Nonaqueous electrolyte battery including positive electrode including lithium nickel cobalt manganese composite oxide and negative electrode including spinel type lithium titanate, and nonaqueous electrolyte

Patent metadata

Field	Value
Publication number	US-10468679-B2
Application number	US-201715454454-A
Country	US
Kind code	B2
Filing date	Mar 9, 2017
Priority date	Mar 15, 2016
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

According to one embodiment, there is provided a nonaqueous electrolyte battery including a positive electrode, a negative electrode and a nonaqueous electrolyte. The positive electrode includes a positive electrode active material layer including a lithium nickel cobalt manganese composite oxide. The negative electrode includes a negative electrode active material layer including a spinel type lithium titanate. The nonaqueous electrolyte has an ion conductivity of not less than 7 mS/cm and not more than 10 mS/cm at 25° C. A capacity ratio p/n is within a range of not less than 1.4 and not more than 1.8. A thickness ratio T p /T n is within a range of not less than 1.05 and less than 1.3. A ratio P p /P n is within a range of not less than 0.55 and less than 0.8.

First claim

What is claimed is:

1. A nonaqueous electrolyte battery comprising:
a positive electrode comprising a positive electrode active material layer comprising lithium nickel cobalt manganese composite oxide;
a negative electrode comprising a negative electrode active material layer comprising a spinel type lithium titanate; and
a nonaqueous electrolyte having an ion conductivity of not less than 7 mS/cm and not more than 10 mS/cm at 25° C.,
wherein a capacity ratio p/n is within a range of not less than 1.4 and not more than 1.8, where p is a capacity per unit area of the positive electrode, and n is a capacity per unit area of the negative electrode,
a thickness ratio T p /T n is within a range of not less than 1.05 and less than 1.3, where T p is a thickness of the positive electrode active material layer, and T n is a thickness of the negative electrode active material layer,
a ratio P p /P n is within a range of not less than 0.55 and less than 0.8, where P p is a porosity of the positive electrode active material layer per 1μm of the thickness of the positive electrode active material layer, and P n is a porosity of the negative electrode active material layer per 1 μm of the thickness of the negative electrode active material layer.

2. The nonaqueous electrolyte battery, according to claim 1 , wherein the lithium nickel cobalt manganese composite oxide is represented by a composition formula of Li 1-a Ni x Co y Mn z O 2 , where 0≤a≤1, x>0, y>0, and z>0, and x, y, and z satisfy an inequality of 0.1≤x/(y+z)≤1.3.

3. The nonaqueous electrolyte battery, according to claim 1 , wherein the porosity of the positive electrode active material layer is 40% or less.

4. The nonaqueous electrolyte battery, according to claim 1 , wherein the density of the positive electrode active material layer is 2.9 g/cm 3 or more.

5. The nonaqueous electrolyte battery, according to claim 1 , wherein the nonaqueous electrolyte comprises a linear carbonate.

6. The nonaqueous electrolyte battery, according to claim 5 , wherein the linear carbonate comprises ethylmethyl carbonate and/or dimethyl carbonate.

7. The nonaqueous electrolyte battery, according to claim 1 , wherein the nonaqueous electrolyte comprises propylene carbonate.

8. The nonaqueous electrolyte battery, according to claim 2 , wherein in the composition formula of the lithium nickel cobalt manganese composite oxide, x, y, and z satisfy inequalities of 0.3≤x/(y+z)≤1.3 and y≥z.

9. The nonaqueous electrolyte battery, according to claim 1 , wherein wherein the nonaqueous electrolyte comprises a linear carbonate and a cyclic carbonate.

10. The nonaqueous electrolyte battery, according to claim 1 , further comprising a container member accommodating the positive electrode, the negative electrode, and the nonaqueous electrolyte,
wherein the container member is a metallic container whose wall thickness is within a range of not less than 0.2 mm and not more than 1 mm.

11. A battery system comprising:
a first battery unit comprising a lead-acid storage battery; and
a second battery unit connected to the first battery unit in parallel and comprising the nonaqueous electrolyte battery according to claim 1 .

12. The nonaqueous electrolyte battery, according to claim 1 , wherein the density of the positive electrode active material layer falls within a range from 3.0 g/cm 3 to 3.4 g/cm 3 .

13. The nonaqueous electrolyte battery, according to claim 1 , wherein a density of the negative electrode active material layer is 1.8 g/cm 3 or more.

14. The nonaqueous electrolyte battery, according to claim 1 , wherein the density of the negative electrode active material layer falls within a range from 1.9 g/cm 3 to 2.3 g/cm 3 .

Assignees

• Toshiba Kk

Inventors

• Yamamoto Dai
• Watanabe Yuki
• Kano tetsuro
• Negishi Nobuyasu
• Saruwatari Hidesato

Classifications

• H01M10/4207

  for several batteries or cells simultaneously or sequentially · CPC title

• H01M2006/5094

  Aspects relating to capacity ratio of electrolyte/electrodes or anode/cathode · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title