Non-phosphorous transition metal control in laundry applications

Patent metadata

Field	Value
Publication number	US-10472596-B2
Application number	US-201816019735-A
Country	US
Kind code	B2
Filing date	Jun 27, 2018
Priority date	Jun 27, 2017
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

Methods and compositions for improving laundry quality in multiple areas including detergency, bleaching and wastewater operations are provided by a laundry additive composition. The laundry additive composition and methods of using the composition control iron and other transition metals in water utilized within laundry applications.

First claim

What is claimed is:

1. A method for treating laundry comprising:
contacting the laundry with a laundry additive composition comprising:
a) a gluconate chelant;
b) at least one aminocarboxylate or salt thereof, wherein the at least one aminocarboxylate or salt thereof comprises methyl glycine diacetic acid and/or diethylenetriaminepentaacetic acid;
c) at least about 16 wt-% of a carboxylate polymer selected from the group consisting of a polyacrylate polymer, a polyacrylic acid, a polymaleic acid, salt thereof, or combination thereof, wherein the ratio of the gluconate chelant to the carboxylate polymer is from about 1:1 to about 3:1; and
d) water, wherein:
i) the composition is substantially phosphorous-free;
ii) the contacting between the laundry additive and the laundry occurs before a bleaching step or together with a bleaching step; and
iii) the laundry additive composition controls transition metal contaminants throughout the laundry process under alkaline to acid pH conditions and optionally in the presence of oxidizers.

2. The method of claim 1 , wherein the laundry process comprises an initial wash process utilizing transition metal contaminated water supplied to the washer and/or transition metal contaminated soils or laundry supplied to the washer.

3. The method of claim 1 , wherein the laundry process comprises a steaming or direct steam injection contaminated with transition metals to heat waters utilized in the laundry process.

4. The method of claim 1 , wherein the gluconate chelant is a gluconate salt.

5. The method of claim 1 , wherein the dosing of the laundry additive conditioning composition is provided at a rate of: (a) about 0.5 fluid ounces to about 30 fluid ounces, (b) about 3 fluid ounces to about 30 fluid ounces per 100 pounds of linen, or (c) at a rate to control at least 0.1 ppm transition metals in the laundry process.

6. The method of claim 1 , wherein the dosing of the laundry additive composition is provided at a rate of about 0.5 to about 5 grams/L of solution of the water conditioning composition, and wherein the composition comprises from about 0.08 to about 0.8 grams/L gluconate chelant.

7. The method of claim 1 , wherein the laundry additive composition is dosed into the washing machine, dosed into a steam receiving side of a steam injection heated process within the laundry process, and/or dosed into a water reuse or recycle storage container or output line.

8. The method of claim 1 , comprising an initial step of measuring iron concentration in a water source or input to the laundry process.

9. The method of claim 1 , wherein the contacting of the laundry additive composition is: before an oxidizing step in the laundry process; and/or simultaneous with an alkaline detergent wash step in the laundry process.

10. The method of claim 1 , wherein the laundry additive composition reduces iron contaminant deposits in the laundry process to less than about 35 ppm, and reduces water hardness metal ion deposits to less than about 300 ppm.

11. A laundry additive composition comprising:
a) a gluconate chelant;
b) at least one aminocarboxylate or salt thereof, wherein the at least one aminocarboxylate or salt thereof comprises methyl glycine diacetic acid and/or diethylenetriaminepentaacetic add;
c) at least about 16 wt-% of a carboxylate polymer selected from the group consisting of a polyacrylate polymer, a polyacrylic add, a polymaleic acid, salt thereof, or combination thereof, wherein the ratio of the gluconate chelant to the carboxylate polymer is from about 1:1 to about 3:1; and
d) water, wherein the composition is substantially phosphorous-free.

12. The composition of claim 11 , wherein the composition is phosphorous-free.

13. The composition of claim 11 , wherein the gluconate chelant is sodium gluconate or gluconic acid.

14. The composition of claim 11 , wherein the at least one aminocarboxylate comprises from about 0.1 wt-% to about 10 wt-% of the composition, the carboxylate polymer comprises from 16 wt-% to about 30 wt-% of the composition, and water comprises at least about 20 wt-% of the liquid composition.

15. The composition of claim 11 , further comprising at least one additional functional ingredient.

16. The composition of claim 11 , wherein the composition is free of surfactants.

Assignees

• Ecolab Usa Inc

Inventors

• Lang jason
• Stokes Jimmy
• Silvernail Carter M
• Dotzauer David
• Lundberg Steven
• Otting Krista

Classifications

• C11D7/26

  containing oxygen · CPC title

• C11D7/3245

  Aminoacids · CPC title

• C11D7/265 Primary

  Carboxylic acids or salts thereof · CPC title

• C11D7/3209

  Amines or imines with one to four nitrogen atoms; Quaternized amines · CPC title

• C11D11/0017

  Chemistry & Metallurgy · mapped topic