Lubricating oil composition

Patent metadata

Field	Value
Publication number	US-10472583-B2
Application number	US-201515318837-A
Country	US
Kind code	B2
Filing date	Sep 18, 2015
Priority date	Sep 19, 2014
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

The present invention provides a lubricating oil composition including a viscosity index improver (A) containing a comb-shaped polymer and having an SSI (shear stability index) of 30 or less together with a base oil, wherein an HTHS viscosity (high temperature high shear viscosity) at 150° C. (T150) is 1.6 to 2.9 mPa·s, and a ratio of a kinematic viscosity at 40° C. (V40) [mm2/s] to the HTHS viscosity at 150° C. (T150) [mPa·s] (V40/T150) is 12.4 or less. The lubricating oil composition of the present invention is excellent in fuel consumption reducing properties in a low-temperature region assuming the time of starting an engine while making various properties, such as a viscosity, etc., in a high-temperature region assuming the time of high-speed operation of an engine favorable.

First claim

The invention claimed is:

1. A lubricating oil composition, comprising:
a viscosity index improver; and
a base oil;
wherein:
the viscosity index improver comprises a comb-shaped polymer;
the comb-shaped polymer has a molecular weight distribution Mw/Mn of 1.01 or greater and less than 2.00, where Mw represents a weight average molecular weight of the comb-shaped polymer, and Mn represents a number average molecular weight of the comb-shaped polymer;
the comb-shaped polymer has a weight average molecular weight of 330,000 to 600,000;
a content of the comb-shaped polymer in the viscosity index improver is 60 to 100 mass % based on a total amount of a solid component in the viscosity index improver;
the comb-shaped polymer is present in an amount of 0.90 to 4.00 mass % based on the total mass of the composition;
the viscosity index improver has a shear stability index of 30 or less;
the base oil comprises a Group 3 mineral oil;
the base oil has a kinematic viscosity at 100° C. in mm 2 /s of 2.0 to 7.0;
the base oil is present in an amount of 70 to 95 mass % based on the total mass of the composition;
the lubricating oil composition has a high temperature high shear viscosity at 150° C. of 1.6 to 2.9 mPa·s; and
a ratio of a kinematic viscosity at 40° C. in mm 2 /s of the lubricating oil composition to the high temperature high sheer viscosity at 150° C. of the lubricating oil composition is 8.00 to 12.4.

2. The lubricating oil composition according to claim 1 , wherein the comb-shaped polymer is a polymer comprising at least a constituent unit derived from a macromonomer.

3. The lubricating oil composition according to claim 1 , further comprising at least one additive for lubricating oil selected from the group consisting of a metal-based detergent, a dispersant, an anti-wear agent, an extreme pressure agent, an antioxidant, a pour-point depressant, and an anti-foaming agent.

4. The lubricating oil composition according to claim 3 , which comprises the metal-based detergent, which is an organic metal-based compound containing a metal atom selected from the group consisting of an alkali metal atom and an alkaline earth metal atom.

5. The lubricating oil composition according to claim 1 , wherein a kinematic viscosity at 100° C. of the lubricating oil composition is 4.0 to 12.5 mm 2 /s.

6. The lubricating oil composition according to claim 1 , wherein a kinematic viscosity at 40° C. of the lubricating oil composition is 10.0 to 40.0 mm 2 /s.

7. The lubricating oil composition according to claim 1 , wherein a viscosity index of the lubricating oil composition is 140 or more.

8. The lubricating oil composition according to claim 1 , wherein a content of a polymethacrylate-based compound which is not the comb-shaped polymer is 0 to 30 parts by mass based on 100 parts by mass of the comb-shaped polymer contained in the lubricating oil composition.

9. A method for improving fuel consumption reducing property, the method comprising adding the lubricating oil composition according to claim 1 to a fuel in a low-temperature region at 10 to 60° C.

10. A method for producing a lubricating oil composition, the method comprising:
blending a base oil with a viscosity index improver to obtain the lubricating oil composition;
wherein:
the viscosity index improver comprises a comb-shaped polymer;
the comb-shaped polymer has a molecular weight distribution Mw/Mn of 1.01 or greater and less than 2.00, where Mw represents a weight average molecular weight of the comb-shaped polymer, and Mn represents a number average molecular weight of the comb-shaped polymer;
the comb-shaped polymer has a weight average molecular weight of 330,000 to 600,000;
a content of the comb-shaped polymer in the viscosity index improver is 60 to 100 mass % based on a total amount of a solid component in the viscosity index improver;
the comb-shaped polymer is present in an amount of 0.90 to 4.00 mass % based on the total mass of the composition;
the viscosity index improver has a shear stability index of 30 or less;
the base oil comprises a Group 3 mineral oil;
the base oil has a kinematic viscosity at 100° C. in mm 2 /s of 2.0 to 7.0;
the base oil is present in an amount of 70 to 95 mass % based on the total mass of the composition;
the lubricating oil composition has a high temperature high shear viscosity at 150° C. of 1.6 to 2.9 mPa·s; and
a ratio of a kinematic viscosity of the lubricating oil composition at 40° C. mm 2 /s to the high temperature high sheer viscosity of the lubricating oil composition at 150° C. is 8.00 to 12.4.

11. The lubricating oil composition according to claim 1 , wherein a ratio of a kinematic viscosity of the lubricating oil composition at 40° C. mm 2 /s to the high temperature high sheer viscosity of the lubricating oil composition at 150° C. is 8.00 to 11.2.

12. The lubricating oil composition according to claim 1 , wherein the comb-shaped polymer has a weight average molecular weight of 360,000 to 600,000.

13. The lubricating oil composition according to claim 1 , further comprising:
a dispersant;
an anti-wear agent;
an anti-foaming agent;
a metal-based detergent; and
an antioxidant.

14. The lubricating oil composition according to claim 13 , wherein:
the dispersant comprises at least one of a high-molecular weight bisimide and a boron-modified monoimide;
the anti-wear agent comprises at least one of a primary zinc dialkyldithiophosphate and a secondary zinc dialkyldithiophosphate; and
the anti-foaming agent comprises a silicone-based anti-foaming agent.

15. The method according to claim 10 , wherein the comb-shaped polymer has a weight average molecular weight of 360,000 to 600,000.

16. The method according to claim 10 , wherein:
blending comprises blending a dispersant, an anti-wear agent, an anti-foaming agent, and a metal-based detergent together with the base oil and the viscosity index improver to obtain the lubricating oil composition.

17. The method according to claim 16 , wherein:
the dispersant comprises at least one of a high-molecular weight bisimide and a boron-modified monoimide;
the anti-wear agent comprises at least one of a primary zinc dialkyldithiophosphate and a secondary zinc dialkyldithiophosphate; and
the anti-foaming agent comprises a silicone-based anti-foaming agent.

Assignees

• Idemitsu Kosan Co

Inventors

• Utaka Toshimasa

Classifications

• C10N2030/68

  Shear stability · CPC title

• C10N2030/18

  Anti-foaming property · CPC title

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title

• C10N2030/04

  Detergent property or dispersant property · CPC title

• C10N2020/071

  Branched chain compounds · CPC title