed is:

1. An apparatus consisting essentially of
a feed containing a reaction mixture arranged below the middle of the apparatus,
a quenching agent inlet arranged above the feed,
an outlet arranged below the feed and
a draw arranged above the quenching agent inlet,

the apparatus having, between the quenching agent inlet and the feed containing the reaction mixture, a region provided with one or more packing elements, wherein 2 or 3 sieve trays or ripple trays which ensure the formation of a liquid layer having a height of at least 1 cm is present between the quenching agent inlet and a packing element present between the quenching agent inlet and feed containing the reaction mixture, the liquid layer being arranged in the apparatus such that gaseous substances which pass through the feed containing the reaction mixture into the apparatus have to pass through the liquid layer in order to get into the top of the apparatus.

2. The apparatus according to claim 1 , wherein the liquid layer has a height of 2 to 10 cm.

3. The apparatus according to claim 1 wherein the packing element is a structured packing element or a fabric packing element.

4. The apparatus according to claim 1 , wherein the packing element has a height of 50 to 85% of the internal height of the apparatus.

5. The apparatus according to claim 1 , wherein a distributor present between a lowermost sieve trays or ripple trays and the uppermost packing element distributes the liquid phase flowing downward from the lowermost sieve trays or ripple trays over the packing element.

6. The apparatus according to claim 5 , wherein a collector arranged between the lowermost sieve trays or ripple trays and distributor collects the liquid phase flowing downward from the lowermost sieve trays or ripple trays and feeds liquid phase to the distributor.

7. A process for preparing acrylic acid, including a step of oxidizing acrolein, wherein the reaction mixture obtained in this oxidation is contacted with water as quenching agent in an apparatus consisting essentially of
a feed containing a reaction mixture arranged below the middle of the apparatus,
a quenching agent inlet arranged above the feed,
an outlet arranged below the feed and
a draw arranged above the quenching agent inlet,

the apparatus having, between the quenching agent inlet and the feed containing the reaction mixture, a region provided with one or more packing elements, wherein 2 or 3 sieve trays or ripple trays which ensure the formation of a liquid layer having a height of at least 1 cm is present between the quenching agent inlet and a packing element present between the quenching agent inlet and feed containing the reaction mixture, the liquid layer being arranged in the apparatus such that gaseous substances which pass through the feed containing the reaction mixture into the apparatus have to pass through the liquid layer in order to get into the top of the apparatus.

8. The process according to claim 7 , wherein the ratio of the volume flow rates of the quenching agent which is fed to the apparatus and the reaction mixture which is fed to the apparatus is from 1:2 to 1:20.

9. The process according to claim 7 , wherein the temperature of the liquid phase on the sieve trays or ripple trays is from 50° C. to 100° C.

10. The process according to claim 7 , wherein the pressure differential between the pressure measured at the top of the apparatus and the pressure measured in the gas space of the liquid phase in the bottom of the apparatus is from 10 mbar to 60 mbar.

11. The process according to claim 7 wherein the apparatus is fed with 210 to 380 kg of reaction mixture per hour per m 3 of apparatus volume.

12. The apparatus according to claim 2 , wherein the liquid has a height of 3 to 8 cm.

13. The apparatus according to claim 3 , wherein the packing element is a structured packing.

14. The process according to claim 8 , wherein the ratio of the volume flow rates of the quenching agent which is fed to the apparatus and the reaction mixture which is fed to the apparatus is from 1:5 to 1:10.

15. The process according to claim 9 , wherein the temperature of the liquid phase on the sieve trays or ripple trays is from 70° C. to 80° C.

16. The process according to claim 10 , wherein the apparatus is operated in such a way that the pressure differential between the pressure measured at the top of the apparatus and the pressure measured in the gas space of the liquid phase in the bottom of the apparatus is from 30 mbar to 40 mbar.

Assignees

• Evonik Degussa Gmbh

Inventors

• Mosler Jürgen
• Psiorz Christian
• Kuppinger Franz-Felix
• Schriewer Raphael
• Bruhns Arnd
• Rix Armin
• Kreis Peter
• Meier Ralf
• Elder James Edward

Classifications

• B01D3/009

  in combination with chemical reactions · CPC title

• B01D3/163

  Plates with valves · CPC title

• B01J2219/3325

  Counter-current flow · CPC title

• B01J19/30

  Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer · CPC title

• C07C51/252 Primary

  of propene, butenes, acrolein or methacrolein · CPC title