Catalyst tube for reforming

Patent metadata

Field	Value
Publication number	US-10472236-B2
Application number	US-201716344776-A
Country	US
Kind code	B2
Filing date	Oct 25, 2017
Priority date	Oct 25, 2016
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

The inventions is directed to a new design for catalyst tubes, which makes it possible to apply the concept of regenerative reforming into steam reformers having catalyst tube inlets and outlets at opposite sides of the furnace chamber. The catalyst tube comprises an inlet for process gas to enter the catalyst tube and an outlet for process gas to exit the catalyst tube, which inlet and outlet are located at opposite ends of the catalyst tube. The catalyst tube further comprises a first annular channel comprising the catalyst, a second annular channel for process gas to flow countercurrently or co-currently to the process gas flowing through the first annular channel.

First claim

The invention claimed is:

1. A catalyst tube for regenerative catalytic conversion of process gas in an industrial furnace comprising
a catalyst tube inlet for process gas to enter the catalyst tube and a catalyst tube outlet for process gas to exit the catalyst tube, which inlet and outlet are located at opposite ends of the catalyst tube;
an outer reactor tube;
an inner tube that extends coaxially inside the outer reactor tube;
a boundary located between the inner wall of the outer reactor tube and the outer wall of the inner tube;
a first annular channel for catalytically converting process gas, which channel is defined by the inner wall of the outer reactor tube and the outer wall of the boundary, which channel is loaded with catalyst material;
a second annular channel for process gas to flow countercurrently or co-currently to the process gas flowing through the first annular channel, which second annular channel is defined by the inner wall of the boundary and the outer wall of the inner tube;
an inlet barrier at the inlet end of the catalyst tube for preventing process gas to exit the outer reactor tube from the second annular channel and inner tube at the inlet end of the catalyst tube;
an outlet barrier at the outlet end of the catalyst tube for preventing process gas to exit the outer reactor tube from the first annular channel and from one of the second annular channel and the inner tube, while allowing process gas to exit the outer reactor tube from the other of the second annular channel and the inner tube;
wherein the inner tube, first annular channel and second annular channel each have an opening at the inlet side of the catalyst tube and an opening at the outlet side of the catalyst tube,
wherein the catalyst tube inlet is fluidly connected with the opening of the first annular channel at the inlet end of the catalyst tube; the opening of the first annular channel at the outlet end of the catalyst tube is fluidly connected with either the opening of the second annular channel at the outlet end of the catalyst tube or the opening of the inner tube at the outlet end of the catalyst tube; the opening of the second annular channel at the inlet end of the catalyst tube is fluidly connected with the opening of the inner tube at the inlet end of the catalyst tube; and either the opening of the inner tube at the outlet end of the catalyst tube or the opening of the second annular channel at the outlet end of the catalyst tube is fluidly connected with the catalyst tube outlet.

2. A catalyst tube according to claim 1 , wherein
the outlet barrier is an outlet barrier at the outlet end of the catalyst tube for preventing process gas to exit the outer reactor tube from the first annular channel and second annular channel, while allowing process gas to exit the outer reactor tube from the inner tube; and
wherein the catalyst tube inlet is fluidly connected with the opening of the first annular channel at the inlet end of the catalyst tube; the opening of the first annular channel at the outlet end of the catalyst tube is fluidly connected with the opening of the second annular channel at the outlet end of the catalyst tube; the opening of the second annular channel at the inlet end of the catalyst tube is fluidly connected with the opening of the inner tube at the inlet end of the catalyst tube; and the opening of the inner tube at the outlet end of the catalyst tube is fluidly connected with the catalyst tube outlet.

3. A catalyst tube according to claim 1 , wherein
the outlet barrier is an outlet barrier at the outlet end of the catalyst tube for preventing process gas to exit the outer reactor tube from the first annular channel and the inner tube, while allowing process gas to exit the outer reactor tube from the second annular channel; and
wherein the catalyst tube inlet is fluidly connected with the opening of the first annular channel at the inlet end of the catalyst tube; the opening of the first annular channel at the outlet end of the catalyst tube is fluidly connected with the opening of the inner tube at the outlet end of the catalyst tube; the opening of the second annular channel at the inlet end of the catalyst tube is fluidly connected with the opening of the inner tube at the inlet end of the catalyst tube; and
the opening of the second annular channel at the outlet end of the catalyst tube is fluidly connected with the catalyst tube outlet.

4. A catalyst tube according to claim 1 , wherein the outlet barrier comprises a circular surface connected at its sides to the inner wall of the outer reactor tube, wherein the circular surface comprises a gap at its center for allowing process gas to exit the inner tube.

5. A catalyst tube according to claim 1 , wherein the outlet barrier comprises a cone shaped body, a cylinder shaped body or a conical frustum shaped body.

6. A catalyst tube according to claim 1 , wherein the inner tube is mounted on the surface of the outlet barrier or wherein the inner tube extends through the outlet barrier.

7. A catalyst tube according to claim 1 , wherein the outer reactor tube has a tapered end at the outlet end of the reactor.

8. A catalyst tube according to claim 1 , wherein the boundary has an open end at the outlet end of the catalyst tube and a closed end at the inlet end of the catalyst tube, wherein the closed end is closed off by the inlet barrier, wherein the inlet barrier is preferably fixed or welded to the boundary at the inlet end of the reactor.

9. A catalyst tube according to claim 1 , wherein the first annular channel comprises a structure comprising one or more of corrugated plates, finned elements and foam, upon which structure the catalyst is provided.

10. A catalyst tube according to claim 1 , wherein the boundary is made of a high thermal conductivity material.

11. A catalyst tube according to claim 1 , wherein the boundary comprises a continuous assembly of multiple tubular devices stacked upon each other.

12. A catalyst tube according to claim 1 , wherein the inner reactor tube is made of a low thermal conductivity material having a thermal conductivity below 10 W/(m·K) at 800° C.

13. A catalyst tube according to claim 1 , wherein the inner tube is a round tube, a square tube or a rectangular tube.

14. A multitubular reactor comprising a furnace chamber and at least one catalyst tube according to claim 1 , wherein the catalyst tube inlets and catalyst tube outlets of the at least one catalyst tube are located at opposite sides of the furnace chamber.

15. A multitubular reactor according to claim 14 , wherein the furnace chamber comprises multiple rows of catalyst tubes contained within the furnace chamber and wherein burners are located in rows between each tube row.

16. A multitubular reactor according to claim 14 , wherein the reactor is a steam reformer.

17. A method for conducting a catalytic conversion reaction in a catalyst tube according to claim 1 .

18. Use of catalyst tube according to claim 1 for revamping a reformer, wherein the reformer comprises a furnace chamber and at least one catalyst tube, wherein the catalyst tube inlets and catalyst tube outlets of the at least one catalyst tube are located at opposite sides of the furnace chamber.

19. Use according to claim 18 , wherein revamping is done by attaching the inner tube, boundary or both to the existing catalyst holder in the reformer tubes of the existing reformer.

20. A catalyst tube according to claim 1 , wherein the boundary comprises a continuous assembly of multiple

Assignees

• Technip France

Inventors

• Farace Antonio
• Walspurger Stephane

Classifications

• B01J2219/1928

  hexagonal · CPC title

• B01J2219/19

  Details relating to the geometry of the reactor · CPC title

• B01J2208/00504

  by means of a burner · CPC title

• C01B3/38

  using catalysts · CPC title

• B01J2219/1923

  square or square-derived · CPC title