Zeolite SSZ-52x

Patent metadata

Field	Value
Publication number	US-10472247-B2
Application number	US-201715846109-A
Country	US
Kind code	B2
Filing date	Dec 18, 2017
Priority date	Dec 18, 2017
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

The present invention relates to new crystalline zeolite SSZ-52x prepared using a quaternary ammonium cation templating agent, for example, having the structure:

wherein X − is an anion which is not detrimental to the formation of the SSZ-52x. SSZ-52x is useful as a catalyst and shows improved durability, particularly with regard to NO x conversion.

First claim

What is claimed is:

1. An aluminosilicate molecular sieve composition comprising at least one intergrowth phase comprising a SFW framework type molecular sieve and an AFX framework type molecular sieve, wherein a ratio of the SFW framework type molecular sieve to the AFX framework type molecular sieve in the at least one intergrowth phase is in a range of from 60:40 to 70:30, as determined by powder X-ray diffraction.

2. The molecular sieve according to claim 1 , wherein the oxides comprise silicon oxide and aluminum oxide.

3. The molecular sieve composition of claim 2 , having a SiO 2 /Al 2 O 3 molar ratio in a range of from 6 to 50.

4. The molecular sieve according to claim 1 , wherein said zeolite is predominantly in the hydrogen form.

5. A zeolite according to claim 4 , wherein W is aluminum and Y is silicon.

6. The molecular sieve according to claim 1 having a composition; as synthesized and in the anhydrous state; in terms of mole ratios as follows:

YO 2 /W 2 O 3
   6-50

M 2/n /YO 2
 0.1-0.5

Q/YO 2
0.01-0.08

wherein Y is silicon; W is aluminum; M is an alkali metal cation, alkaline earth metal cation or mixtures thereof; n is the valence of M; and Q is a quaternary ammonium cation having the structure

where X— is an anion which is not detrimental to the formation of the zeolite.

7. The molecular sieve of claim 6 , wherein Q comprises one or more of N-ethyl-N-(2,4,4-trimethylcyclopentyl)pyrrolidinium cations, and N-ethyl-N-(3,3,5-trimethylcyclohexyl)pyrrolidinium cations.

8. A process for converting a feedstock comprising an organic compound to a conversion product which comprises contacting the feedstock at organic compound conversion conditions with a catalyst comprising an active form of the molecular sieve composition of claim 1 .

9. A method for treating an exhaust gas, the method comprising:
(a) contacting an exhaust gas stream comprising NO, and a reducing agent with a supported metal catalyst comprising: (1) one or more transition metals selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir, Pt, and mixtures thereof, and (2) a support comprising the molecular sieve composition of claim 1 , wherein the transition metal is present in an amount of 0.01 to about 6 wt. %, based on the total weight of the molecular sieve material; and
(b) selectively reducing at least a portion of the NO, with the reducing agent to produce N 2 and H 2 O.

10. The method of claim 9 , wherein the exhaust gas stream is generated by a lean-burn engine.

11. The method of claim 9 , wherein the reducing agent is ammonia.

12. The method of claim 9 , wherein the reducing agent is a hydrocarbon.

13. The method of claim 9 , wherein the contacting occurs at a temperature of 150° C. to 750° C.

14. The method of claim 9 , wherein the contacting occurs at a temperature of at least 900° C.

Assignees

• Chevron Usa Inc

Inventors

• Davis Tracy Margaret

Classifications

• B01J29/76

  Iron group metals or copper · CPC title

• B01J29/7049

  containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead · CPC title

• C01B39/48 Primary

  using at least one organic template directing agent · CPC title

• B01D53/9418

  for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas · CPC title

• B01J2029/062

  Mixtures of different aluminosilicates · CPC title