Patterned organic semiconductor layers

Patent metadata

Field	Value
Publication number	US-10468599-B2
Application number	US-201414328084-A
Country	US
Kind code	B2
Filing date	Jul 10, 2014
Priority date	Jan 11, 2012
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

A method of patterning organic semiconductor layers is disclosed. In one aspect, a method for forming a patterned organic semiconductor layer on a substrate includes providing a plurality of first electrodes on a substrate. The method additionally includes providing a patterned self-assembling monolayer at predetermined locations on each of the plurality of first electrodes. The method further includes providing a layer comprising an organic semiconductor material over the patterned self-assembling monolayer. A corresponding device and a photovoltaic module comprising such a device are also disclosed.

First claim

What is claimed is:

1. A method of forming a patterned organic semiconductor layer on a substrate, the method comprising:
providing a plurality of first electrodes on the substrate;
providing a patterned self-assembling monolayer at a predetermined location on each of the plurality of first electrodes;
providing a layer comprising an organic semiconductor material over the patterned self-assembling monolayer; and
providing a plurality of second electrodes on the layer comprising the organic semiconductor material, wherein each of the second electrodes corresponds to one of the first electrodes,
wherein providing the plurality of second electrodes forms an electrical contact between one or more of the second electrodes and corresponding one or more of the first electrodes by physical penetration of an electrically conductive material of the corresponding one or more of the second electrodes through the patterned self-assembling monolayer, and
wherein providing the plurality of second electrodes electrically connects one or more neighboring photovoltaic cells in series.

2. The method according to claim 1 , wherein providing the patterned self-assembling monolayer comprises providing a monolayer adapted to locally repel the layer comprising the organic semiconductor material.

3. The method according to claim 2 , wherein providing the patterned self-assembling monolayer comprises initially covering regions of the substrate where the layer comprising the organic semiconductor material is not present in a final patterned layer after completion of the method.

4. The method according to claim 2 , wherein providing the layer comprising the organic semiconductor material comprises applying the layer comprising the organic semiconductor material entirely over the entire substrate and allowing portions of the layer comprising the organic semiconductor material applied over the patterned self-assembling monolayer to be repelled therefrom, such that the layer comprising the organic semiconductor material is patterned without an additional patterning process.

5. The method according to claim 2 , wherein the predetermined location corresponds to a portion of each of the plurality of first electrodes.

6. The method according to claim 2 , wherein providing the layer comprising the organic semiconductor material comprises applying a solvent-based organic semiconductor material.

7. The method according to claim 6 , wherein providing the patterned self-assembling monolayer comprises providing a monolayer configured to repel a solvent of the solvent-based organic semiconductor material.

8. The method according to claim 7 , wherein providing the layer comprising the organic semiconductor material further comprises performing a drying process for evaporating the solvent from the solvent-based organic semiconductor material.

9. The method according to claim 1 , further comprising providing a charge injection layer on at least the plurality of first electrodes before providing the patterned self-assembling monolayer.

10. The method according to claim 9 , further comprising performing a heat treatment for inducing a reaction between the self-assembling monolayer and at least one of the plurality of first electrodes and the charge injection layer.

11. The method according to claim 1 , wherein providing the patterned self-assembling monolayer at the predetermined locations comprises ink-based printing.

12. The method according to claim 2 , wherein the predetermined locations are configured for defining a plurality of photoactive cells of an organic photovoltaic module or an array to be formed on the substrate.

13. The method according to claim 2 , wherein the predetermined locations are configured for defining a plurality of organic light emitting diodes (OLED) of an OLED array to be formed on the substrate.

14. The method according to claim 2 , wherein providing the layer comprising the organic semiconductor material comprises providing a layer comprising an organic electroluminescent material.

15. The method according to claim 1 , wherein providing the patterned self-assembling monolayer comprises forming the self-assembling monolayer only at the predetermined location on each of the plurality of first electrodes.

16. The method according to claim 1 , wherein providing the patterned self-assembling monolayer comprises removing portions of the self-assembling monolayer after providing the patterned self-assembling layer.

17. The method according to claim 1 , wherein the method comprises forming a plurality of photovoltaic cells, and wherein forming the electrical contact between the one or more of the second electrodes and the corresponding one or more of the first electrodes comprises electrically connecting neighboring ones of the plurality of photovoltaic cells.

18. The method according to claim 1 , wherein upon providing the layer comprising the organic semiconductor material, the layer comprising the organic semiconductor material is repelled from the predetermined locations covered with the patterned self-assembling monolayer while remaining in areas outside of the predetermined locations, such that the patterned organic semiconductor layer is formed, wherein the patterned organic semiconductor layer defines a plurality of photovoltaic cells of an organic photovoltaic module.

Assignees

• Imec Vzw

Inventors

• Cheyns David

Classifications

• Y02E10/549

  Organic PV cells · CPC title

• H01L27/32

  Electricity · mapped topic

• H01L51/56

  Electricity · mapped topic

• H01L51/42

  Electricity · mapped topic

• H01L2251/566

  Electricity · mapped topic