Coated article having a protective coating containing silicon nitride and/or silicon oxynitride

Patent metadata

Field	Value
Publication number	US-10479724-B2
Application number	US-201916274767-A
Country	US
Kind code	B2
Filing date	Feb 13, 2019
Priority date	Feb 15, 2018
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

A coated article includes a substrate, a functional layer over at least a portion of the substrate, and a protective coating over at least a portion of the functional layer, wherein an uppermost layer of the functional layer is a metal oxide layer, and wherein the protective coating comprises a metal nitride layer and a metal oxynitride layer that is disposed between and in contact with at least part of the metal nitride layer and the metal oxide layer of the functional layer.

First claim

What is claimed is:

1. A coated article comprising:
a substrate;
a first functional layer over at least a portion of the substrate, the first functional layer comprising a silver layer over at least a portion of the substrate and an uppermost layer comprising a metal oxide over at least a portion of the silver layer;
a metal oxynitride layer comprising silicon directly over at least a portion of the uppermost layer comprising a metal oxide;
a metal nitride layer comprising silicon over at least a portion of the metal oxynitride layer; and
a protective layer comprising TiAlO over at least a portion of the metal nitride layer.

2. The coated article of claim 1 , wherein the metal oxynitride layer comprising silicon is a gradient layer in which the portion of the metal oxynitride layer closest to the uppermost layer of the first functional layer comprises a greater amount of oxygen than the portion of the metal oxynitride layer closest to the metal nitride layer.

3. The coated article of claim 1 , wherein the uppermost layer of the first functional layer comprises zinc stannate.

4. The coated article of claim 1 , wherein the first functional layer comprises a dielectric layer over at least a portion of the substrate and the silver layer over at least a portion of the dielectric layer.

5. The coated article of claim 4 , wherein the first functional layer further comprises a primer layer over at least a portion of the silver layer and under at least a portion of the uppermost layer.

6. The coated article of claim 5 , wherein the primer layer comprises titanium, or titanium and aluminum.

7. The coated article of claim 6 , wherein at least a portion of the titanium, or titanium and aluminum are oxidized after the titanium or titanium and aluminum are deposited over the silver layer.

8. The coated article of claim 5 , wherein the dielectric layer comprises one or more layers comprising zinc oxide and/or zinc stannate and/or the uppermost layer comprises zinc oxide and/or zinc stannate.

9. The coated article of claim 1 , wherein the uppermost layer of the functional layer does not comprise zinc oxide.

10. The coated article of claim 1 , further comprising a second functional layer beneath at least a portion of the first functional layer and over at least a portion of the substrate.

11. The coated article of claim 1 , wherein the metal nitride layer is directly over the metal oxynitride layer.

12. The coated article of claim 1 , mounted in a body of a vehicle or an insulating glass unit.

13. A coated article, comprising:
a glass substrate;
a first layer of zinc stannate directly over at least a portion of the glass substrate;
a layer of zinc oxide directly over at least a portion of the layer of zinc stannate;
a layer of silver directly over at least a portion of the layer of zinc oxide;
a primer layer comprising Ti, TiAl, and/or oxides of either of the preceding directly over at least a portion of the layer of silver;
a second layer of zinc stannate directly over at least a portion of the primer layer;
a metal oxynitride layer comprising silicon directly over at least a portion of the second layer of zinc stannate;
a metal nitride layer comprising silicon directly over at least a portion of the metal oxynitride layer; and
a protective layer comprising TiAlO directly over at least a portion of the metal nitride layer.

14. A coated article, comprising:
a glass substrate;
a first layer of zinc stannate over at least a portion of the glass substrate and having a thickness ranging from 250 Å to 400 Å;
a layer of zinc oxide over at least a portion of the layer of zinc stannate and having a thickness ranging from 70 Å to 90 Å;
a layer of silver over at least a portion of the layer of zinc oxide and having a thickness ranging from 70 Å to 90 Å;
a primer layer comprising Ti over at least a portion of the layer of silver and having a thickness ranging from 10 Å to 30 Å;
a second layer of zinc stannate over at least a portion of the primer layer and having a thickness ranging from 30 Å to 100 Å;
a metal oxynitride layer comprising SiON directly over at least a portion of the second layer of zinc stannate and having a thickness ranging from 70 Å to 400 Å;
a metal nitride layer comprising SiN directly over at least a portion of the metal oxynitride layer and having a thickness ranging from 100 Å to 400 Å; and
a protective layer comprising TiAlO over the metal nitride layer and having a thickness ranging from 100 Å to 400 Å.

Assignees

• Vitro Flat Glass Llc

Inventors

• Ganjoo Ashtosh
• Narayanan Sudarshan
• Finley James J
• Medwick Paul V

Classifications

• C23C28/32

  including at least one pure metallic layer · CPC title

• C03C17/3652

  the coating stack containing at least one sacrificial layer to protect the metal from oxidation · CPC title

• C03C17/3681

  the multilayer coating being used in glazing, e.g. windows or windscreens · CPC title

• C23C28/36

  including layers graded in composition or physical properties · CPC title

• C23C28/3455

  with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer · CPC title