Binder for power storage device electrode

Patent metadata

Field	Value
Publication number	US-10472441-B2
Application number	US-201615746535-A
Country	US
Kind code	B2
Filing date	Sep 14, 2016
Priority date	Sep 17, 2015
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

The present invention aims to provide a binder for a power storage device electrode which favorably maintains adhesiveness between active materials in a long-term cycle, and which enables production of a high-capacity storage battery with a small irreversible capacity and low resistance to have excellent output characteristics. The present invention further aims to provide a composition for a power storage device electrode, a power storage device electrode, and a power storage device each prepared using the binder for a power storage device electrode. The present invention relates to a binder for a power storage device electrode used for an electrode of a power storage device, the binder containing a polyvinyl acetal resin, the polyvinyl acetal resin having a hydroxy group-containing structural unit of the formula (1) comprising a hydroxy group-containing structural unit with a sequence length of 1, the hydroxy group-containing structural unit with a sequence length of 1 constituting 25% by weight or less of the whole hydroxy group-containing structural unit in the polyvinyl acetal resin, the polyvinyl acetal resin having a hydroxy group content of 30 to 60 mol %:

First claim

The invention claimed is:

1. A binder for a power storage device electrode used for an electrode of a power storage device,
the binder comprising a polyvinyl acetal resin,
wherein the polyvinyl acetal resin has a hydroxy group-containing structural unit of the formula (1) comprising a hydroxy group-containing structural unit with a sequence length of 1, the hydroxy group-containing structural unit with a sequence length of 1 constitutes 25% by weight or less of the whole hydroxy group-containing structural unit in the polyvinyl acetal resin, and the polyvinyl acetal resin has a hydroxy group content of 30 to 60 mol %:

wherein the polyvinyl acetal resin has a structural unit of the formula (3) having an acetyl group, a structural unit of the formula (4) having an acetal group, and a structural unit of the formula (5) having an acetal group including an ionic functional group:

wherein, in the formula (4), R 2 represents a hydrogen atom or a C1-C20 alkyl group, and in the formula (5), R 3 represents a C1-C20 alkylene group or an aromatic ring, and X represents an ionic functional group.

2. The binder for a power storage device electrode according to claim 1 ,
wherein the polyvinyl acetal resin has a structural unit of the formula (2) in an amount of 0.3 mol % or more:

wherein R 1 represents a hydrogen atom or a C1-C20 alkyl group.

3. The binder for a power storage device electrode according to claim 2 ,
wherein the polyvinyl acetal resin has the structural unit of the formula (2) in the amount of 0.3 to 5 mol %.

4. The binder for a power storage device electrode according to claim 1 , comprising a dispersion containing the polyvinyl acetal resin dispersed in an aqueous medium,
wherein the polyvinyl acetal resin is in the form of fine particles.

5. The binder for a power storage device electrode according to claim 4 ,
wherein the polyvinyl acetal resin has a volume average particle size of 10 to 500 nm.

6. A composition for a power storage device electrode, comprising the binder for a power storage device electrode according to claim 1 and an active material,
the composition containing the polyvinyl acetal resin in an amount of 0.1 to 12 parts by weight relative to 100 parts by weight of the active material.

7. A power storage device electrode comprising the composition for a power storage device electrode according to claim 6 .

8. A power storage device comprising a power storage device electrode according to claim 7 .

9. The binder for a power storage device electrode according to claim 2 , comprising a dispersion containing the polyvinyl acetal resin dispersed in an aqueous medium,
wherein the polyvinyl acetal resin is in the form of fine particles.

10. The binder for a power storage device electrode according to claim 9 ,
wherein the polyvinyl acetal resin has a volume average particle size of 10 to 500 nm.

11. A composition for a power storage device electrode, comprising the binder for a power storage device electrode according to claim 2 and an active material,
the composition containing the polyvinyl acetal resin in an amount of 0.1 to 12 parts by weight relative to 100 parts by weight of the active material.

12. A power storage device electrode comprising the composition for a power storage device electrode according to claim 11 .

13. A power storage device comprising a power storage device electrode according to claim 12 .

14. The binder for a power storage device electrode according to claim 3 , comprising a dispersion containing the polyvinyl acetal resin dispersed in an aqueous medium,
wherein the polyvinyl acetal resin is in the form of fine particles.

15. The binder for a power storage device electrode according to claim 14 ,
wherein the polyvinyl acetal resin has a volume average particle size of 10 to 500 nm.

16. A composition for a power storage device electrode, comprising the binder for a power storage device electrode according to claim 3 and an active material,
the composition containing the polyvinyl acetal resin in an amount of 0.1 to 12 parts by weight relative to 100 parts by weight of the active material.

17. A power storage device electrode comprising the composition for a power storage device electrode according to claim 16 .

18. A power storage device comprising a power storage device electrode according to claim 17 .

Assignees

• Sekisui Chemical Co Ltd

Inventors

• Morita Hiroyuki
• Nagai Yasuharu

Classifications

• H01M4/622 Primary

  being polymers · CPC title

• C08L29/14

  Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols · CPC title

• C08F216/38 Primary

  by an acetal or ketal radical · CPC title

• H01M4/13 Primary

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title