Methods of fabricating ceramic or intermetallic parts

Patent metadata

Field	Value
Publication number	US-10471507-B2
Application number	US-201514909889-A
Country	US
Kind code	B2
Filing date	Apr 24, 2015
Priority date	Apr 24, 2015
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

A part includes a three-dimensional porous metallic workpiece printed via an additive manufacturing process and subsequently subjected to a diffusion-based process to convert at least a portion of the porous metallic workpiece to a ceramic workpiece or an intermetallic workpiece.

First claim

What is claimed is:

1. A method, comprising:
extending a drill string into a wellbore from a drilling platform, the drill string having a drill bit attached to an end thereof; and
circulating a drilling fluid to the drill bit and through the wellbore with a pump fluidly connected to the drill string,
wherein the drill bit is manufactured by:
positioning one or more ceramic or intermetallic workpieces into a mold assembly that defines at least a portion of an infiltration chamber, each ceramic or intermetallic workpiece being fabricated by:
printing a three-dimensional porous metallic workpiece via an additive manufacturing process; and
subjecting the porous metallic workpiece to a diffusion-based process and thereby converting at least a portion of the porous metallic workpiece to a ceramic workpiece or an intermetallic workpiece, wherein the porous metallic workpiece comprises a metal or a metal alloy that forms a carbide, upon being subjected to a reaction atmosphere of the diffusion-based process;
depositing reinforcing materials into the infiltration chamber; and
infiltrating the one or more ceramic or intermetallic workpieces and the reinforcing materials with a binder material and thereby producing a composite, wherein a bit body of the drill bit includes a hard composite portion and the one or more ceramic or intermetallic workpieces are localized proximal to a nozzle opening or an apex of the drill bit.

2. The method of claim 1 , wherein the additive manufacturing process is selected from the group consisting of laser sintering, laser melting, electron-beam melting, laser metal deposition, fused deposition modeling, fused filament fabrication, selective laser sintering, stereolithography, laminated object manufacturing, polyj et, and any combination thereof.

3. The method of claim 1 , wherein the metal is selected from the group consisting of aluminum, antimony, barium, beryllium, bismuth, boron, cadmium, calcium, cerium, cesium, chromium, cobalt, copper, erbium, europium, gadolinium, gallium, germanium, hafnium, holmium, indium, iron, lanthanum, lead, lutetium, lithium, magnesium, manganese, molybdenum, neodymium, nickel, niobium, osmium, palladium, platinum, potassium, praseodymium, rhenium, rhodium, rubidium, ruthenium, samarium, scandium, silicon, sodium, strontium, tantalum, tellurium, terbium, thulium, tin, titanium, tungsten, vanadium, yttrium, ytterbium, zinc, and zirconium.

4. The method of claim 1 , wherein the metal alloy is an alloy resulting from the combination of at least two metals selected from the group consisting of aluminum, antimony, barium, beryllium, bismuth, boron, cadmium, calcium, cerium, cesium, chromium, cobalt, copper, erbium, europium, gadolinium, gallium, germanium, hafnium, holmium, indium, iron, lanthanum, lead, lutetium, lithium, magnesium, manganese, molybdenum, neodymium, nickel, niobium, osmium, palladium, platinum, potassium, praseodymium, rhenium, rhodium, rubidium, ruthenium, samarium, scandium, silicon, sodium, strontium, tantalum, tellurium, terbium, thulium, tin, titanium, tungsten, vanadium, yttrium, ytterbium, zinc, and zirconium.

5. The method of claim 1 , wherein some or all of the porous metallic workpiece is subjected to the reaction atmosphere during the diffusion-based process, the reaction atmosphere comprising a media selected from the group consisting of methane, air, oxygen, endogas, exogas, nitrogen, ammonia, charcoal, carbon, graphite, nitriding salts, boron, silicon, a vaporized metal, a molten metal, and any combination thereof.

6. The method of claim 1 , further comprising penetrating at least a portion of a porous network of the porous metallic workpiece with a media of the reaction atmosphere, wherein the media is selected from the group consisting of methane, air, oxygen, endogas, exogas, nitrogen, ammonia, charcoal, carbon, graphite, nitriding salts, boron, silicon, a vaporized metal, a molten metal, and any combination thereof.

7. The method of claim 1 , wherein the binder material is a material selected from the group consisting of copper, nickel, cobalt, iron, aluminum, molybdenum, chromium, manganese, tin, zinc, lead, silicon, tungsten, boron, phosphorous, gold, silver, palladium, indium, titanium, vanadium, zirconium, niobium, hafnium, tantalum, rhenium, ruthenium, osmium, iridium, and alloy thereof.

8. The method of claim 1 , wherein infiltrating the ceramic workpiece or the intermetallic workpiece with a binder material comprises:
liquefying the binder material; and
infiltrating at least a portion of a porous network of the ceramic workpiece or the intermetallic workpiece with a liquefied binder material.

9. The method of claim 1 , wherein subjecting the porous metallic workpiece to the diffusion-based process comprises masking at least a portion of the porous metallic workpiece and thereby preventing a media of the reaction atmosphere from accessing at least a portion of the porous metallic workpiece.

10. The method of claim 1 , wherein the mold assembly defines one or more cutter pockets, and wherein positioning the one or more ceramic or intermetallic workpieces into the mold assembly comprises positioning the one or more ceramic or intermetallic workpieces adjacent or near the one or more cutter pockets.

11. The method of claim 1 , wherein the mold assembly defines one or more blade regions, and wherein positioning the one or more ceramic or intermetallic workpieces into the mold assembly comprises positioning at least one ceramic or intermetallic workpiece into each blade region.

Assignees

• Halliburton Energy Services Inc

Inventors

• Thomas Jeffrey G
• Cook Iii Grant O

Classifications

• C23C8/48

  Nitriding · CPC title

• C22C29/00

  Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides {(C22C26/00 takes precedence)} · CPC title

• C04B41/88

  Metals · CPC title

• C04B41/51

  Metallising {, e.g. infiltration of sintered ceramic preforms with molten metal (covering materials with metals in general C23C; ceramic compositions containing free metal bonded to carbides, diamond, oxides, borides, nitrides, silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides or sulfides, other than as macroscopic reinforcing agents C22C; infiltration of preforms containing free metal, e.g. cermets C22C)} · CPC title

• C04B41/009

  characterised by the material treated · CPC title