Methanol synthesis process layout for large production capacity

Patent metadata

Field	Value
Publication number	US-10478798-B2
Application number	US-201716083549-A
Country	US
Kind code	B2
Filing date	Mar 23, 2017
Priority date	Mar 30, 2016
Publication date	Nov 19, 2019
Grant date	Nov 19, 2019

Abstract

A process layout for large scale methanol synthesis comprises one or more boiling water reactors and one or more radial flow reactors in series, the boiling water reactor(s) being fed with approximately fresh make-up syngas. The methanol synthesis loop comprises a make-up gas compressor K 1 , a recycle gas compressor K 2 , two or more boiling water converters for methanol synthesis (A 1 , A 2 , . . . ), a radial flow converter (B) for methanol synthesis, a steam drum (V 1 ), a high pressure separator (V 2 ), a low pressure separator (V 3 ), feed effluent heat exchangers (E 1 and E 2 ), a wash column (C), an air cooler (E 3 ) and a water cooler (E 4 ).

First claim

The invention claimed is:

1. A process layout for a methanol synthesis loop comprising;
a first gas compressor for pressurizing a make-up gas,
two or more boiling water converters for receiving the pressurized make-up gas and outputting a product gas,
a first heat exchanger for cooling the product gas and pre-heating the make-up gas,
a high pressure separator for separating the cooled product gas into a liquid stream and a gas stream,
a second gas compressor for compressing the gas stream,
a second heat exchanger for pre-heating the compressed gas stream,
a radial flow reactor for receiving pre-heated compressed gas stream and outputting an effluent product gas, the effluent product gas being partly cooled in the second heat exchanger and added, in part, to the product gas from the boiling water converters, wherein a second part of the effluent product gas is drawn as a purge gas,
a wash column for washing the purge gas with water to remove methanol, resulting in a methanol-free gas and a washed product, and
a low pressure separator for receiving the washed product and the cooled liquid stream from the high pressure separator, separating out gases, and outputting a crude methanol product.

2. A process layout for a methanol synthesis loop according to claim 1 , wherein the purge gas is split from the effluent product gas as wet gas (including methanol) and washed with water in the wash column to recover methanol at approximately the synthesis loop pressure.

3. A process layout for a methanol synthesis loop according to claim 1 , wherein the radial flow reactor temperature is controlled by adjusting the purge gas and hence the level of inert gas in the reactor inlet.

4. A process layout for a methanol synthesis loop according to claim 1 , wherein the radial flow reactor has a structure which requires no cooling device.

5. A process layout for a methanol synthesis loop according to claim 1 , wherein only one train of cooling equipment is used.

Assignees

• Haldor Topsoe As

Inventors

• Modarresi Hassan

Classifications

• B01J2219/00018

  Construction aspects · CPC title

• C07C29/152 Primary

  characterised by the reactor used · CPC title

• B01J2219/00051

  Controlling the temperature · CPC title

• B01J8/06

  in tube reactors; the solid particles being arranged in tubes · CPC title

• B01J2208/00176

  outside the reactor · CPC title