Electrode containing silicon and copolymer having ionic ally conductive polymer and electrically conductive polymer, and battery cell using same

Patent metadata

Field	Value
Publication number	US-10476103-B2
Application number	US-201515522338-A
Country	US
Kind code	B2
Filing date	Oct 26, 2015
Priority date	Nov 5, 2014
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

An electrode for a battery cell, including an active material which contains silicon and which contains a first polymer which is ionically conductive. The active material contains in this case a copolymer, which includes the first polymer and a second polymer, the second polymer being electrically conductive. A battery cell which includes at least one electrode is also described.

First claim

What is claimed is:

1. An electrode for a battery cell, including an active material which contains:
at least one of silicon and an alloy including silicon,
a first polymer which is ionically conductive,
a copolymer which includes the first polymer and a second polymer, the second polymer being electrically conductive, wherein the at least one of the silicon and the alloy including silicon is embedded as grains in the copolymer so as to prevent contact between an electrolyte in the battery cell and the grains of the at least one of the silicon and the alloy including silicon, wherein:
the at least one of silicon and the alloy including silicon includes a plurality of grains of at least one of silicon and the alloy including silicon,
the second polymer includes a plurality of blocks, and
at least one of the plurality of blocks of the second polymer contacts a first and a second of the grains such that the at least one of the blocks serves as an electronically conductive bridge between the first and the second grains.

2. The electrode as recited in claim 1 , wherein the electrode is an anode of the battery cell.

3. The electrode as recited in claim 1 , wherein the first polymer contains polyethylene oxide.

4. The electrode as recited in claim 1 , wherein the second polymer contains one of polyaniline (PAM) or polypyrrole (PPY).

5. The electrode as recited in claim 1 , wherein the active material contains carbon.

6. The electrode as recited in claim 1 , wherein the at least one of the silicon and the alloy including silicon is embedded in the copolymer as one of nanometer grains and micrometer grains.

7. The electrode as recited in claim 1 , wherein at least some of the silicon grains are disposed in the active material in direct contact with the first polymer and the second polymer.

8. The electrode as recited in claim 1 , wherein the alloy contains an active metal which is able to take up lithium ions.

9. The electrode as recited in claim 8 , wherein the active metal includes one of aluminum, magnesium, and tin.

10. The electrode as recited in claim 1 , wherein the alloy contains an inactive metal which is not able to take up lithium ions.

11. The electrode as recited in claim 10 , wherein the inactive metal includes one of iron, titanium, and copper.

12. A battery cell, including at least one electrode, the electrode including an active material which contains silicon and a first polymer which is ionically conductive, wherein the active material contains a copolymer which includes the first polymer and a second polymer, the second polymer being electrically conductive, wherein the silicon is embedded as grains in the copolymer so as to prevent contact between an electrolyte in the battery cell and the grains of the silicon, wherein:
the silicon includes a plurality of grains of silicon,
the second polymer includes a plurality of blocks, and
at least one of the plurality of blocks of the second polymer contacts a first and a second of the grains such that the at least one of the blocks serves as an electronically conductive bridge between the first and the second grains.

13. The battery cell as recited in claim 12 , wherein the silicon is embedded in the copolymer as one of nanometer grains and micrometer grains.

14. The battery cell as recited in claim 12 , wherein at least some of the silicon grains are disposed in the active material in direct contact with the first polymer and the second polymer.

15. A method of using a battery cell, comprising:
providing a battery cell in one of an electric vehicle, a hybrid electric vehicle, or a plug-in hybrid electric vehicle, the battery cell including at least one electrode, the electrode including an active material which contains silicon and a first polymer which is ionically conductive, wherein the active material contains a copolymer which includes the first polymer and a second polymer, the second polymer being electrically conductive, wherein the silicon is embedded as grains in the copolymer so as to prevent contact between an electrolyte in the battery cell and the grains of the silicon; and
using the battery cell in the electric vehicle, the hybrid electric vehicle, or the plug-in hybrid electric vehicle, wherein:
the silicon includes a plurality of grains of the silicon,
the second polymer includes a plurality of blocks, and
at least one of the plurality of blocks of the second polymer contacts a first and a second of the grains such that the at least one of the blocks serves as an electronically conductive bridge between the first and the second grains.

16. The method as recited in claim 15 , wherein the silicon is embedded in the copolymer as one of nanometer grains and micrometer grains.

17. The method as recited in claim 15 , wherein at least some of the silicon grains are disposed in the active material in direct contact with the first polymer and the second polymer.

Assignees

• Bosch Gmbh Robert

Inventors

• Schumann Bernd
• Verma Pallavi

Classifications

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• B60Y2200/92

  Hybrid vehicles · CPC title

• C08F26/06

  by a heterocyclic ring containing nitrogen · CPC title

• H01M2200/20

  Pressure-sensitive devices · CPC title