Struvite-K and Syngenite composition for use in building materials

Patent metadata

Field	Value
Publication number	US-10479728-B2
Application number	US-201415028372-A
Country	US
Kind code	B2
Filing date	Oct 14, 2014
Priority date	Aug 12, 2013
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

A composition and process for manufacture thereof used in hybrid inventive building materials comprising Syngenite (K 2 Ca(SO 4 ) 2 .H 2 O) and Struvite-K (KMgPO 4 .6H 2 O). Starting constituents include magnesium oxide (MgO), monopotassium phosphate (MKP) and stucco (calcium sulfate hemihydrate), mixed in predetermined ratios, cause reactions to proceed through multiple phases, which reactions variously are proceeding simultaneously and in parallel. Variables, e.g., water temperature, pH, mixing times and rates, have been found to affect resultant reaction products. Preferred ratios of chemical constituents and manufacturing parameters, including predetermined weight percent and specified ratios of Struvite-K and Syngenite are provided for building products used for specified purposes. Reactions are optimized in stoichiometry and additives to reduce the combined heat of formation to non-destructive levels. Various additives help control and guide reactions. Building products, such as board panels, include the resultant composition. A significant amount of the composition is disposed adjacent a building panel face.

First claim

What is claimed is:

1. A process for the continuous manufacture of a building product comprising:
a) providing a mixer reaction chamber;
b) continuously combining together constituent materials into the mixer reaction chamber; wherein the constituent materials comprise the following compounds in specified ranges by weight percent:
MgO: 3.33 to 70.00%
KH 2 PO 4 : 4.67 to 70.00%
stucco hemihydrate (CaSO 4 .½H 2 O): 10.5 to 90.0%
and addition of water: 15 to 60% of the constituent solid materials;

c) continuously mixing the constituent materials within said mixing reaction chamber for a length of time sufficient to produce a slurry;
d) withdrawing the slurry from the mixer reaction chamber; and
e) utilizing said slurry in the manufacture of the building product.

2. The process according to claim 1 wherein the specified ranges by weight percent of said compounds are:
MgO: 10.0 to 40.0%
KH 2 PO 4 : 40.0 to 70.00%
stucco hemihydrate: 25.0 to 75.0%
and an addition of water in an amount of 15 to 60% by weight relative to the solid constituents.

3. The process according to claim 1 wherein the ratio of MgO to KH 2 PO 4 is between 1:1.0 and 1:3.37.

4. The process according to claim 3 wherein the ratio of MgO to KH 2 PO 4 is between 1:1.8 and 1:2.2.

5. The process according to claim 1 , wherein the constituent materials further include a buffer, wherein the buffer comprises a rate retarding compound selected from one or more of boric acid (H 3 BO 3 ) and sulfuric acid (H 2 SO 4 ).

6. The process according to claim 5 wherein the constituent materials further comprise a defoamer, a dispersant comprising polynapthalene sulfonate, and a silicone oil selected from the group consisting of polysiloxane (C 2 H 6 OSi) n , polydimethylsiloxane (CH 3 [Si(CH 3 ) 2 O] n Si(CH 3 ) 3 ), polydimethylsiloxane, and poly(methyl hydrogen) siloxane.

7. The process according to claim 1 wherein MgO, KH 2 PO 4 , and CaSO 4 .½H 2 O react to produce in varying amounts KMgPO 4 .6H 2 O and K 2 Ca(SO 4 ) 2 .H 2 O.

8. The process according to claim 1 further comprising continuously feeding into the mixer reaction chamber one or more of the compounds selected from the group consisting of sulfuric acid, boric acid, siloxanes, and naphthalene sulfonate.

9. A lightweight building board panel comprising a building product composition manufactured by the process of claim 1 , wherein said composition is disposed adjacent to at least one of the faces of the board panel.

10. A building board panel comprising at least one building composition disposed adjacent to at least one of the faces of the board panel, wherein the building composition comprises Struvite-K (KMgPO 4 .6H 2 O), Syngenite (K 2 Ca(SO 4 ) 2 .H 2 O), and one or more of anhydrite gypsum, stucco (CaSO 4 .½H 2 O), hydrated gypsum (CaSO 4 .2H 2 O), and magnesium oxide (MgO).

11. A building board panel for use in building construction in which at least one of the faces comprises a composition comprising Struvite-K (KMgPO 4 .6H 2 O), Syngenite (K 2 Ca(SO 4 ) 2 .H 2 O) and gypsum.

12. The board panel according to claim 10 , wherein the amount of Struvite-K and Syngenite exceeds 10 weight percent of the building composition.

13. The board panel for use in building construction according claim 11 , wherein the amount of Struvite-K (KMgPO 4 .6H 2 O) and Syngenite (K 2 Ca(SO 4 ) 2 .H 2 O) comprising the face material exceeds 10 weight percent.

14. The board panel according to claim 10 , wherein at least one of the building compositions comprises Struvite-K in an amount of from 0.1 to 67.0 weight percent; Syngenite in an amount of from 2.5 to 60.0 weight percent; and one or more of anhydrite gypsum, stucco, hydrated gypsum, and magnesium oxide making up the remaining building composition.

15. The board panel according to claim 10 , wherein at least one of the building compositions comprises Struvite-K in an amount of from 15.1 to 37.0 weight percent; Syngenite in an amount of from 12.5 to 46.0 weight percent; and one or more of anhydrite gypsum, stucco, hydrated gypsum, and magnesium oxide making up the remaining building composition.

16. The process of claim 1 , wherein the building product is a building board panel.

17. The process of claim 1 , wherein the building product is a wall board panel or a ceiling tile.

18. The process of claim 1 , wherein utilizing said slurry in the manufacture of the building product comprises allowing the slurry to set and dry to form a solid building composition.

Assignees

• Certainteed Gypsum Inc

Inventors

• Hauber Robert J
• Boydston Gerald D
• Frailey Nathan
• Lamberet Severine
• Pattarkine Gaurav V
• Cherian Isaac K
• Centurione Sergio
• Ghosh Anirban

Classifications

• C04B12/027

  mixtures thereof with other inorganic cementitious materials · CPC title

• C04B12/025

  Phosphates of ammonium or of the alkali or alkaline earth metals · CPC title

• C04B2111/0062

  Gypsum-paper board like materials · CPC title

• C04B22/141

  Acids · CPC title

• C04B24/42

  Organo-silicon compounds · CPC title