Poly(vinylbiphenyl) and poly(vinylcyclohexylstyrene) polymers and articles therefrom

Patent metadata

Field	Value
Publication number	US-10472437-B2
Application number	US-201715808096-A
Country	US
Kind code	B2
Filing date	Nov 9, 2017
Priority date	Dec 5, 2016
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

Disclosed is an article comprising polymers and copolymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted versions thereof, and blends thereof, the polymer or copolymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C. The polymers are desirably processed in the melted state at a temperature of at least 150° C. to impart orientation and extensional strain hardening.

First claim

The invention claimed is:

1. An article comprising polymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted poly(vinylbiphenyl), substituted poly(vinylcyclohexylstyrene), and blends thereof, the polymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C., wherein: 1) the polymer or polymer blend exhibits extensional strain hardening at a temperature of at least 150° C., and 2) the polymers are copolymers comprising within a range from 0.01 to 5 wt % divinylbenzene.

2. The article of claim 1 , wherein the polymer or polymer blend has a flexural modulus of at least 2000 MPa.

3. The article of claim 1 , wherein the polymer or polymer blend has a Tg within a range from 100° C. to 200° C.

4. The article of claim 1 , wherein the polymer has an Mw within a range from 100 kg/mole to 1000 kg/mole.

5. The article of claim 1 , wherein the polymer has an Mw/Mn value within the range from 1.5 to 5.

6. An article comprising: 1) polymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted poly(vinylbiphenyl), substituted poly(vinylcyclohexylstyrene), and blends thereof, the polymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C., wherein the polymer or polymer blend exhibits extensional strain hardening at a temperature of at least 150° C.; and 2) poly(phenylene oxide), a diene elastomer, or a combination of the two.

7. An article comprising polymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted poly(vinylbiphenyl), substituted poly(vinylcyclohexylstyrene), and blends thereof, the polymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C., wherein the polymer or polymer blend exhibits extensional strain hardening at a temperature of at least 150° C., wherein the poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted poly(vinylbiphenyl), and substituted poly(vinylcyclohexylstyrene) polymers are copolymers comprising within a range from 0.1 to 5 wt % divinylbenzene.

8. The article of claim 1 , wherein the polymer or polymer blend exhibits extensional strain hardening at a temperature of at least 170° C.

9. The article of claim 1 , wherein the polymer or polymer blend exhibits an increase in the viscosity above the LVE over time of at least 100 MPa·sec at a given scan rate.

10. The article of claim 1 , wherein the polymer or polymer blend is oriented when forming a fiber, a fabric, a foamed article, or a thermoformed article.

11. A process to form the polymers of claim 1 comprising combining 4-vinyl-biphenyl and/or 4-vinyl-cyclohexylstyrene and an initiator, wherein the level of such initiator in the reaction with the monomer is within a range from 0.0001 to 0.01 weight initiator/weight monomer ratio.

12. An article comprising: 1) polymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted poly(vinylbiphenyl), substituted poly(vinylcyclohexylstyrene), and blends thereof, the polymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C., wherein the polymer or polymer blend exhibits extensional strain hardening at a temperature of at least 150° C.; and 2) poly(phenylene oxide) and a diene elastomer.

13. An article comprising: 1) polymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted poly(vinylbiphenyl), substituted poly(vinylcyclohexylstyrene), and blends thereof, the polymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C., wherein the polymer or polymer blend exhibits extensional strain hardening at a temperature of at least 150° C.; and 2) poly(phenylene oxide).

14. An article comprising: 1) polymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted poly(vinylbiphenyl), substituted poly(vinylcyclohexylstyrene), and blends thereof, the polymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C., wherein the polymer or polymer blend exhibits extensional strain hardening at a temperature of at least 150° C.; and 2) diene elastomer.

15. The article of claim 1 , wherein the polymers are selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), and blends thereof.

16. An article comprising polymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted versions thereof, and blends thereof, where the term “substituted versions thereof” means the poly(vinylbiphenyl) and the poly(vinylcyclohexylstyrene) have one or more hydrogen atoms substituted for another atom or moiety selected from the group consisting of C1 to C6, or C10 alkyl, C6 to C20 aryl, C7 to C22 alkylaryl, C7 to C22 arylalkyl, C1 to C6 or C10 alkoxy, hydroxyl group, carboxy group, amine group, halogen, and combinations thereof, and the polymers are copolymers comprising within a range from 0.01 to 5 wt % divinylbenzene, have a weight average molecular weight (Mw) of at least 100 kg/mole, a glass transition temperature (Tg) of at least 100° C., and the polymer or polymer blend exhibits extensional strain hardening at a temperature of at least 150° C.

17. An article comprising polymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted poly(vinylbiphenyl), substituted poly(vinylcyclohexylstyrene), and blends thereof, wherein:
1) the polymer has a weight average molecular weight (Mw) of 100 to 1000 kg/mole
2) the polymer has a glass transition temperature (Tg) of from 100° C. to 200° C.,
3) the polymer or polymer blend exhibits extensional strain hardening at a temperature of at least 170° C.;
4) the polymer or polymer blend has a flexural modulus of at least 2000 MPa;
5) the polymer is a copolymer comprising from 0.01 to 5 wt % divinylbenzene; and
6) the polymer has an Mw/Mn value within the range from 1.5 to 5.

18. The article of claim 1 , also comprising poly(phenylene oxide), a diene elastomer, or a combination of the two.

19. The article of claim 10 , wherein the polymer or polymer blend is oriented in the melted state at a temperature of at least 150° C. to form the article.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Lopez-Barron Carlos R
• Davis Mark K
• Galuska Alan A
• Yang Yong
• Zhao Mosha H

Classifications

• C08F12/32

  containing two or more rings · CPC title

• C08L25/02

  Homopolymers or copolymers of hydrocarbons · CPC title

• C08F112/32 Primary

  containing two or more rings · CPC title

• C08F2438/00

  Living radical polymerisation · CPC title

• C08L25/04

  Homopolymers or copolymers of styrene · CPC title