Methods for reducing thermal resistance of carbon nanotube arrays or sheets

Patent metadata

Field	Value
Publication number	US-10468327-B2
Application number	US-201214345897-A
Country	US
Kind code	B2
Filing date	Sep 21, 2012
Priority date	Sep 21, 2011
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

Carbon nanotube (CNT) forests or sheets coated and/or bonded at room temperature with one or more coatings were measured to produce thermal resistances that are on par with conventional metallic solders. These results were achieved by reducing the high contact resistance at CNT tips and/or sidewalls, which has encumbered the development of high-performance thermal interface materials based on CNTs. Resistances as low as 4.9±0.3 mm2−K/W were achieved for the entire polymer-coated CNT interface structure.

First claim

We claim:

1. A coated array or sheet of carbon nanotubes comprising
an array comprising a substrate and a plurality of vertically aligned carbon nanotubes attached to or supported by the substrate,
wherein the plurality of vertically aligned carbon nanotubes are present at a density between about 1×10 7 and 1×10 11 carbon nanotubes per mm 2 on the substrate, or
a sheet comprising a plurality of carbon nanotubes aligned in plane with the sheet surface, and
wherein tips of the plurality of vertically aligned carbon nanotubes of the array or tips of the plurality of carbon nanotubes aligned in plane with the sheet surface are coated with an effective amount of a conformal coating to reduce thermal resistance of the plurality of vertically aligned carbon nanotubes of the array or the plurality of carbon nanotubes aligned in plane with the sheet surface, as compared to an array or sheet having uncoated carbon nanotube tips when measured by a photoacoustic method,
wherein the plurality of vertically aligned carbon nanotubes of the array or the plurality of carbon nanotubes aligned in plane with the sheet surface, each comprising sidewalls of the carbon nanotubes which are uncoated by the conformal coating,
wherein the conformal coating is a flowable material selected from the group consisting of conjugated polymers, non-conjugated polymers, wax, hot glue, hot melt adhesive, and combinations thereof; and
wherein the conformal coating on the tips of the carbon nanotubes of the array or the sheet has a thickness between 1 and 1000 nm.

2. The array or sheet of claim 1 , wherein at least 90% of the plurality of vertically aligned carbon nanotubes of the array or of the plurality of carbon nanotubes aligned in plane with the sheet surface remain on the surface after sonication in ethanol.

3. The array or sheet of claim 1 , wherein the conformal coating bonds to the tips of the plurality of vertically aligned carbon nanotubes of the array or to the tips of the plurality of carbon nanotubes aligned in plane with the sheet surface through van der Waals bonds, π-π stacking, mechanical wrapping and/or covalent bonds.

4. The array or sheet of claim 1 , the substrate comprises a metal, metal oxide and/or semiconductor material and wherein the conformal coating bonds to the metal, metal oxide, or semiconductor material surfaces through van der Waals bonds, π-π stacking, and/or covalent bonds.

5. The array or sheet of claim 1 , wherein the conjugated polymer is an aromatic, heteroaromatic, or non-aromatic polymer.

6. The array or sheet of claim 1 , wherein the conjugated polymer is selected from the group consisting of polythiophenes, polystyrenes, polypyrroles, polyacetylenes, polyanilines, polyfluorenes, polyphenylenes, polypyrenes, polyazulenes, polynaphthalenes, polycarbazoles, polyindoles, polyazepines, poly(3,4-ethylenedioxythiophenes), poly(p-phenyl sulfides), poly(p-phenylene vinylene), polyacetylenes, polydiacetylenes, and combinations thereof.

7. The array or sheet of claim 6 , wherein the conjugated polymer is a polystyrene.

8. The array or sheet of claim 6 , wherein the conjugated polymer is a polythiophene.

9. The array or sheet of claim 8 , wherein the polythiophene is poly(3-hexylthiophene).

10. The array or sheet of claim 1 , wherein the non-conjugated polymer is selected from the group consisting of polyvinyl alcohol, poly(methyl methacrylate), polydimethylsiloxane, and combinations thereof.

11. The array or sheet of claim 1 , wherein the wax is selected from the group consisting of paraffin wax, synthetic wax, and polyethylene waxes.

12. The array or sheet of claim 11 , wherein the wax has a melting temperature above 80, 90, 100, 110, 120° C., or 130° C.

13. The array or sheet of claim 1 , wherein the hot glue or hot melt adhesive combines a wax, tackifiers, a polymer base, or combinations thereof.

14. The array or sheet of claim 1 , wherein the conformal coating is present in an amount effective to reduce the thermal resistance of the array by about 50%, as compared to the array or sheet having uncoated carbon nanotube tips.

15. The array or sheet of claim 1 , wherein shear adhesive strength of the array or sheet having the conformally coated tips on a glass slide is at least about two-fold greater than the shear adhesive strength of the array or sheet having uncoated carbon nanotube tips on a glass slide.

16. The array or sheet of claim 1 , further comprising a plurality of metallic particles.

17. The array or sheet of claim 16 , wherein the metallic particles are selected from the group consisting of palladium nanoparticles, gold nanoparticles, silver nanoparticles, titanium nanoparticles, iron nanoparticles, nickel nanoparticles, copper nanoparticles, and combinations thereof.

18. The array or sheet of claim 1 , further comprising one or more flowable or phase change materials that displace air between the carbon nanotubes and improve contact of the distal ends of the carbon nanotubes to a surface.

19. The array or sheet of claim 18 , wherein the one or more flowable phase change materials are selected from the group consisting of paraffin waxes, polyethylene waxes, hydrocarbon-based waxes, and blends thereof.

20. A method of making the coated carbon nanotube array or sheet of claim 1 , the method comprising the steps of
providing an array or sheet comprising a plurality of vertically aligned carbon nanotubes, and
conformally coating tips of the vertically aligned carbon nanotubes of the array or sheet with one or more conformal coating materials in an amount effective to lower the thermal resistance of the vertically aligned carbon nanotubes of the array or sheet;
wherein the plurality of the vertically aligned carbon nanotubes of the array or sheet each comprise sidewalls of the carbon nanotubes which are uncoated by the one or more conformal coating materials,
wherein the one or more coating materials is a flowable material selected from the group consisting of conjugated polymers, non-conjugated polymers, wax, hot glue, hot melt adhesive, and combinations thereof; and
wherein the conformal coating on the tips of the vertically aligned carbon nanotubes of the array or sheet has a thickness between 1 and 1000 nm.

21. The method of claim 20 , wherein the one or more coating materials are spray coated onto the array or sheet or are coated onto the array or sheet using electrochemical deposition.

22. The method of claim 20 , further comprising exposing the coating to a solvent or solvents to form a gel or viscous liquid and pressing the coated nanotube array or sheet to allow the coating to flow and fill interface voids.

23. The method of claim 22 , further comprising removing the solvent or solvent to solidify the coating.

24. The array or sheet of claim 1 , wherein the conformal coating has a thickness between 1 and 500 nm.

25. The array or sheet of claim 1 , wherein the conformal coating has a thickness between 1 and 100 nm.

26. The array or sheet of claim 1 , wherein the conformal coating has a thickness between 1 and 50 nm.

27. The array or sheet of claim 1 , wherein the plurality of vertically aligned carbon nanotubes of the array or the plurality of carbon nanotubes aligned in plane with the sheet surface each comprise void space between the sidewalls of the carbon nanotubes.

Assignees

• Georgia Tech Res Inst

Inventors

• Cola Baratunde
• Singh Virendra
• Bougher Thomas L
• Taphouse John H

Classifications

• H10W40/70

  Fillings or auxiliary members in containers or in encapsulations for thermal protection or control · CPC title

• H10W40/25 Primary

  characterised by their materials · CPC title

• H10W40/255 Primary

  having a laminate or multilayered structure, e.g. direct bond copper [DBC] ceramic substrates · CPC title

• Y10T428/30

  Self-sustaining carbon mass or layer with impregnant or other layer · CPC title

• C25D7/006

  Nanoparticles · CPC title