Chemical reaction device

Patent metadata

Field	Value
Publication number	US-10472724-B2
Application number	US-201916256630-A
Country	US
Kind code	B2
Filing date	Jan 24, 2019
Priority date	Sep 17, 2013
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

Disclosed here is a method of operating a chemical reaction device that includes the steps of determining the presence of surplus power more than a demand, and determining the presence of solar energy.

First claim

What is claim is:

1. A method of operating a chemical reaction device, the method comprising:
(1) determining presence of surplus power more than a demand; and
(2) determining presence of solar energy,

wherein:
if it is determined in the determining (1) that the surplus power is not present, electrodes in an electrolytic cell are prohibited from being immersed in an electrolyte solution, and the chemical reaction device is caused to operate as a first system using electromotive force of a photovoltaic layer including a diode characteristic; and
if it is determined in the determining (1) that the surplus power is present, the second step is performed so that, in an absence of the solar energy, the electrodes in the electrolytic cell are immersed in the electrolyte solution, and the chemical reaction device is caused to operate as a second system to generate chemical energy using the surplus power, and
in the presence of the solar energy, the electrodes in the electrolytic cell are immersed in the electrolyte solution, and the chemical reaction device is caused to operate as a third system to generate chemical energy using the electromotive force of the photovoltaic layer.

2. The method of claim 1 , further comprising:
filling the electrolytic cell with gas or a nonconductive liquid, when the chemical reaction device is caused to operate as the first system.

3. The method of claim 1 , further comprising:
filling the electrolytic cell with gas generated by the second system or the third system, when the chemical reaction device is caused to operate as the first system.

4. The method of claim 1 , wherein:
the electrodes include a first electrode and a second electrode, the first electrode arranged on a light irradiation side and the second electrode arranged on a side opposite to the light irradiation side;
the photovoltaic layer is electrically connected to the first electrode and the second electrode;
the chemical reaction device includes:
an external power supply electrically connected between the first electrode and the second electrode via a first switching element,
a power demand unit electrically connected between the first electrode and the second electrode via a second switching element in parallel with the external power supply, and
a switching element control unit configured to on/off-control the first switching element and the second switching element; and

the switching element control unit on/off-controls the first switching element and the second switching element so that the chemical reaction device operates as at least one of the first system, the second system, and the third system.

5. The method of claim 4 , wherein, in a case without surplus power more than a demand of the power demand unit, the switching element control unit turns off the first switching element and turns on the second switching element so that the chemical reaction device operates as the first system.

6. The method of claim 4 , wherein, in a case with surplus power more than a demand of the power demand unit and without light energy, the switching element control unit turns off the second switching element and turns on the first switching element so that the chemical reaction device operates as the second system.

7. The method of claim 4 , wherein, in a case with surplus power more than a demand of the power demand unit and with light energy, the switching element control unit turns off the first switching element and the second switching element so that the chemical reaction device operates as the third system.

8. The method of claim 4 , wherein the chemical reaction device comprises a sensor configured to operate by electromotive force of the external power supply or electromotive force of the photovoltaic layer.

9. The method of claim 8 , wherein the sensor is configured to measure at least one of a pH of the electrolyte solution, a concentration of the electrolyte solution, a composition of the electrolyte solution, a pressure in the electrolytic cell, a temperature in the electrolytic cell, and a light intensity.

Assignees

• Toshiba Kk

Inventors

• Ono Akihiko
• Mikoshiba Satoshi
• Kudo Yuki
• Kitagawa Ryota
• Tamura Jun
• Huang Chingchun

Classifications

• C25B1/04

  by electrolysis of water · CPC title

• C25B1/00

  Electrolytic production of inorganic compounds or non-metals · CPC title

• H01G9/20

  Light-sensitive devices · CPC title

• C25B15/02 Primary

  Process control or regulation · CPC title

• C25B3/04

  Chemistry & Metallurgy · mapped topic