Catalyst system and process for the production of glycols

Patent metadata

Field	Value
Publication number	US-10478809-B2
Application number	US-201615777096-A
Country	US
Kind code	B2
Filing date	Nov 17, 2016
Priority date	Nov 19, 2015
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

The invention provides a catalyst system comprising: a) one or more Group 1 metal phosphotungstate-containing species; and b) one or more catalytic species suitable for hydrogenation; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor in the presence of a solvent and said catalyst system.

First claim

That which is claimed is:

1. A catalyst system comprising:
a) one or more sodium phosphotungstate-containing species; and
b) one or more catalytic species suitable for hydrogenation.

2. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals from Groups 8, 9 or 10 of the Periodic Table, and compounds thereof.

3. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals selected from the group of cobalt, iron, platinum, palladium, ruthenium, rhodium, nickel, iridium, and compounds thereof.

4. The catalyst system according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are solid, unsupported species.

5. The catalyst system according to claim 1 , wherein the one or more sodium phosphotungstate-containing species and/or the one or more catalytic species suitable for hydrogenation are on solid catalyst supports.

6. The catalyst system according to claim 5 , wherein the solid catalyst supports are selected from aluminas, silicas, zirconium oxide, magnesium oxide, zinc oxide, titanium oxide, carbon, activated carbon, zeolites, clays, silica alumina and mixtures thereof.

7. The catalyst system according to claim 1 , wherein the weight ratio of the one or more sodium metal phosphotungstate-containing species to the one or more catalytic species suitable for hydrogenation is in the range of from 0.01:1 to 3000:1, on the basis of the total weight of the catalyst system.

8. A process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor in the presence of a solvent and the catalyst system according to claim 1 .

9. The process according to claim 8 , wherein the saccharides are selected from the group consisting of monosaccharides, disaccharides, oligosaccharides and polysaccharides.

10. The process according to claim 8 , wherein the one or more sodium phosphotungstate-containing species are present in an amount in the range of from 0.001 to 10 wt. %, based on the total weight of the reaction mixture.

11. The process according to claim 8 , wherein the reactor temperature is in the range of from 130 to 300° C.

12. The process according to claim 8 , wherein the reactor pressure is in the range of from at least 1 to at most 25 MPa.

Assignees

• Shell Oil Co

Inventors

• Geyer Reinhard
• Preising Henri
• De Vlieger Dionysius Jacobus Maria
• Edulji Smita
• Van Der Heide Evert
• Lange Jean Paul Andre Marie Joseph Ghislain

Classifications

• B01J25/02

  Raney nickel · CPC title

• B01J23/462

  Ruthenium · CPC title

• C07C29/132

  by reduction of an oxygen containing functional group · CPC title

• B01J2523/69

  Tungsten · CPC title

• C07C31/202

  Ethylene glycol · CPC title