Use of comb polymers for controlling the rheology of mineral binder compositions

Patent metadata

Field	Value
Publication number	US-10472283-B2
Application number	US-201815952629-A
Country	US
Kind code	B2
Filing date	Apr 13, 2018
Priority date	Apr 17, 2013
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

A comb polymer is used for increasing the flow rate and/or reducing the viscosity of a mineral binder composition, where the comb polymer has a main chain including acid groups and there are pendent chains linked to the main chain, and where the average number-average molar mass of all of the pendent chains is from 120 to 1000 g/mol and the molar ratio of the acid groups to the side chains is in the range from 0.5 to 2.

First claim

The invention claimed is:

1. A process comprising:
obtaining a comb polymer having:
a main chain comprising acid groups, and side chains attached on the main chain, where a number-average molecular weight (Mn) of all side chains in a range of from 120-800 g/mol, and a molar ratio of the acid groups to the side chains in the range of from 0.5-1.7; and

mixing the comb polymer, a mineral binder and water to form a mineral binder composition; wherein
the comb polymer is mixed into the binder composition in an amount sufficient to increase the flow rate and/or reduce the viscosity of the mineral binder composition relative to an analogous mineral binder composition that does not contain the comb polymer but otherwise is identical with the mineral binder composition comprising the comb polymer, the amount of the comb polymer also being effective to keep the yield point and/or the slump flow of the binder composition from deviating by less than 2% from that of the analogous mineral binder composition, wherein the yield point, the slump flow, the flow rate and the viscosity are measured according to DIN EN 12350-8:2010-12.

2. A process comprising:
obtaining a comb polymer having:
a main chain comprising acid groups, and side chains attached on the main chain, where a number-average molecular weight (Mn) of all side chains in a range of from 120-800 g/mol, and a molar ratio of the acid groups to the side chains in the range of from 0.5-1.7; and

mixing the comb polymer, a mineral binder and water to form a mineral binder composition; wherein
the comb polymer is mixed into the binder composition in an amount sufficient to increase the flow rate and/or reduce the viscosity of the mineral binder composition relative to an analogous mineral binder composition that does not contain the comb polymer but otherwise is identical with the mineral binder composition comprising the comb polymer, the amount of the comb polymer also being effective to keep the yield point and/or the slump flow of the binder composition from deviating by less than 1% from that of the analogous mineral binder composition, wherein the yield point, the slump flow, the flow rate and the viscosity are measured according to DIN EN 12350-8:2010-12.

3. The process of claim 1 , wherein the molar ratio of the acid groups to the side chains is in the range of from 0.75-1.7.

4. The process of claim 1 , wherein the molar ratio of the acid groups to the side chains is in the range of from 0.85-1.5.

5. The process of claim 1 , wherein the side chains are bonded to the main chain via ester, ether, amide and/or imide groups.

6. The process of claim 1 , wherein the number-average molecular weight (Mn) of the side chains is in the range of 250-800 g/mol.

7. The process of claim 1 , wherein at least 50 mol % of the side chains consist of polyalkylene oxide side chains.

8. The process of claim 7 , wherein a fraction of ethylene oxide units in the polyalkylene oxide side chains, based on all alkylene oxide units present in the side chains, is more than 90 mol %.

9. The process of claim 1 , wherein the side chains have no hydrophobic groups.

10. The process of claim 1 , wherein the comb polymer comprises the following structural subunits:
a) a mole fractions of a structural subunit S1 of the formula (I)

b) b mole fractions of a structural subunit S2 of the formula (II)

c) optionally c mole fractions of a structural subunit S3 of the formula (III)

d) optionally d mole fractions of a structural subunit S4 of the formula (IV)

where
R 1 , in each case independently of any other,

is —COOM, —SO 2 -OM, —O—PO(OM) 2 and/or —PO(OM) 2 ,
R 2 , R 3 , R 5 , R 6 , R 9 , R 10 , R 13 and R 14 , in each case independently of one another, are H or an alkyl group having 1 to 5 carbon atoms,
R 4 , R 7 , R 11 and R 15 , in each case independently of one another, are H, —COOM or an alkyl group having 1 to 5 carbon atoms,
M, independently of any other, is H + , an alkali metal ion, an alkaline earth metal ion, a di- or trivalent metal ion, an ammonium ion or an organic ammonium group,
m is 0, 1 or 2,
p is 0 or 1,
R 8 and R 12 , in each case independently of one another, are a C 1 to C 20 alkyl, cycloalkyl or alkylaryl group or are a group of the formula -[AO] n —R a ,
where A is C 2 to C 4 alkylene, R a is H, a C 1 to C 20 alkyl, cyclohexyl or alkylaryl group,
and n is 2-250,

R 16 , independently of any other, is NH 2 , —NR b R c or —OR d NR e R f , where R b and R c , independently of one another, are
a C 1 to C 20 alkyl, cycloalkyl, alkylaryl or aryl group,
or are a hydroxyalkyl group or are an acetoxyethyl (CH 3 —CO—O—CH 2 —CH 2 —) or a hydroxyisopropyl (HO—CH(CH 3 )—CH 2 —) or an acetoxyisopropyl (CH 3 —CO—O—CH(CH 3 )—CH 2 —) group;

or R b and R c together form a ring of which the nitrogen is a part, in order to construct a morpholine or imidazoline ring;
R d is a C 2 -C 4 alkylene group,
R e and R f each independently of one another are a C 1 to C 20 alkyl, cycloalkyl, alkylaryl or aryl group or a hydroxyalkyl group,
and where a, b, c and d are mole fractions of the respective structural subunits S1, S2, S3, and S4, where a/b/c/d=(0.1-0.9)/(0.1-0.9)/(0-0.8)/(0-0.8).

11. The process of claim 10 , the comb polymer consists of the structural subunits S1, S2, S3, and S4.

12. The process of claim 10 , wherein
R 8 is -[AO] n —R a ,
A is C 2 alkylene,
R a is H or a C 1 alkyl group, and
n is 2-30.

13. The process of claim 10 , wherein
m is 0,
p is 1, and
R 2 and R 5 are each mixtures of 40-60 mol % H and 40-60 mol % —CH 3 .

14. The process of claim 1 , wherein
the amount of the comb polymer is in a range of from 0.01-10 wt % based on the mineral binder content, and
a weight ratio of the water to the mineral binder in the mineral binder composition is in the range of 0.25-0.7.

15. The process of claim 1 , wherein
the amount of the comb polymer is in a range of from 0.2-5 wt % based on the mineral binder content, and
a weight ratio of the water to the mineral binder in the mineral binder composition is in the range of 0.25-0.55.

16. The process of claim 1 , wherein the mineral binder composition is a self-compacting concrete.

17. The process of claim 16 , further comprising:
filling a cavity with the self-compacting concrete; and
curing the self-compacting concrete; wherein
the cavity is filled and the self-compacting concrete is cured without separation or demixing of the self-compacting concrete, and without air inclusions.

18. The process of claim 17 , wherein
the self-compacting concrete further comprises cement and fine-grain material, and
the fine-grain material comprises flyash, metakaolin, silica dust and/or inert, finely ground rock.

19. The process of claim 18 , wherein a content of the fine-grain material is greater than 350 kg/m 3 .

20. The process of claim 18 , wherein the fine-grain material has a Blaine fineness of at least 5000 cm 2 /g.

21. The process of claim 1 , wherein
the molar ratio of the acid groups to the side

Assignees

• Sika Tech Ag

Inventors

• Frunz Lukas
• Lorcet Loic
• Zimmermann Jörg
• Petriol Pierre
• Gueville Julien
• De Carvalho Walter

Classifications

• C08F216/14

  Monomers containing only one unsaturated aliphatic radical · CPC title

• C04B28/021

  Ash cements, e.g. fly ash cements (fly ash as filler C04B18/08); Cements based on incineration residues, e.g. alkali-activated slags from waste incineration (alkali-activated combustion residues as such C04B7/243; mixtures of the lime-pozzuolane type C04B28/18); Kiln dust cements · CPC title

• C04B24/2694

  containing polyether side chains · CPC title

• C04B24/2658 Primary

  containing polyether side chains · CPC title

• C08F220/286

  and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate · CPC title